SCOPUS 정보 검색 플랫폼

Volumn 124, Issue 2, 1991, Pages 333-336

The title compound 4 was synthesized from dipotassium 1,8‐anthracenedisulfonate (9) and potassium diphenylphosphide (Ph2PK). On reaction of 4 with nickel(II) chloride and bis‐(benzonitrile)palladium(II) chloride, cyclometallation of the C – H bond in anthracene 9‐position led to the square‐planar chelate complexes 11 and 13, respectively. In the case of the palladium complex 13, the cyclometallated structure was proved by X‐ray structure analysis. Treatment with aqueous potassium cyanide did not remove nickel from 11, but converted 11 into 12 by substitution of chloride with cyanide, demonstrating the high stability of these cyclometallated chelate complexes.;1,8‐Bis(diphenylphosphino)anthracene and Metal Complexes1)

(4) Haenel, Matthias W a Jakubik, Dieter a Krüger, Carl a Betz, Peter a

a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG (Germany)

Author keywords

Anthracene; Cyclometallated chelate complexes; Nickel(II) complexes; Palladium(II) complexes; Phosphine ligand

Indexed keywords

EID: 84985665896 PISSN: 00092940 EISSN: 10990682 Source Type: Journal
DOI: 10.1002/cber.19911240214 Document Type: Article

Times cited : (55)

References (33)

1
- 84985685304
- This work is part of the doctoral thesis of, University of Düsseldorf
- (1990)
- Jakubik, D.¹

2
- 0002100344
- Chemistry of bis(diphenylphosphino)methane
- See e.g.
- (1983) Chemical Society Reviews , vol.12 , pp. 99
- Puddehatt, R.J.¹

3
- 33845556732
- (1981) Inorg. Chem. , vol.20 , pp. 3543
- Hoffman, D.M.¹ Hoffmann, R.²

4
- 0007988724
- (1988) Inorg. Chem. , vol.27 , pp. 2479
- Miedaner, A.¹ DuBois, D.L.²

5
- 49049131935
- (1982) Inorg. Chim. Acta , vol.62 , pp. 1
- Belluco, U.¹ Casellato, U.² Fenton, D.E.³ Vigato, P.A.⁴

6
- 0000462198
- For cyclometallation see
- (1973) Inorg. Chem. , vol.12 , pp. 1215
- Trofimenko, S.¹

7
- 37049103692
- Dalton Trans.
- J. Chem. Soc. , vol.1976 , pp. 1020
- Moulton, C.J.¹ Shaw, B.L.²

8
- 33845554618
- (1982) J. Am. Chem. Soc. , vol.104 , pp. 6609
- Grove, D.M.¹ van Koten, G.² Louwen, J.N.³ Noltes, J.G.⁴ Spek, A.L.⁵ Ubbels, H.J.C.⁶

9
- 0000811009
- (1984) Organometallics , vol.3 , pp. 1003
- Grove, D.M.¹ van Koten, G.² Ubbels, H.J.C.³ Zoet, R.⁴ Spek, A.L.⁵

10
- 0001305763
- (1980) J. Org. Chem. , vol.45 , pp. 1807
- House, H.O.¹ Ghali, N.I.² Haack, J.L.³ VanDerveer, D.⁴

11
- 0000863211
- (1977) Inorg. Synth. , vol.17 , pp. 186
- Luther, G.W.¹ Beyerle, G.²

12
- 84985696779
- We thank the Bayer AG, D‐5090 Leverkusen, for a gift of this compound.

13
- 85027473105
- (1927) Helvetica Chimica Acta , vol.10 , pp. 197
- Firz‐David, H.E.¹

14
- 84948941200
- J. Chem. Soc. , vol.1954 , pp. 2468
- Coffey, S.¹ Boyd, V.²

15
- 0039546566
- (1972) Org. Prep. Proc. Int. , vol.4 , pp. 211
- Hinshaw, J.C.¹

16
- 84917983337
- THE SYNTHESIS OF BENZ[α]ANTHRACENE
- (1975) Organic Preparations and Procedures International , vol.7 , pp. 267
- Ahmed, F.U.¹ Rangarajan, T.² Eisenbraun, E.J.³ Keen, G.W.⁴ Hamming, M.C.⁵

