Review of the hydrolysis of iron(III) and the crystallization of amorphous iron(III) hydroxide hydrate

Journal of Chemical Technology & Biotechnology

Volumn 46, Issue 2, 1989, Pages 115-134

  Cornell, Rochelle M ^a,c   Giovanoli, Rudolf ^b   Schneider, Walter ^a  

^a ETH ZURICH   (Switzerland)

^b UNIVERSITY OF BERN   (Switzerland)

^c PAUL SCHERRER INSTITUTE   (Switzerland)

Author keywords

additives; crystal morphology; crystallization; electron microscopy; iron(III) ageing; review; spinel; Fe2O3; FeO(OH)

Indexed keywords

EID: 84988110429     PISSN: 02682575     EISSN: 10974660     Source Type: Journal    
DOI: 10.1002/jctb.280460204     Document Type: Article

References (59)

1. The hydrolysis of iron
2. Hydrolysis of inorganic iron(III) salts
3. Hydrolysis of iron(III)—chaotic olation versus nucleation
4. Iron hydrolysis and the biochemistry of iron—the interplay of hydroxide and biogenic ligands
5. Characterization of partly neutralized ferric nitrate solution
6. Characterization of hydrolysed ferric ion solutions. A comparison of the effects of various anions on the solutions
7. Formation of colloidal dispersions from supersaturated iron(III) nitrate solution. I. Precipitation of amorphous iron hydroxide
8. Formation of colloidal dispersions from iron(III) nitrate solutions. II. Kinetics of growth at elevated temperatures
9. Kinetics of hydroxide Fe(III) solid phase formation
10. Precipitation in hydrolysed iron(III) solutions
11. Crystal nucleation in Fe(III) solutions and hydroxide gels
12. Structural relationships between colloidal solutions of hydroxide gels of iron(III) nitrate
13. Uber die Hydrolyse von Eisen(III) Perchlorat‐Lösungen
14. β‐Ferric oxyhydroxide
15. Crystal nucleation and growth in hydrolysing iron(III) chloride solutions
16. A detailed study of the transformation of ferrihydrite to haematite in an aqueous medium at 92°C
17. The effect of pH on the formation of goethite and hematite from ferrihydrite
18. Mineralogical constitution of colloidal hydrous ferric oxides
19. Infrared spectroscopy of ferrihydrite: evidence for the presence of structural hydroxyl groups
20. The structure of iron(III) oxide‐hydrate gels
21. Uber die Hydrolyse von Eisen(III) Salzlösungen. I. Die Hydrolyse der Lösungen von Eisen(III) Chlorid
22. The formation of hematite from amorphous iron(III) hydroxide
23. 3 aus Amorphem Eisen(III) Hydroxid
24. Hydrothermal crystal growth rate of goethite and haematite from amorphous iron(III) hydroxide investigated by X‐ray diffraction and neutron diffraction
25. Study of the local structure in poorly ordered precursors of iron oxyhydroxides
26. 59Fe. I. Fallungs‐ und Auflösungs Versuche
27. Differenzierung der Eisenoxides des Bodens durch Extraktion mit Ammoniumoxalt‐Lösung
28. Effect of solution conditions on the proportion and morphology of goethite formed from ferrihydrite
29. Influence of organic anions on the crystallization of ferrihydrite
30. Crystallization of Fe(III)‐oxide from ferrihydrite in salt solutions. Osmotic and specific ion effects
31. Der Einfluss organische Anionen auf die Bildung von Goethit und Hämatit aus amorphem Fe(III)‐Hydroxid
32. Effect of simple sugars on the alkaline transformation of ferrihydrite into goethite and hematite
33. Effect of silicate species on the transformation of ferrihydrite into goethite and hematite in alkaline media
34. Effect of silicon on the crystallization and adsorption of ferric oxides
35. The influence of aluminium on the formation of iron oxides. IV. The influence of [Al], [OH] and temperature
36. The influence of Al on iron oxides. Part III, Preparation of Al‐goethites in M KOH
37. Evidence for manganese substitution in synthetic goethites
38. Effect of manganese on the transformation of ferrihydrite into goethite and jacobsite in alkaline media
39. Amorphous and crystalline titanium and iron‐titanium oxides in synthetic preparations at near ambient conditions and in soil clays
40. The effect of copper(II) on the crystallization of α‐FeOOH
41. 2O) into crystalline products in alkaline media
42. The influence of some divalent cations on the transformation of ferrihydrite to more crystalline products
43. Comparison and classification of the effects of simple ions and molecules upon the transformation of ferrihydrite into more crystalline products
44. Interactions of metal hydrous oxides with chelating agents. 1. β‐FeOOH and EDTA
45. Infrared study of the adsorption of hydroxycarboxylic acids on α‐FeOOH and amorphous Fe(III) hydroxide
46. Ferric hydrous oxide sols and the preparation of uniform particles by hydrolysis of Fe(III) chloride‐nitrate and perchlorate solutions
47. A high resolution electron microscopy examination of domain boundaries in crystals of synthetic goethite
48. Factors that govern the formation of multi‐domainic goethites
49. Crystal morphology and the dissolution of goethite
50. The influence of aluminium on iron oxides. XII High resolution electron microscopic study of aluminous goethites