Hydrogen evolution using the visible-light-induced metal-to-polyoxometalate multiple electron transfer

Chemistry Letters

Volumn 43, Issue 9, 2014, Pages 1429-1431

  Suzuki, Kosuke ^a   Tang, Fei ^a   Kikukawa, Yuji ^a   Yamaguchi, Kazuya ^a   Mizuno, Noritaka ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84988424227     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.140450     Document Type: Article

References (44)

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40. 8
41. 6] (0.5 μmol), N,N-dimethylacetamide (5 mL), and 4-methoxybenzyl alcohol (50 mmol). A Teflon-coated magnetic stir bar was added, and the atmosphere of the reaction vessel was replaced by Ar. The reaction was initiated by irradiation of visible light (λ > 400 nm) with a 300 W Xe lamp equipped with a 400 nm cut off filter. Hydrogen evolution was confirmed and monitored by GC (TCD) analysis. Products in the liquid phase were confirmed by comparison of their GC (FID) retention times and GC-MS spectra with those of authentic data. Every 10 h, the reaction system was replaced by Ar to remove the evolved hydrogen. After the reaction, the catalyst was retrieved by precipitation method by addition of excess diethyl ether to the reaction solution. The retrieved I was washed with n-hexane and then air-dried prior to being used for the reuse experiment. The IR and CSI-MS spectra of the retrieved catalyst showed that the structure of I was preserved after the hydrogen evolution (Figures S3 and S4).
42. 6] (Pt cocatalyst), no hydrogen was evolved (Table 1, Entry 7). The Pt cocatalyst likely acted as a proton reduction site in the present photocatalytic system.
43. 5+ redox potential (reduction ability) of I shifted to more negative reduction potential with an increase in the acceptor number of solvents (Table S2).
44. The quantum efficiency for photocatalytic hydrogen evolution of the present system at 440 nm (using band-pass filter) was 0.35%.