Lanthanoid-free perovskite oxide catalyst for dehydrogenation of ethylbenzene working with redox mechanism

Frontiers in Chemistry

Volumn 1, Issue , 2013, Pages

  Watanabe, Ryo ^a   Ikushima, Maiko ^b   Mukawa, Kei ^b   Sumomozawa, Fumitaka ^b   Ogo, Shuhei ^b   Sekine, Yasushi ^b  

^a SHIZUOKA UNIVERSITY   (Japan)

^b WASEDA UNIVERSITY   (Japan)

Author keywords

Dehydrogenation of ethylbenzene; Lattice oxygen; Perovskite oxide catalyst; Redox mechanism; Stable under severe conditions; Styrene production

Indexed keywords

EID: 84987602274     PISSN: None     EISSN: 22962646     Source Type: Journal    
DOI: 10.3389/fchem.2013.00021     Document Type: Article

References (42)

1. Adkin, J. J., and Hayward, M. A. (2006). Structure and magnetism of 4H-BaMnO3-x (0 = x = 0.35) and 4H-Ba0.5Sr0.5MnO3-x (0 = x = 0.21). J. Solid State Chem. 179, 70-76. doi: 10.1016/j.jssc.2005.09.046
2. Adkin, J. J., and Hayward, M. A. (2007). BaMnO3-x revisited: a structural and magnetic study. Chem. Mater. 19, 755-762. doi: 10.1021/cm062055r
3. Carver, J. C., Schweitzer, G. K., and Carlson, T. A. (1972). Use of X-ray photoelectron spectroscopy to study bonding in Cr, Mn, Fe, and Co compounds. J. Chem. Phys. 57, 973-982. doi: 10.1063/1.1678348
4. Cavani, F., and Trifirò, F. (1995). Alternative processes for the production of styrene. Appl. Catal. A 133, 219-239. doi: 10.1016/0926-860X(95)00218-9
5. Chang, W. S., Chen, Y. Z., and Yang, B. L. (1995). Oxidative dehydrogenation of ethylbenzene over VIV and VV magnesium vanadates. Appl. Catal. A 124, 221-243. doi: 10.1016/0926-860X(94)00253-3
6. Cheng, Y., Zhao, H., Teng, D., Li, F., Lu, X., and Ding, W. (2008). Investigation of Ba fully occupied A-site BaCo0.7Fe0.3-xNbxO3-d perovskite stabilized by low concentration of Nb for oxygen permeation membrane. J. Membr. Sci. 322, 484-490. doi: 10.1016/j.memsci.2008.05.065
7. Eggertsen, F. T., and Voge, H. H. (1947). Catalytic dehydrogenation. US Patent 2414585.
8. Ghaffari, M., Shannon, M., Hui, H., Tan, O. K., and Irannejad, A. (2012). Preparation, surface state and band structure studies of SrTi(1-x)Fe(x)O(3-d) (x = 0-1) perovskite-type nano structure by X-ray and ultraviolet photoelectron spectroscopy. Surf. Sci. 606, 670-677. doi: 10.1016/j.susc.2011.12.013
9. Hirano, T. (1986). Dehydrogenation of ethylbenzene over potassium-promoted iron oxide containing cerium and molybdenum oxides. Appl. Catal. 28, 119-132. doi: 10.1016/S0166-9834(00)82497-5
10. Kearby, K. K. (1945). Method for the catalytic dehydrogenation of hydrocarbons. US Patent 2370797.
11. Keller, N., Maksimova, N. I., Roddatis, V. V., Schur, M., Mestl, G., Butenko, Y. V., et al. (2002). The catalytic use of onion-like carbon materials for styrene synthesis by oxidative dehydrogenation of ethylbenzene. Angew. Chem. Int. Ed. 41, 1885-1888. doi: 10.1002/1521-3773(20020603)
12. Lee, E. H. (1974). Iron oxide catalysts for dehydrogenation of ethylbenzene in the presence of steam. Catal. Rev. Sci. Eng. 8, 285-305. doi: 10.1080/01614947408071864
13. Meima, G. R., and Menon, P. G. (2001). Catalyst deactivation phenomena in styrene production. Appl. Catal. A 212, 239-245. doi: 10.1016/S0926-860X(00)00849-8
