In-situ nano-alloying Pd-Ni for economical control of syngas production from high-temperature thermo-electrochemical reduction of steam/CO2

Applied Catalysis B: Environmental

Volumn 200, Issue , 2017, Pages 265-273

  Kim, Si Won ^a,b   Park, Mansoo ^a   Kim, Hyoungchul ^a   Yoon, Kyung Joong ^a   Son, Ji Won ^a   Lee, Jong Ho ^a   Kim, Byung Kook ^a   Lee, Jong Heun ^b   Hong, Jongsup ^a  

^a Korea Institute of Science and Technology   (South Korea)

^b Korea University   (South Korea)

Author keywords

CO2 reduction; Energy storage; Noble metal alloys; Reverse water gas shift; Syngas production

Indexed keywords

ALLOYING; CHEMICAL SHIFT; COST EFFECTIVENESS; ELECTROLYTIC REDUCTION; ENERGY STORAGE; PALLADIUM; PRECIOUS METALS; QUALITY CONTROL; REDUCTION; SOLID OXIDE FUEL CELLS (SOFC); SYNTHESIS GAS; WATER GAS SHIFT;

ELECTROCHEMICAL REDUCTIONS; ENERGY STORAGE CAPACITY; ENVIRONMENTAL SCIENCE; HIGH DENSITY ENERGY; NOBLE METAL ALLOYS; REVERSE WATER GAS SHIFT; REVERSE WATER-GAS SHIFT REACTION; SYNGAS PRODUCTION;

CARBON DIOXIDE;

EID: 84979222082     PISSN: 09263373     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apcatb.2016.07.008     Document Type: Article

References (41)

