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Volumn , Issue , 2016, Pages 3381-3387

Carbon-Rich Active Materials with Macrocyclic Nanochannels for High-Capacity Negative Electrodes in All-Solid-State Lithium Rechargeable Batteries

Author keywords

lithium batteries; macrocylic molecules; negative electrode materials; X ray diffraction

Indexed keywords

AROMATIC HYDROCARBONS; CARBON; ELECTRIC BATTERIES; ELECTRODES; ELECTROLYTES; LITHIUM; LITHIUM BATTERIES; SECONDARY BATTERIES; X RAY DIFFRACTION;

EID: 84977559858     PISSN: 16136810     EISSN: 16136829     Source Type: Journal    
DOI: 10.1002/smll.201600916     Document Type: Article
Times cited : (26)

References (71)
  • 12
    • 84977493382 scopus 로고    scopus 로고
    • in, 2nd ed., (Eds, L. A. Paquette, D. Crich, P. L. Fuchs, G. A. Molander, Wiley, Chichester, UK
    • L. Banfi, E. Narisano, in Encyclopedia of Reagents for Organic Synthesis, 2nd ed., Vol. 8 (Eds: L. A. Paquette, D. Crich, P. L. Fuchs, G. A. Molander), Wiley, Chichester, UK 2009, pp. 6097-2013;6104.
    • (2009) Encyclopedia of Reagents for Organic Synthesis , vol.8 , pp. 6097-6104
    • Banfi, L.1    Narisano, E.2
  • 30
    • 85043116123 scopus 로고    scopus 로고
    • The Coulombic efficiency for the initial three cycles at 727 mA h g, were not high (Figure S1, Supporting Information). We believe that Li-migration pathways and conduction interfaces are being formed in the composite during this process, as is often the case with battery electrodes. For similar observations, see refs. [10], [13][14]. Note that tackling interfacial issues is both tedious and complex. For instance, the composition and nature of interfaces of conventional lithium batteries are still the subject of much controversy, partly because the solid electrolyte interphase forms on Li or carbonaceous materials (ref. [1])
    • -2013;1 were not high (Figure S1, Supporting Information). We believe that Li-migration pathways and conduction interfaces are being formed in the composite during this process, as is often the case with battery electrodes. For similar observations, see refs. [10], [13], and [14]. Note that tackling interfacial issues is both tedious and complex. For instance, the composition and nature of interfaces of conventional lithium batteries are still the subject of much controversy, partly because the solid electrolyte interphase forms on Li or carbonaceous materials (ref. [1]).
  • 31
    • 85043119889 scopus 로고    scopus 로고
    • When we analyzed the discharge-2013;charge process at a higher charging rate of 850 mA g, the specific capacity was 14 mA h g, Further extensive studies on the optimum conditions including the charging rate are necessary for practical applications in the future
    • -2013;1. Further extensive studies on the optimum conditions including the charging rate are necessary for practical applications in the future.
  • 32
    • 85043118291 scopus 로고    scopus 로고
    • A decay in the capacity was 99.96% from 30th to 65th cycles, which may indicate, for instance, 560 mA h g, (90% of 624 mA h g,) at 300 cycles. Further evaluation of extensive cycles is important for practical applications and will be studied in the future
    • -2013;1) at 300 cycles. Further evaluation of extensive cycles is important for practical applications and will be studied in the future.
  • 33
    • 85043108066 scopus 로고    scopus 로고
    • An additional plateau was observed at -2248;0.8 V to indicate inferior recyclability in the applied voltage range of 0-2013;1.0 V (vs Li/Li,), which was in stark contrast to the stable recyclability observed in the voltage range of 0.2-2013;1.0 V (Figure S7, Supporting Information). We believe that an excess lithium insertion at low voltage of -003C;0.2 V hampered the stable discharge-2013;charge processes
    • +), which was in stark contrast to the stable recyclability observed in the voltage range of 0.2-2013;1.0 V (Figure S7, Supporting Information). We believe that an excess lithium insertion at low voltage of -003C;0.2 V hampered the stable discharge-2013;charge processes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.