Electrocatalytic hydrogenation of oxygenates using earth-abundant transition-metal nanoparticles under mild conditions

ChemSusChem

Volumn 9, Issue 15, 2016, Pages 1904-1910

  Carroll, Kyler J ^a   Burger, Thomas ^a,b   Langenegger, Lukas ^a,c   Chavez, Steven ^a   Hunt, Sean T ^a   Román Leshkov, Yuriy ^a   Brushett, Fikile R ^a  

^a Massachusetts Institute of Technology   (United States)

^b TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^c ETH ZURICH   (Switzerland)

Author keywords

Electrocatalysis; Heterogeneous catalysis; Hydrogenation; Nickel; Renewable resources

Indexed keywords

CATALYSIS; CATALYST ACTIVITY; CATALYSTS; ELECTROCATALYSIS; ELECTROCATALYSTS; HYDROGENATION; METAL NANOPARTICLES; NANOPARTICLES; NICKEL; PRECIOUS METALS; SYNTHESIS (CHEMICAL);

ELECTROCATALYTIC HYDROGENATION; FARADAIC EFFICIENCIES; NON-PRECIOUS METAL CATALYSTS; NON-PRECIOUS METALS; OPERATING CONDITION; PRODUCT SELECTIVITIES; RENEWABLE RESOURCE; TURNOVER FREQUENCY;

CATALYST SELECTIVITY;

CARBON; METAL NANOPARTICLE; OXYGEN; TRANSITION ELEMENT;

CATALYSIS; CHEMISTRY; CONFORMATION; ELECTROCHEMISTRY; HYDROGENATION; MOLECULAR MODEL;

CARBON; CATALYSIS; ELECTROCHEMISTRY; HYDROGENATION; METAL NANOPARTICLES; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXYGEN; TRANSITION ELEMENTS;

EID: 84981243937     PISSN: 18645631     EISSN: 1864564X     Source Type: Journal    
DOI: 10.1002/cssc.201600290     Document Type: Article

References (20)

1. Y. Román-Leshkov, C. J. Barrett, Z. Y. Liu, J. A. Dumesic, Nature 2007, 447, 982 –985.
2. J. Jae, W. Zheng, R. F. Lobo, D. G. Vlachos, ChemSusChem 2013, 6, 1158 – 1162.
3. S. De, S. Dutta, B. Saha, ChemSusChem 2012, 5, 1826 –1833.
4. Encyclopedia of Applied Electrochemistry (Eds.: G. Kreysa, K. Ota, R. F. Savinell), Springer New York, New York, NY, 2014.
5. S. De, B. Saha, R. Luque, Bioresour. Technol. 2015, 178, 108 –118.
6. I. Gandarias, P. L. Arias, J. Requies, M. El Doukkali, M. B. Güemez, J. Catal. 2011, 282, 237 –247.
7. Y. S. Yun, D. S. Park, J. Yi, Catal. Sci. Technol. 2014, 4, 3191 –3202.
8. R. Parsons, Trans. Faraday Soc. 1958, 54, 1053 –1063.
9. Z. Li, M. Garedew, C. H. Lam, J. E. Jackson, D. J. Miller, C. M. Saffron, Green Chem. 2012, 14, 2540 –2549.
10. P. Nilges, U. Schröder, Energy Environ. Sci. 2013, 6, 2925 –2931.
11. Z. Li, S. Kelkar, C. H. Lam, K. Luczek, J. E. Jackson, D. J. Miller, C. M. Saffron, Electrochim. Acta 2012, 64, 87–93.
12. B. Mahdavi, A. Lafrance, A. Martel, J. Lessard, H. Me, L. Brossard, J. Appl. Electrochem. 1997, 27, 605 –611.
13. S. H. Pang, N. E. Love, J. W. Medlin, J. Phys. Chem. Lett. 2014, 5, 4110– 4114.
14. L. Chen, Y. Zhu, H. Zheng, C. Zhang, B. Zhang, Y. Li, J. Mol. Catal. A 2011, 351, 217 –227.
15. A. R. Ardiyanti, S. A. Khromova, R. H. Venderbosch, V. A. Yakovlev, I. V. Melián-Cabrera, H. J. Heeres, Appl. Catal. A 2012, 449, 121 –130.
16. M. Besson, P. Gallezot, Catal. Today 2003, 81, 547 –559.
17. I. Arends, R. A. Sheldon, Appl. Catal. A 2001, 212, 175 –187.
18. K. Manthiram, Y. Surendranath, A. P. Alivisatos, J. Am. Chem. Soc. 2014, 136, 7237 –7240.
19. Metal Prices in the United States through 2010: U.S. Geological Survey Scientific Investigations Report 2012 –5188, U.S. Geological Survey, 2013.
20. K. Seto, A. Iannelli, B. Love, J. Lipkowski, J. Electroanal. Chem. Interfacial Electrochem. 1987, 226, 351 –360.