1. [1] Graves, C., Ebbesen, S.D., Mogensen, M., Lackner, K.S., Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy. Renew. Sustainable Energy Rev. 15 (2011), 1–23.
2. [2] Bierschenk, D.M., Wilson, J.R., Barnett, S.A., High efficiency electrical energy storage using a methane-oxygen solid oxide cell. Energy Environ. Sci. 4 (2011), 944–951.
3. [3] Fu, Q., Mabilat, C., Zahid, M., Brisse, A., Gautier, L., Syngas production via high-temperature steam/CO2 co-electrolysis: an economic assessment. Energy Environ. Sci. 3 (2010), 1382–1397.
4. [4] O'Brien, J.E., McKellar, M.G., Harvego, E.A., Stoots, C.M., High-temperature electrolysis for large-scale hydrogen and syngas production from nuclear energy – summary of system simulation and economic analyses. Int. J. Hydrogen Energy 35 (2010), 4808–4819.
5. [5] Chen, L., Chen, F., Xia, C., Direct synthesis of methane from CO2-H2O co-electrolysis in tubular solid oxide electrolysis cells. Energy Environ. Sci. 7 (2014), 4018–4022.
6. [6] Yang, C., Li, J., Newkirk, J., Baish, V., Hu, R., Chen, Y., Chen, F., Co-electrolysis of H2O and CO2 in a solid oxide electrolysis cell with hierarchically structured porous electrodes. J. Mater. Chem. A 3 (2015), 15913–15919.
7. [7] Kim, S.-W., Kim, H., Yoon, K.J., Lee, J.-H., Kim, B.-K., Choi, W., Lee, J.-H., Hong, J., Reactions and mass transport in high temperature co-electrolysis of steam/CO2 mixtures for syngas production. J. Power Sources 280 (2015), 630–639.
8. [8] Graves, C., Ebbesen, S.D., Jensen, S.H., Simonsen, S.B., Mogensen, M.B., Eliminating degradation in solid oxide electrochemical cells by reversible operation. Nat. Mater. 14 (2015), 239–244.
9. [9] Ebbesen, S.D., Knibbe, R., Mogensen, M., Co-electrolysis of steam and carbon dioxide in solid oxide cells. J. Electrochem. Soc. 159 (2012), F482–F489.
10. [10] Graves, C., Ebbesen, S.D., Mogensen, M., Co-electrolysis of CO2 and H2O in solid oxide cells: performance and durability. Solid State Ionics 192 (2011), 398–403.
11. [11] Ebbesen, S.D., Høgh, J., Nielsen, K.A., Nielsen, J.U., Mogensen, M., Durable SOC stacks for production of hydrogen and synthesis gas by high temperature electrolysis. Int. J. Hydrogen Energy 36 (2011), 7363–7373.
12. [12] Jensen, S.H., Sun, X., Ebbesen, S.D., Knibbe, R., Mogensen, M., Hydrogen and synthetic fuel production using pressurized solid oxide electrolysis cells. Int. J. Hydrogen Energy 35 (2010), 9544–9549.
13. [13] Stoots, C.M., O'Brien, J.E., Herring, J.S., Hartvigsen, J.J., Syngas production via high-temperature coelectrolysis of steam and carbon dioxide. J. Fuel Cell Sci. Technol., 6, 2009.
14. [14] Stoots, C., O'Brien, J., Hartvigsen, J., Results of recent high temperature coelectrolysis studies at the Idaho National Laboratory. Int. J. Hydrogen Energy 34 (2009), 4208–4215.
15. [15] Takeguchi, T., Kikuchi, R., Yano, T., Eguchi, K., Murata, K., Effect of precious metal addition to Ni-YSZ cermet on reforming of CH4 and electrochemical activity as SOFC anode. Catal. Today 84 (2003), 217–222.
16. [16] Pekridis, G., Kalimeri, K., Kaklidis, N., Vakouftsi, E., Iliopoulou, E.F., Athanasiou, C., Marnellos, G.E., Study of the reverse water gas shift (RWGS) reaction over Pt in a solid oxide fuel cell (SOFC) operating under open and closed-circuit conditions. Catal. Today 127 (2007), 337–346.
17. [17] Jiang, S.P., Ye, Y., He, T., Ho, S.B., Nanostructured palladium–La0.75Sr0.25Cr0.5Mn0.5O3/Y2O3–ZrO2 composite anodes for direct methane and ethanol solid oxide fuel cells. J. Power Sources 185 (2008), 179–182.
18. [18] He, H.P., Wood, A., Steedman, D., Tilleman, M., Sulphur tolerant shift reaction catalysts for nickel-based SOFC anode. Solid State Ionics 179 (2008), 1478–1482.
19. [19] Gross, M.D., Vohs, J.M., Gorte, R.J., An examination of SOFC anode functional layers based on ceria in YSZ. J. Electrochem. Soc. 154 (2007), B694–B699.
20. [20] Nabae, Y., Yamanaka, I., Hatano, M., Otsuka, K., Catalytic behavior of Pd-Ni/composite anode for direct oxidation of methane in SOFCs. J. Electrochem. Soc. 153 (2006), A140–A145.
21. [21] Nabae, Y., Yamanaka, I., Hatano, M., Otsuka, K., Mechanism of suppression of carbon deposition on the Pd-Ni/Ce(Sm)O2-La(Sr)CrO3 anode in dry CH4 fuel. J. Phys. Chem. C 112 (2008), 10308–10315.
