Mn3O4@CoMn2O4-CoxOy Nanoparticles: Partial Cation Exchange Synthesis and Electrocatalytic Properties toward the Oxygen Reduction and Evolution Reactions

ACS Applied Materials and Interfaces

Volumn 8, Issue 27, 2016, Pages 17435-17444

  Luo, Zhishan ^a   Irtem, Erdem ^a   Ibánez, Maria ^a   Nafria, Raquel ^a   Martĺ Sánchez, Sara ^c   Genç, Aziz ^c   De La Mata, Maria ^c   Liu, Yu ^a   Cadavid, Doris ^a   Llorca, Jordi ^b   Arbiol, Jordi ^c,e   Andreu, Teresa ^a   Morante, Joan Ramon ^a,d   Cabot, Andreu ^a,e  

^a CATALONIA INSTITUTE FOR ENERGY RESEARCH IREC   (Spain)

^b UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

^c CSIC   (Spain)

^d UNIVERSITY OF BARCELONA   (Spain)

^e INSTITUCIÓ CATALANA DE RECERCA I ESTUDIS AVANÇATS ICREA   (Spain)

Author keywords

cation exchange; cobalt oxide; colloidal; electrocatalysis; manganese oxide; nanoparticle; OER; ORR

Indexed keywords

COBALT; ELECTROCATALYSIS; ELECTROLYTIC REDUCTION; MANGANESE OXIDE; NANOPARTICLES; OXYGEN; POSITIVE IONS; SYNTHESIS (CHEMICAL); TEMPERATURE; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

BIFUNCTIONAL OXYGEN CATALYSTS; CATION EXCHANGES; COBALT OXIDES; COLLOIDAL; ELECTROCATALYTIC PROPERTIES; NON-PRECIOUS METALS; OXYGEN REDUCTION AND EVOLUTION REACTIONS; TRANSITION-METAL OXIDES;

MANGANESE;

EID: 84978916730     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/acsami.6b02786     Document Type: Article

References (63)