17
- 84981759782
- Umsetzung von Alkalimetallphosphiden mit Salzen aromatischer Sulfonsäuren, I: Eine neue Synthese für tertiäre und ditertiäre Phosphine
- (1965) Chemische Berichte , vol.98 , pp. 2431
- Zorn, H.¹ Schindlbauer, H.² Hagen, H.³

18
- 84978586259
- Über 1.5- und 1.8-Anthradiol (Rufol und Chrysazol)
- (1909) Berichte der deutschen chemischen Gesellschaft , vol.42 , pp. 1413
- Lampe, B.¹

19
- 84933968060
- Alkali-Phosphorverbindungen und ihr reaktives Verhalten, I. Die Darstellung der Alkali-Phosphorverbindungen
- (1959) Chemische Berichte , vol.92 , pp. 1118
- Issleib, K.¹ Tzschach, A.²

20
- 0001494347
- 1,8-Naphthalindiylbis(dimethylphosphan): Konsequenzen sterischer Hinderung für Methylierung und Borylierung
- (1982) Chemische Berichte , vol.115 , pp. 1374
- Costa, T.¹ Schmidbaur, H.²

21
- 84985701367
- The silver(I) and gold(I) complexes of 4 formed with silver triflate and gold(I) chloride will be described in a forthcoming communication.

22
- 84985662262
- AB = 139.4 Hz.

23
- 84985735834
- −1 (CN).

24
- 0000652304
- −31 at 25°C
- (1959) J. Am. Chem. Soc. , vol.81 , pp. 4780
- Freund, H.¹ Schneider, C.R.²

25
- 84985644806
- aryl–Pd s̀‐bonds; these data show 1.909, 2.050, and 1.981 Å for the minimum, maximum, and mean bond length, respectively.

26
- 0001635093
- The Cambridge Crystallographic Data Centre: computer-based search, retrieval, analysis and display of information
- (1979) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry , vol.35 , pp. 2331
- Allen, F.H.¹ Bellard, S.² Brice, M.D.³ Cartwright, B.A.⁴ Doubleday, A.⁵ Higgs, H.⁶ Hummelink, T.⁷ Hummelink‐Peters, B.G.⁸ Kennard, O.⁹ Motherwell, W.D.S.¹⁰ Rodgers, J.R.¹¹ Watson, D.G.¹²

27
- 0000968884
- Quadratisch-planare Übergangsmetall-Komplexe mit einem zweizähnigen Liganden intrans-Positionen
- See e.g.
- (1974) Angewandte Chemie , vol.86 , pp. 133
- DeStefano, N.J.¹ Johnson, D.K.² Venanzi, L.M.³

28
- 84982379265
- (1974) Angew. Chem. Int. Ed. Engl. , vol.13 , pp. 133

29
- 84986409006
- Transition-metal complexes with bidentate ligands spanningtrans-position. Part XVI. X-ray structural and31P-NMR solution studies of 2,11-Bis(diethylphosphinomethyl)benzo[c]phenanthrenesilver(I) perchlorate
- (1988) Helvetica Chimica Acta , vol.71 , pp. 703
- Camalli, M.¹ Caruso, F.² Chaloupka, S.³ Venanzi, L.M.⁴

30
- 0000564629
- (1980) J. Am. Chem. Soc. , vol.102 , pp. 4933
- Gillie, A.¹ Stille, J.K.²

31
- 0001755776
- (1989) Tetrahedron Lett. , vol.30 , pp. 463
- Ziessel, R.¹

32
- 84985733264
- We thank Prof. R. Benn and Dr. R. Mynott (NMR), Dr. K. Seevogel (IR), Dr. D. Henneberg (MS), Prof. G. Schomburg (GC), and their co‐workers, Max‐Planck‐Institut für Kohlenforschung.

33
- 84985696761
- Further details of the crystal structure investigation are available on request from the Fachinformationszentrum Karlsruhe, Gesellschaft für wissenschaftlich‐technische Information mbH, D‐7514 Eggenstein‐Leopoldshafen 2, on quoting the depository number CSD‐54914, the names of the authors, and the journal citation.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.