22. [22] Chen, L., Guo, H., Fujita, T., Hirata, A., Zhang, W., Inoue, A., Chen, M., Nanoporous PdNi bimetallic catalyst with enhanced electrocatalytic performances for electro-oxidation and oxygen reduction reactions. Adv. Funct. Mater. 21 (2011), 4364–4370.
23. [23] Coq, B., Figueras, F., Bimetallic palladium catalysts: influence of the co-metal on the catalyst performance. J. Mol. Catal. A: Chem. 173 (2001), 117–134.
24. [24] Mukainakano, Y., Li, B., Kado, S., Miyazawa, T., Okumura, K., Miyao, T., Naito, S., Kunimori, K., Tomishige, K., Surface modification of Ni catalysts with trace Pd and Rh for oxidative steam reforming of methane. Appl. Cata. A: Gen. 318 (2007), 252–264.
25. [25] Hermann, P., Guigner, J.M., Tardy, B., Jugnet, Y., Simon, D., Bertolini, J.C., The Pd/Ni(110) bimetallic system: surface characterisation by LEED, AES, XPS, and LEIS techniques; new insight on catalytic properties. J. Catal. 163 (1996), 169–175.
26. [26] Daza, Y.A., Kuhn, J.N., CO2 conversion by reverse water gas shift catalysis: comparison of catalysts, mechanisms and their consequences for CO2 conversion to liquid fuels. RSC Adv. 6 (2016), 49675–49705.
27. [27] Ko, J., Kim, B.-K., Han, J.W., Density functional theory study for catalytic activation and dissociation of CO2 on bimetallic alloy surfaces. J. Phys. Chem. C 120 (2016), 3438–3447.
28. [28] Lee, S.I., Kim, J., Son, J.W., Lee, J.H., Kim, B.K., Je, H.J., Lee, H.W., Song, H., Yoon, K.J., High performance air electrode for solid oxide regenerative fuel cells fabricated by infiltration of nano-catalysts. J. Power Sources 250 (2014), 15–20.
29. [29] Lee, J.-H., Kim, H., Kim, S.M., Noh, T.-W., Jung, H.-Y., Lim, H.-Y., Jung, H.-G., Son, J.-W., Kim, H.-R., Kim, B.-K., Je, H.-J., Lee, J.-C., Song, H., Lee, H.-W., Effect of elastic network of ceramic fillers on thermal cycle stability of a solid oxide fuel cell stack. Adv. Energy Mater. 2 (2012), 461–468.
30. [30] Jiang, S.P., Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: advances and challenges. Int. J. Hydrogen Energy 37 (2012), 449–470.
31. [31] Jung, S., Lu, C., He, H., Ahn, K., Gorte, R.J., Vohs, J.M., Influence of composition and Cu impregnation method on the performance of Cu/CeO2/YSZ SOFC anodes. J. Power Sources 154 (2006), 42–50.
32. [32] Babaei, A., Jiang, S.P., Li, J., Electrocatalytic promotion of palladium nanoparticles on hydrogen oxidation on Ni/GDC anodes of SOFCs via spillover. J. Electrochem. Soc. 156 (2009), B1022–B1029.
33. [33] Li, W.Y., Lu, Z., Zhu, X.B., Guan, B., Wei, B., Guan, C.Z., Su, W.H., Effect of adding urea on performance of Cu/CeO2/yttria-stabilized zirconia anodes for solid oxide fuel cells prepared by impregnation method. Electrochim. Acta 56 (2011), 2230–2236.
34. [34] Sordelet, D., Akinc, M., Preparation of spherical, monosized Y2O3 precursor particles. J. Colloid Interface Sci. 122 (1988), 47–59.
35. [35] Murr, L.E., Interfacial Phenomena in Metals and Alloys. 1975, Addison-Wesley Publishing Co., Reading, Massachusetts.
36. [36] Ghosh, G., Kantner, C., Olson, G.B., Thermodynamic modeling of the Pd-X (X = Ag, Co Fe, Ni) systems. JPE 20 (1999), 295–308.
37. [37] Irvine, J.T.S., Neagu, D., Verbraeken, M.C., Chatzichristodoulou, C., Graves, C., Mogensen, M.B., Evolution of the electrochemical interface in high-temperature fuel cells and electrolysers. Nat. Energy, 1, 2016, 15014.
38. [38] Hanna, J., Lee, W.Y., Shi, Y., Ghoniem, A.F., Fundamentals of electro- and thermochemistry in the anode of solid-oxide fuel cells with hydrocarbon and syngas fuels. Prog. Energy Combust. Sci. 40 (2014), 74–111.
39. [39] Lee, S., Kim, H., Yoon, K.J., Son, J.-W., Lee, J.-H., Kim, B.-K., Choi, W., Hong, J., The effect of fuel utilization on heat and mass transfer within solid oxide fuel cells examined by three-dimensional numerical simulations. Int. J. Heat Mass Transfer 97 (2016), 77–93.
40. [40] Hammer, B., Nørskov, J.K., Theoretical surface science and catalysis—calculations and concepts. Advances in Catalysis, 2000, Academic Press, 71–129.
41. [41] Wang, J.X., Markovic, N.M., Adzic, R.R., Kinetic analysis of oxygen reduction on Pt(111) in acid solutions: intrinsic kinetic parameters and anion adsorption effects. J. Phys. Chem. B 108 (2004), 4127–4133.