14. Miyakoshi, A., Ueno, A., and Ichikawa, M. (2001). Mn-substituted Fe-K mixed oxide catalysts for dehydrogenation of ethylbenzene towards styrene. Appl. Catal. A 216, 137-146. doi: 10.1016/S0926-860X(01)00555-5
15. O'Hara, F. J. (1975). Dehydrogenation catalyst. US Patent 3904552.
16. Oku, M., and Hirokawa, K. (1976). X-ray photoelectron spectroscopy of Co3O4, Fe3O4, Mn3O4, and related compounds. J. Elec. Spec. Rel. Phenom. 8, 475-481. doi: 10.1016/0368-2048(76)80034-5
17. Park, M. S., Vislovskiy, V. P., Chang, J. S., Shul, Y. G., Yoo, J. S., and Park, S. E. (2003). Catalytic dehydrogenation of ethylbenzene with carbon dioxide: promotional effect of antimony in supported vanadium-antimony oxide catalyst. Catal. Today 87, 205-212. doi: 10.1016/j.cattod.2003.10.015
18. Pitzer, E. W. (1958). Catalyst and dehydrogenation process. US Patent 2866791.
19. Ponce, S., Peña, M. A., and Fierro, J. L. G. (2000). Surface properties and catalytic performance in methane combustion of Sr-substituted lanthanum manganites. Appl. Catal. B 24, 193-205. doi: 10.1016/S0926-3373(99)00111-3
20. Reddy, B. M., Rao, K. N., Reddy, G. K., Khan, A., and Park, S. E. (2007). Structural characterization and oxidehydrogenation activity of CeO2/Al2O3 and V2O5/CeO2/Al2O3 catalysts. J. Phys. Chem. C 111, 18751-18758. doi: 10.1021/jp076617l
21. Riesser, G. H. (1979). Dehydrogenation catalyst. US Patent 4144197.
22. Rokicki, A., Smith, D., and Williams, D. L. (2004). Dehydrogenation catalysts. US Patent 6756339.
23. Sakurai, Y., Suzaki, T., Nakagawa, K., Ikenaga, N., Aota, H., and Suzuki, T. (2000a). Oxidation capability of carbon dioxide in the dehydrogenation of ethylbenzene over vanadium oxide-loaded MgO catalyst. Chem. Lett. 29, 526-527. doi: 10.1246/cl.2000.526
24. Sakurai, Y., Suzaki, T., Ikenaga, N., and Suzuki, T. (2000b). Dehydrogenation of ethylbenzene with an activated carbon-supported vanadium catalyst. Appl. Catal. A 192, 281-288. doi: 10.1016/S0926-860X(99)00398-1
25. Sakurai, Y., Suzaki, T., Nakagawa, K., Ikenaga, N., Aota, H., and Suzuki, T. (2002). Dehydrogenation of ethylbenzene over vanadium oxide-loaded MgO catalyst: promoting effect of carbon dioxide. J. Catal. 209, 16-24. doi: 10.1006/jcat.2002.3593
26. Sekine, Y., Watanabe, R., Matsukata, M., and Kikuchi, E. (2008). High performance of Fe-K oxide catalysts for dehydrogenation of ethylbenzene to styrene with an aid of ppm-order Pd. Catal. Lett. 125, 215-219. doi: 10.1007/s10562-008-9580-8
27. Shao, Z., Xiong, G., Tong, J., Dong, H., and Yang, W. (2001). Ba effect in doped Sr(Co0.8Fe0.2)O3-d on the phase structure and oxygen permeation properties of the dense ceramic membranes. Sep. Purif. Technol. 25, 419-429. doi: 10.1016/S1383-5866(01)00071-5
28. Shiju, N. R., Anilkumar, M., Mirajkar, S. P., Gopinath, C. S., Rao, B. S., and Satyanarayana, C. V. (2005). Oxidative dehydrogenation of ethylbenzene over vanadia-alumina catalysts in the presence of nitrous oxide: structure-activity relationship. J. Catal. 230, 484-492. doi: 10.1016/j.jcat.2005.01.010
