-
15
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-
84985573184
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-
For the structural relationships between the chemistry of clusters and solid‐state chemistry, see, for example
-
(1981)
Angew. Chem.
, vol.93
, pp. 44
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-
von Schnering, H.G.1
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17
-
-
84985523559
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-
Osmium clusters are an exception; for a review see, in [3a], p. 391.
-
-
-
Deeming, A.J.1
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19
-
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84985550561
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-
The word “bond” is used here even when the “observed” bond is not a localized two‐center two‐electron bond. It indicates more a geometrical relation between two centers; if they are as close as would be predicted from the sum of the covalent radii, they form a “bond”: if the bond is broken, this geometrical condition is no longer fulfilled.
-
-
-
-
20
-
-
84985594620
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-
“Daran merkt man, daß wir nicht nur blöd, sondern auch gebildet sind.”, Karl Valentin, Liesl Karlstadt; all titles available from Piper, Munich; recordings available from Ariola Eurodisc GmbH.
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-
-
-
24
-
-
84985538003
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-
2(XR)] (X = P, As, Sb, Bi) the terms phosphinidene, arsinidene, stibinidene, and bismuthinidene complex, respectively, are accepted internationally. We have therefore used these terms, instead of the rarely used IUPAC recommendations: phosphanediyl, arsanediyl, … complex.
-
-
-
-
50
-
-
84985505163
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-
Further examples:, A Specialist Periodical Report. The Royal Society of Chemistry.
-
(1985)
Organophosphorus Chem.
, vol.15
-
-
-
51
-
-
84985513991
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-
m)] (X = N, P, S)
-
-
-
-
64
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-
34250264488
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The behaviour of the AsCo3(CO)9 cluster as a ligand for Cr, Mo, W, and Fe carbonyls and AlCl3
-
(1979)
Transition Metal Chemistry
, vol.4
, pp. 294
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-
Vizi‐Orosz, A.1
Galamb, V.2
Ötvös, I.3
Pályi, G.4
Markó, L.5
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66
-
-
84982065848
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Heteronucleare Clustersysteme, XVI. Darstellung und Untersuchung von Tris(tetracarbonylcobaltio)-bismutan — ein Beitrag zur Frage der Existenz Bismut-haltiger Nonacarbonyltricobalt-Clusterverbindungen
-
(1979)
Chemische Berichte
, vol.112
, pp. 2574
-
-
Etzrodt, G.1
Boese, R.2
Schmid, G.3
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82
-
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84985576929
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-
Similar cage structures: [19]
-
-
-
-
95
-
-
0001588127
-
-
(1986)
J. Organomet. Chem.
, vol.304
, pp. 157
-
-
Lang, H.1
Huttner, G.2
Zsolnai, L.3
Mohr, G.4
Sigwarth, B.5
Weber, U.6
Orama, O.7
Jibril, I.8
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133
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-
84985630564
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-
3‐RP‐clusters has not been investigated.
-
-
-
-
185
-
-
0002385123
-
-
Relevant articles are referred to in [111] under references 3–26. A nice example of the rediscovery of this principle is given by
-
(1986)
Inorg. Chim. Acta
, vol.115
, pp. L39
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-
Johnson, B.F.G.1
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192
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84985625612
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-
Diplomarbeit, Universität Konstanz 1984
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-
-
Frank, L.‐R.1
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200
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-
84985495744
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-
The kinetics of adduct formation corresponds to the pattern discussed for the conversion 16 → 43:, Diplomarbeit. Universität Konstanz 1986
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-
-
Buchholz, D.1
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202
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-
84985581103
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-
See Ref. 22 in [117].
-
-
-
-
230
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-
84944295883
-
Chirale PFeCoM-Cluster: Darstellung durch Metallaustausch und Untersuchung der optischen Aktivität
-
for chiral RP‐bridged clusters, see
-
(1983)
Chemische Berichte
, vol.116
, pp. 2748
-
-
Müller, M.1
Vahrenkamp, H.2
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235
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84985523574
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-
13] shows that clusters of higher nuclearity can be formed on heating [62].
-
-
-
-
236
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84985505199
-
-
10] by HCl [123],are not discussed here, sine they do not involve the cluster itself.
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-
-
-
246
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-
0000409678
-
Niederkoordinierte Phosphor-, Arsen-, Antimon- und Bismut-Mehrfachbindungssysteme als Komplexliganden
-
review
-
(1985)
Angewandte Chemie
, vol.97
, pp. 905
-
-
Scherer, O.J.1
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254
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-
84985624538
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-
A phosphagermaalkene was recently reported
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-
-
-
291
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-
0002941662
-
Metall-Kohlenstoff- und Metall-Metall-Mehrfachbindungen als Liganden in der Übergangsmetallchemie: Die Isolobal-Beziehung
-
review
-
(1984)
Angewandte Chemie
, vol.96
, pp. 85
-
-
Stone, F.G.A.1
-
301
-
-
84985513298
-
-
The MO analysis of clusters that consist of organometallic fragments and main‐group units generally involves the study of interactions between the main‐group ligands (e. g., RP[l85]or acetylene [186]) and the transition‐metal cluster fragment. This method corresponds to the view that “sbuilding blocks” with similar orbital energies should be grouped together. The fragment analysis suggested here (which has not yet been substantiated by MO studies) does not follow this method. This can be justified by the view that the interactions between “soft” ligands such as RP, S, or acetylene and transition metals are certainly strongly influenced by overlap, so that the difference in orbital energies between main‐group centers and transition‐metal centers is no longer so important. We thank Dr. H. Berke (Konstanz) for this comment.
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-
-
-
305
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84985499900
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-
unpublished results, presented at the International Workshop Fundamental Pathways at Dinuclear and Polynuclear Transition Metal Centers, Königstein/Taunus, September 1985.
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-
-
Adams, R.D.1
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