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Volumn 20, Issue 8, 1981, Pages 687-689

A General Procedure for Intramolecular α‐tert‐Alkylation of Carbonyl Compounds

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EID: 84985516453 PISSN: 05700833 EISSN: 15213773 Source Type: Journal
DOI: 10.1002/anie.198106872 Document Type: Article

Times cited : (24)

References (11)

1
- 84982071588
- Lewis-Säure-bedingte α-Alkylierung von Carbonylverbindungen, VII. Regio- und positionsspezifische α-tert-Alkylierung von Ketonen
- and lit. cited therein
- (1980) Chemische Berichte , vol.113 , pp. 3741
- Reetz, M.T.¹ Maier, W.F.² Chatziiosifidis, I.³ Giannis, A.⁴ Heimbach, H.⁵ Löwe, U.⁶

2
- 0000697458
- Only a few isolated examples of such processes are known: The cyclization of (6a) has been described independently
- (1979) J. Am. Chem. Soc. , vol.101 , pp. 4401
- Sum, F.W.¹ Weiler, L.²

3
- 0010470995
- see also other strategies
- (1969) J. Am. Chem. Soc. , vol.91 , pp. 1557
- Corey, E.J.¹ Girota, N.N.² Mathew, C.T.³

7
- 33847805890
- (1974) J. Am. Chem. Soc , vol.96 , pp. 1082
- Huckin, S.N.¹ Weiler, L.²

8
- 84982055879
- This process is related to the tert‐butylation of dicarbonyl compounds under Friedel‐Crafts conditions
- (1969) Justus Liebigs Ann. Chem. , vol.718 , pp. 101
- Boldt, P.¹ Militzer, H.² Thielecke, W.³ Schulz, L.⁴

10
- 33947478720
- (1961) J. Org. Chem. , vol.26 , pp. 1609
- Barnes, R.A.¹ Houlihan, W.J.²

11
- 84985507416
- (18a–c) were prepared analogously to (l)→(2). The corresponding allyl bromides can be made classically by addition of vinylmagnesium bromide to cyclic ketones and subsequent treatment with HBr.

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