29. Su, D., Maksimova, N. I., Mestl, G., Kuznetsov, V. L., Keller, V., Schlögl, R., et al. (2007). Oxidative dehydrogenation of ethylbenzene to styrene over ultra-dispersed diamond and onion-like carbon. Carbon 45, 2145-2151. doi: 10.1016/j.carbon.2007.07.005
30. Su, D., Zhang, J., Frank, B., Thomas, A., Wang, X., Paraknowitsch, et al. (2010). Metal-free heterogeneous catalysis for sustainable chemistry. ChemSusChem 3, 169-180. doi: 10.1002/cssc.200900180
31. Su, D. S., Maksimova, N. I., Delgado, J. J., Keller, N., Mestl, G., Ledoux, M. J., et al. (2005). Nanocarbons in selective oxidative dehydrogenation reaction. Catal. Today 102-103, 110-114. doi: 10.1016/j.cattod.2005.02.012
32. Sugino, M., Shimada, H., Turuda, T., Miura, H., Ikenaga, N., and Suzuki, T. (1995). Oxidative dehydrogenation of ethylbenzene with carbon dioxide. Appl. Catal. A 121, 125-137. doi: 10.1016/0926-860X(95)85015-5
33. Vente, J. F., Haije, W. G., and Rak, Z. S. (2006). Performance of functional perovskite membranes for oxygen production. J. Membr. Sci. 276, 178-184. doi. 10.1016/j.memsci.2005.09.046
34. Vislovskiy, V. P., Chang, J. S., Park, M. S., and Park, S. E. (2002). Ethylbenzene into styrene with carbon dioxide over modified vanadia-alumina catalysts. Catal. Commun. 3, 227-231. doi: 10.1016/S1566-7367(02)00105-X
35. Wang, H., Tablet, C., Feldhoff, A., and Caro, J. (2005). Investigation of phase structure, sintering, and permeability of perovskite-type Ba0.5Sr0.5Co0.8Fe0.2O3-d membranes. J. Membr. Sci. 262, 20-26. doi: 10.1016/j.memsci.2005.03.046
36. Watanabe, R., Mukawa, K., Kojima, J., Kikuchi, E., and Sekine, Y. (2013). Dehydrogenation of ethylbenzene over La0.8Ba0.2Fe0.4Mn0.6O3-d perovskite oxide catalyst working by redox mechanism using steam and lattice oxygen. Appl. Catal. A 462-463, 168-177. doi: 10.1016/j.apcata.2013.04.041
37. Watanabe, R., Sekine, Y., Kojima, J., Matsukata, M., and Kikuchi, E. (2011). Dehydrogenation of ethylbenzene over highly active and stable perovskite oxide catalyst-Effect of lattice oxygen on/in perovskite oxide and role of A/B site in perovskite oxide. Appl. Catal. A 398, 66-72. doi: 10.1016/j.apcata.2011.03.016
38. Watanabe, R., Sekine, Y., Matsukata, M., and Kikuchi, E. (2009). Novel perovskite-type oxide catalysts for dehydrogenation of ethylbenzene to styrene. Catal. Lett. 131, 54-58. doi: 10.1007/s10562-009-0028-6
39. Won, J. K., and Jang, H. H. (2011). Method for improving productivity and process stability in styrene manufacturing system having multiple reactors connected in series. US Patent 2011/0166399.
40. Xu, J., Wang, L. C., Liu, Y. M., Cao, Y., He, H. Y., and Fan, K. N. (2009). Mesostructured CeO2 as an effective catalyst for styrene synthesis by oxidative dehydrogenation of ethylbenzene. Catal. Lett. 133, 307-313. doi: 10.1007/s10562-009-0174-x
41. Zeng, P., Chen, Z., Zhou, W., Gu, H., Shao, Z., and Liu, S. (2007). Re-evaluation of Ba0.5Sr0.5Co0.8Fe0.2O3-d perovskite as oxygen semi-permeable membrane. J. Membr. Sci. 291, 148-156. doi: 10.1016/j.memsci.2007.01.003
42. Zhao, T. J., Sun, W. Z., Gu, X. Y., Rønning, M., Chen, D., Dai, Y. C., et al. (2007). Rational design of the carbon nanofiber catalysts for oxidative dehydrogenation of ethylbenzene. Appl. Catal. A 323, 135-146. doi: 10.1016/j.apcata.2007.02.008