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Angewandte Chemie International Edition in English
Volumn 12, Issue 4, 1973, Pages 330-332
A Macroisopolyanion of Molybdenum: Mo36O 8−112
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Indexed keywords

EID: 84982379095     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.197303301     Document Type: Article
Times cited : (50)
References (27)
  • 5
    • 84982363223 scopus 로고    scopus 로고
    • 7O 246− per 1.
  • 6
    • 84982359042 scopus 로고    scopus 로고
    • + to MO 2−4 applied initially.
  • 7
    • 84982361443 scopus 로고    scopus 로고
    • Measurements were performed on a CODERG PH 1 Raman spectrometer combined with an OIP 181 E 200 mW‐He‐Ne‐laser.
  • 8
    • 84982374038 scopus 로고    scopus 로고
    • If for a solution appropriate steps are taken to obtain linearity between the concentration of a species and the intensity of its Raman spectrum, intensity difference diagrams can be used in the same way as extinction difference diagrams in absorption spectroscopy [6] for clarification of the course of chemical reactions.
  • 9
    • 84982369376 scopus 로고    scopus 로고
    • Dissertation, Technische Hochschule Aachen 1967
    • Tytko, K.H.1
  • 11
    • 84982376864 scopus 로고    scopus 로고
    • By “molybdenum fraction” we mean the amount of molybdenum, expressed as a fraction, in the species under discussion.
  • 12
    • 84982366830 scopus 로고    scopus 로고
    • + and MO 2−4 in the overall equation of formation of the isopolyion.
  • 15
    • 84943475086 scopus 로고
    • Über die Bildungsweise von Polywolframaten und -molybdaten in wäßriger Lösung
    • (1971) Angewandte Chemie , vol.83 , pp. 935
    • Tytko, K.H.1
  • 16
    • 84982344184 scopus 로고
    • Lecture at Heidelberg 1972, and at the 1st Meeting, International Society for the Study of Solute‐Solute‐Solvent Interactions, Marseille 1972
    • (1971) Angew. Chem. internat. Edit. , vol.10 , pp. 860
  • 18
    • 84982381845 scopus 로고    scopus 로고
    • o, and that value must be further corrected in respect of the charge.
  • 19
    • 84982385259 scopus 로고    scopus 로고
    • + ions take part in the packing, analogously to ammonium polymetalates [13].
  • 22
    • 84982384693 scopus 로고    scopus 로고
    • 4 salts are isotypic) several monoclinic species were found whose diffraction patterns were the same or very similar. Analogous calculations and considerations (see above and the structural proposal) lead to an almost identical distribution of the 36‐molybdate ions in the unit cell. Further investigation is in progress.
  • 26
    • 84982376340 scopus 로고    scopus 로고
    • + concentration at equilibrium.
  • 27
    • 84982383334 scopus 로고    scopus 로고
    • We thank Dr. W. Bähr, MPI für Biophysikalische Chemie, Göttingen, for his help with this part of the investigation.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.