1. Kraytsberg, A.; Ein-Eli, Y. The Impact of Nano-Scaled Materials on Advanced Metal-air Battery Systems Nano Energy 2013, 2, 468-480 10.1016/j.nanoen.2012.11.016
2. He, Q.; Cairns, E. J. Review-Recent Progress in Electrocatalysts for Oxygen Reduction Suitable for Alkaline Anion Exchange Membrane Fuel Cells J. Electrochem. Soc. 2015, 162, F1504-F1539 10.1149/2.0551514jes
3. Yang, Z.; Nie, H.; Chen, X.; Chen, X.; Huang, S. Recent Progress in Doped Carbon Nanomaterials as Effective Cathode Catalysts for Fuel Cell Oxygen Reduction Reaction J. Power Sources 2013, 236, 238-249 10.1016/j.jpowsour.2013.02.057
4. Cheng, F.; Chen, J. Metal-Air Batteries: From Oxygen Reduction Electrochemistry to Cathode Catalysts Chem. Soc. Rev. 2012, 41, 2172-2192 10.1039/c1cs15228a
5. Neburchilov, V.; Wang, H.; Martin, J. J.; Qu, W. A Review on Air Cathodes for Zinc-air Fuel Cells J. Power Sources 2010, 195, 1271-1291 10.1016/j.jpowsour.2009.08.100
6. Jaouen, F.; Proietti, E.; Lefèvre, M.; Chenitz, R.; Dodelet, J.-P.; Wu, G.; Chung, H. T.; Johnston, C. M.; Zelenay, P. Recent Advances in Non-Precious Metal Catalysis for Oxygen-Reduction Reaction in Polymer Electrolyte Fuelcells Energy Environ. Sci. 2011, 4, 114-130 10.1039/C0EE00011F
7. 4 (M = Fe, Cu, Co, Mn) Nanoparticles and Their Electrocatalysis for Oxygen Reduction Reaction Nano Lett. 2013, 13, 2947-2951 10.1021/nl401325u
8. 4 Nanocrystals on Graphene as a Synergistic Catalyst for Oxygen Reduction Reaction Nat. Mater. 2011, 10, 780-786 10.1038/nmat3087
9. Cheng, F.; Shen, J.; Peng, B.; Pan, Y.; Tao, Z.; Chen, J. Rapid Room-Temperature Synthesis of Nanocrystalline Spinels as Oxygen Reduction and Evolution Electrocatalysts Nat. Chem. 2011, 3, 79-84 10.1038/nchem.931
10. Zhao, A.; Masa, J.; Xia, W.; Maljusch, A.; Willinger, M.-G.; Clavel, G.; Xie, K.; Schlögl, R.; Schuhmann, W.; Muhler, M. Spinel Mn-Co Oxide in N-Doped Carbon Nanotubes as a Bifunctional Electrocatalyst Synthesized by Oxidative Cutting J. Am. Chem. Soc. 2014, 136, 7551-7554 10.1021/ja502532y
11. Li, J.; Wang, Y.; Zhou, T.; Zhang, H.; Sun, X.; Tang, J.; Zhang, L.; Al-Enizi, A. M.; Yang, Z.; Zheng, G. Nanoparticle Superlattices as Efficient Bifunctional Electrocatalysts for Water Splitting J. Am. Chem. Soc. 2015, 137, 14305-14312 10.1021/jacs.5b07756
12. Indra, A.; Menezes, P. W.; Driess, M. Uncovering Structure-Activity Relationships in Manganese-Oxide-Based Heterogeneous Catalysts for Efficient Water Oxidation ChemSusChem 2015, 8, 776-785 10.1002/cssc.201402812
13. Chen, D.; Chen, C.; Baiyee, Z. M.; Shao, Z.; Ciucci, F. Nonstoichiometric Oxides as Low-Cost and Highly-Efficient Oxygen Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices Chem. Rev. 2015, 115, 9869-9921 10.1021/acs.chemrev.5b00073
14. Li, C.; Han, X.; Cheng, F.; Hu, Y.; Chen, C.; Chen, J. Phase and Composition Controllable Synthesis of Cobalt Manganese Spinel Nanoparticles towards Efficient Oxygen Electrocatalysis Nat. Commun. 2015, 6, 7345 10.1038/ncomms8345
15. Cheng, F.; Shen, J.; Ji, W.; Tao, Z.; Chen, J. Selective Synthesis of Manganese Oxide Nanostructures for Electrocatalytic Oxygen Reduction ACS Appl. Mater. Interfaces 2009, 1, 460-466 10.1021/am800131v
