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Volumn 26, Issue 8, 1987, Pages 743-760

RP‐Bridged Metal Carbonyl Clusters: Synthesis, Properties, and Reactions

Author keywords

Bridging ligands; Carbonyl ligands; Cluster compounds; P ligands

Indexed keywords


EID: 84985580866     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.198707431     Document Type: Review
Times cited : (151)

References (309)
  • 15
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    • For the structural relationships between the chemistry of clusters and solid‐state chemistry, see, for example
    • (1981) Angew. Chem. , vol.93 , pp. 44
    • von Schnering, H.G.1
  • 17
    • 84985523559 scopus 로고    scopus 로고
    • Osmium clusters are an exception; for a review see, in [3a], p. 391.
    • Deeming, A.J.1
  • 19
    • 84985550561 scopus 로고    scopus 로고
    • The word “bond” is used here even when the “observed” bond is not a localized two‐center two‐electron bond. It indicates more a geometrical relation between two centers; if they are as close as would be predicted from the sum of the covalent radii, they form a “bond”: if the bond is broken, this geometrical condition is no longer fulfilled.
  • 20
    • 84985594620 scopus 로고    scopus 로고
    • “Daran merkt man, daß wir nicht nur blöd, sondern auch gebildet sind.”, Karl Valentin, Liesl Karlstadt; all titles available from Piper, Munich; recordings available from Ariola Eurodisc GmbH.
  • 24
    • 84985538003 scopus 로고    scopus 로고
    • 2(XR)] (X = P, As, Sb, Bi) the terms phosphinidene, arsinidene, stibinidene, and bismuthinidene complex, respectively, are accepted internationally. We have therefore used these terms, instead of the rarely used IUPAC recommendations: phosphanediyl, arsanediyl, … complex.
  • 50
    • 84985505163 scopus 로고
    • Further examples:, A Specialist Periodical Report. The Royal Society of Chemistry.
    • (1985) Organophosphorus Chem. , vol.15
  • 51
    • 84985513991 scopus 로고    scopus 로고
    • m)] (X = N, P, S)
  • 66
    • 84982065848 scopus 로고
    • Heteronucleare Clustersysteme, XVI. Darstellung und Untersuchung von Tris(tetracarbonylcobaltio)-bismutan — ein Beitrag zur Frage der Existenz Bismut-haltiger Nonacarbonyltricobalt-Clusterverbindungen
    • (1979) Chemische Berichte , vol.112 , pp. 2574
    • Etzrodt, G.1    Boese, R.2    Schmid, G.3
  • 82
    • 84985576929 scopus 로고    scopus 로고
    • Similar cage structures: [19]
  • 133
    • 84985630564 scopus 로고    scopus 로고
    • 3‐RP‐clusters has not been investigated.
  • 185
    • 0002385123 scopus 로고
    • Relevant articles are referred to in [111] under references 3–26. A nice example of the rediscovery of this principle is given by
    • (1986) Inorg. Chim. Acta , vol.115 , pp. L39
    • Johnson, B.F.G.1
  • 200
    • 84985495744 scopus 로고    scopus 로고
    • The kinetics of adduct formation corresponds to the pattern discussed for the conversion 16 → 43:, Diplomarbeit. Universität Konstanz 1986
    • Buchholz, D.1
  • 202
    • 84985581103 scopus 로고    scopus 로고
    • See Ref. 22 in [117].
  • 212
  • 230
    • 84944295883 scopus 로고
    • Chirale PFeCoM-Cluster: Darstellung durch Metallaustausch und Untersuchung der optischen Aktivität
    • for chiral RP‐bridged clusters, see
    • (1983) Chemische Berichte , vol.116 , pp. 2748
    • Müller, M.1    Vahrenkamp, H.2
  • 235
    • 84985523574 scopus 로고    scopus 로고
    • 13] shows that clusters of higher nuclearity can be formed on heating [62].
  • 236
    • 84985505199 scopus 로고    scopus 로고
    • 10] by HCl [123],are not discussed here, sine they do not involve the cluster itself.
  • 246
    • 0000409678 scopus 로고
    • Niederkoordinierte Phosphor-, Arsen-, Antimon- und Bismut-Mehrfachbindungssysteme als Komplexliganden
    • review
    • (1985) Angewandte Chemie , vol.97 , pp. 905
    • Scherer, O.J.1
  • 254
    • 84985624538 scopus 로고    scopus 로고
    • A phosphagermaalkene was recently reported
  • 291
    • 0002941662 scopus 로고
    • Metall-Kohlenstoff- und Metall-Metall-Mehrfachbindungen als Liganden in der Übergangsmetallchemie: Die Isolobal-Beziehung
    • review
    • (1984) Angewandte Chemie , vol.96 , pp. 85
    • Stone, F.G.A.1
  • 301
    • 84985513298 scopus 로고    scopus 로고
    • The MO analysis of clusters that consist of organometallic fragments and main‐group units generally involves the study of interactions between the main‐group ligands (e. g., RP[l85]or acetylene [186]) and the transition‐metal cluster fragment. This method corresponds to the view that “sbuilding blocks” with similar orbital energies should be grouped together. The fragment analysis suggested here (which has not yet been substantiated by MO studies) does not follow this method. This can be justified by the view that the interactions between “soft” ligands such as RP, S, or acetylene and transition metals are certainly strongly influenced by overlap, so that the difference in orbital energies between main‐group centers and transition‐metal centers is no longer so important. We thank Dr. H. Berke (Konstanz) for this comment.
  • 305
    • 84985499900 scopus 로고    scopus 로고
    • unpublished results, presented at the International Workshop Fundamental Pathways at Dinuclear and Polynuclear Transition Metal Centers, Königstein/Taunus, September 1985.
    • Adams, R.D.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.