16. 2 Nanostructures: Highly Efficient, Ultra-Stable Electrochemical Water Oxidation and Oxygen Reduction Reaction Catalysts Identified in Alkaline Media J. Am. Chem. Soc. 2014, 136, 11452-11464 10.1021/ja505186m
17. 4 Nanoparticles on Nitrogen-Doped Graphene for Enhanced Oxygen Reduction Activity Adv. Funct. Mater. 2014, 24, 2072-2078 10.1002/adfm.201302940
18. Wu, G.; Zelenay, P. Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction Acc. Chem. Res. 2013, 46, 1878-1889 10.1021/ar400011z
19. Kuo, C.-H.; Mosa, I. M.; Thanneeru, S.; Sharma, V.; Zhang, L.; Biswas, S.; Aindow, M.; Pamir Alpay, S.; Rusling, J. F.; Suib, S. L. et al. Facet-Dependent Catalytic Activity of MnO Electrocatalysts for Oxygen Reduction and Oxygen Evolution Reactions Chem. Commun. 2015, 51, 5951-5954 10.1039/C5CC01152C
20. Zhang, K.; Han, X.; Hu, Z.; Zhang, X.; Tao, Z.; Chen, J. Nanostructured Mn-Based Oxides for Electrochemical Energy Storage and Conversion Chem. Soc. Rev. 2015, 44, 699-728 10.1039/C4CS00218K
21. Huynh, M.; Shi, C.; Billinge, S. J. L.; Nocera, D. G. Nature of Activated Manganese Oxide for Oxygen Evolution J. Am. Chem. Soc. 2015, 137, 14887-14904 10.1021/jacs.5b06382
22. 4 Nanocomposites as a Synergistic Bifunctional Catalyst for Oxygen Reduction and Oxygen Evolution Reactions Nanoscale 2013, 5, 5312-5315 10.1039/c3nr00444a
23. Deng, X.; Tüysüz, H. Cobalt-Oxide-Based Materials as Water Oxidation Catalyst: Recent Progress and Challenges ACS Catal. 2014, 4, 3701-3714 10.1021/cs500713d
24. 4 on Its Catalytic Activity for Water Oxidation Chem. Mater. 2014, 26, 6127-6134 10.1021/cm5023163
25. Jin, H.; Wang, J.; Su, D.; Wei, Z.; Pang, Z.; Wang, Y. In Situ Cobalt-Cobalt oxide/N-Doped Carbon Hybrids as Superior Bifunctional Electrocatalysts for Hydrogen and Oxygen Evolution J. Am. Chem. Soc. 2015, 137, 2688-2694 10.1021/ja5127165
26. Menezes, P. W.; Indra, A.; González-Flores, D.; Sahraie, N. R.; Zaharieva, I.; Schwarze, M.; Strasser, P.; Dau, H.; Driess, M. High-Performance Oxygen Redox Catalysis with Multifunctional Cobalt Oxide Nanochains: Morphology-Dependent Activity ACS Catal. 2015, 5, 2017-2027 10.1021/cs501724v
27. Lu, X.; Chan, H. M.; Sun, C.-L.; Tseng, C.-M.; Zhao, C. Interconnected Core-shell Carbon Nanotube-graphene Nanoribbon Scaffolds for Anchoring Cobalt Oxides as Bifunctional Electrocatalysts for Oxygen Evolution and Reduction J. Mater. Chem. A 2015, 3, 13371-13376 10.1039/C5TA02967H
28. Maiyalagan, T.; Jarvis, K. A.; Therese, S.; Ferreira, P. J.; Manthiram, A. Spinel-Type Lithium Cobalt Oxide as a Bifunctional Electrocatalyst for the Oxygen Evolution and Oxygen Reduction Reactions Nat. Commun. 2014, 5, 3949 10.1038/ncomms4949
29. Su, Y.; Zhu, Y.; Jiang, H.; Shen, J.; Yang, X.; Zou, W.; Chen, J.; Li, C. Cobalt Nanoparticles Embedded in N-Doped Carbon as an Efficient Bifunctional Electrocatalyst for Oxygen Reduction and Evolution Reactions Nanoscale 2014, 6, 15080-15089 10.1039/C4NR04357J
30. 4 Nanoparticles Decorated Carbon Nanofiber Mat as Binder-Free Air-Cathode for High Performance Rechargeable Zinc-Air Batteries Nanoscale 2015, 7, 1830-1838 10.1039/C4NR05988C
31. Li, C.-S.; Melaet, G.; Ralston, W. T.; An, K.; Brooks, C.; Ye, Y.; Liu, Y.-S.; Zhu, J.; Guo, J.; Alayoglu, S. et al. High-Performance Hybrid Oxide Catalyst of Manganese and Cobalt for Low-Pressure Methanol Synthesis Nat. Commun. 2015, 6, 6538 10.1038/ncomms7538
32. Dang, F.; Oaki, Y.; Kokubu, T.; Hosono, E.; Zhou, H.; Imai, H. Formation of Nanostructured MnO/Co/solid-Electrolyte Interphase Ternary Composites as a Durable Anode Material for Lithium-Ion Batteries Chem.-Asian J. 2013, 8, 760-764 10.1002/asia.201201109
33. x Binary Oxides for CO, CH4 and VOC Oxidation at Low Temperatures: A Review Catal. Sci. Technol. 2013, 3, 3085 10.1039/c3cy00193h
34. 2 Nanoparticles in Heterogeneous Activation of Peroxymonosulfate for Phenol Degradation in Aqueous Solutions Appl. Catal., B 2012, 127, 330-335 10.1016/j.apcatb.2012.09.001
35. Liang, Y.; Wang, H.; Zhou, J.; Li, Y.; Wang, J.; Regier, T.; Dai, H. Covalent Hybrid of Spinel Manganese-Cobalt Oxide and Graphene as Advanced Oxygen Reduction Electrocatalysts J. Am. Chem. Soc. 2012, 134, 3517-3523 10.1021/ja210924t
36. 4 as Cathode Catalyst for Oxygen Reduction Reaction in Alkaline Media Int. J. Hydrogen Energy 2013, 38, 13611-13616 10.1016/j.ijhydene.2013.08.048
37. 4-CoO Core-shell Spheres Wrapped by Carbon Nanotubes: A High Performance Catalyst for the Oxygen Reduction Reaction and CO Oxidation J. Mater. Chem. A 2014, 2, 3794-3800 10.1039/c3ta14453d
38. Xu, Y.; Jiang, H.; Li, X.; Xiao, H.; Xiao, W.; Wu, T. Synthesis and Characterization of Mn-Based Composite Oxides with Enhanced Electrocatalytic Activity for Oxygen Reduction J. Mater. Chem. A 2014, 2, 13345-13351 10.1039/C4TA02544J
39. Menezes, P. W.; Indra, A.; Sahraie, N. R.; Bergmann, A.; Strasser, P.; Driess, M. Cobalt-Manganese-Based Spinels as Multifunctional Materials That Unify Catalytic Water Oxidation and Oxygen Reduction Reactions ChemSusChem 2015, 8, 164-171 10.1002/cssc.201402699
40. 4 Composites for Zinc-Air Batteries Int. J. Electrochem. Sci. 2015, 10, 10554-10564
41. 2 Electrocatalysts from Layered Double Hydroxides for Oxygen Reduction Reaction Electrochim. Acta 2015, 173, 575-580 10.1016/j.electacta.2015.05.095
42. 4 Nanodots Supported on Graphene Inorg. Chem. 2015, 54, 5467-5474 10.1021/acs.inorgchem.5b00518
43. 4/nanocarbon Hybrids for Electrocatalytic Oxygen Reduction and Evolution ACS Appl. Mater. Interfaces 2014, 6, 12684-12691 10.1021/am502675c
44. 4 Nanocrystals Synthesized at Low Temperature in Air Atmosphere Chem. Mater. 2009, 21, 2272-2279 10.1021/cm900431b
45. Li, Y.; Zhou, W.; Wang, H.; Xie, L.; Liang, Y.; Wei, F.; Idrobo, J.-C.; Pennycook, S. J.; Dai, H. An Oxygen Reduction Electrocatalyst Based on Carbon Nanotube-graphene Complexes Nat. Nanotechnol. 2012, 7, 394-400 10.1038/nnano.2012.72
46. 4 (A = Co, Ni, Cu) Spinels for Remediation of Volatile Organic Compounds-synthesis, Characterization and Catalytic Performance Ceram. Int. 2012, 38, 1655-1661 10.1016/j.ceramint.2011.09.057
47. 4 Nano-Powders and Catalytic Activity in the 2-Propanol and Toluene Combustion: Effect of the Preparation Method J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng. 2011, 46, 291-297 10.1080/10934529.2011.539093
48. Sexton, B. A.; Hughes, A. E.; Turney, T. W. An XPS and TPR Study of the Reduction of Promoted Cobalt-Kieselguhr Fischer-Tropsch Catalysts J. Catal. 1986, 97, 390-406 10.1016/0021-9517(86)90011-4
49. 3 Catalysts J. Catal. 1985, 93, 38-54 10.1016/0021-9517(85)90149-6
50. Brown, R.; Cooper, M. E.; Whan, D. A. Temperature Programmed Reduction of Alumina-Supported Iron, Cobalt and Nickel Bimetallic Catalysts Appl. Catal. 1982, 3, 177-186 10.1016/0166-9834(82)80090-0
51. Lin, H. Y.; Chen, Y. W. The Mechanism of Reduction of Cobalt by Hydrogen Mater. Chem. Phys. 2004, 85, 171-175 10.1016/j.matchemphys.2003.12.028
52. Sytnyk, M.; Kirchschlager, R.; Bodnarchuk, M. I.; Primetzhofer, D.; Kriegner, D.; Enser, H.; Stangl, J.; Bauer, P.; Voith, M.; Hassel, A. et al. Tuning the Magnetic Properties of Metal-Oxide Nanocrystal Heterostructures by Cation Exchange Nano Lett. 2013, 13, 586-593 10.1021/nl304115r
53. Gutmann, V. Coordination Chemistry in Non-Aqueous Solutions; Springer Vienna: Vienna, 1968.
54. Trutia, A. Optical Spectra of Divalent Cobalt Complexes J. Optoelectron. Adv. Mater. 2005, 7, 2677-2686
55. Fine, A. Halide Complexes of Cobalt (II) in Acetone Solution J. Am. Chem. Soc. 1962, 84, 1139-1144 10.1021/ja00866a016
56. Shinagawa, T.; Garcia-Esparza, A. T.; Takanabe, K. Insight on Tafel Slopes from a Microkinetic Analysis of Aqueous Electrocatalysis for Energy Conversion Sci. Rep. 2015, 5, 13801 10.1038/srep13801
57. Roche, I.; Chaînet, E.; Chatenet, M.; Vondrák, J. Carbon-Supported Manganese Oxide Nanoparticles as Electrocatalysts for the Oxygen Reduction Reaction (ORR) in Alkaline Medium: Physical Characterizations and ORR Mechanism J. Phys. Chem. C 2007, 111, 1434-1443 10.1021/jp0647986
58. Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2 nd ed.; Wiley: New York, 2001.
59. Chatenet, M.; Aurousseau, M.; Durand, R.; Andolfatto, F. Silver-Platinum Bimetallic Catalysts for Oxygen Cathodes in Chlor-Alkali Electrolysis: Comparison with Pure Platinum J. Electrochem. Soc. 2003, 150, D47-D55 10.1149/1.1540063
60. Chatenet, M.; Genies-Bultel, L.; Aurousseau, M.; Durand, R.; Andolfatto, F. Oxygen Reduction on Silver Catalysts in Solutions Containing Various Concentrations of Sodium Hydroxide-Comparison with Platinum J. Appl. Electrochem. 2002, 32, 1131-1140 10.1023/A:1021231503922
61. Cherevko, S.; Zeradjanin, A. R.; Keeley, G. P.; Mayrhofer, K. J. J. A Comparative Study on Gold and Platinum Dissolution in Acidic and Alkaline Media J. Electrochem. Soc. 2014, 161, H822-H830 10.1149/2.0881412jes
62. Gong, M.; Li, Y.; Wang, H.; Liang, Y.; Wu, J. Z.; Zhou, J.; Wang, J.; Regier, T.; Wei, F.; Dai, H. An Advanced Ni-Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation J. Am. Chem. Soc. 2013, 135, 8452-8455 10.1021/ja4027715
63. Smith, R. D. L.; Prévot, M. S.; Fagan, R. D.; Zhang, Z.; Sedach, P. A.; Siu, M. K. J.; Trudel, S.; Berlinguette, C. P. Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis Science 2013, 340, 60-63 10.1126/science.1233638