Tuned Chemical Bonding Ability of Au at Grain Boundaries for Enhanced Electrochemical CO2 Reduction

ACS Catalysis

Volumn 6, Issue 7, 2016, Pages 4443-4448

  Kim, Kang Sahn ^a   Kim, Won June ^a   Lim, Hyung Kyu ^a   Lee, Eok Kyun ^a   Kim, Hyungjun ^a  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

Author keywords

Au surface; CO2 reduction; density functional theory; electrochemical reduction; grain boundary

Indexed keywords

CARBON; CATALYST ACTIVITY; CATALYST SELECTIVITY; CATALYSTS; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ELECTROLYTIC REDUCTION; GRAIN BOUNDARIES; METAL NANOPARTICLES; METALS; NANOPARTICLES; REDUCTION;

AU SURFACES; CATALYTIC APPLICATIONS; CATALYTIC PROPERTIES; ELECTROCHEMICAL REDUCTIONS; EMERGING TECHNOLOGIES; METASTABLE STRUCTURES; RATE DETERMINING STEP; STRUCTURE ACTIVITY RELATIONSHIPS;

CARBON DIOXIDE;

EID: 84977134534     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/acscatal.6b00412     Document Type: Article

References (37)

1. Olah, G. A.; Prakash, G. K. S.; Goeppert, A. J. Am. Chem. Soc. 2011, 133, 12881-12898 10.1021/ja202642y
2. Arakawa, H.; Aresta, M.; Armor, J. N.; Barteau, M. A.; Beckman, E. J.; Bell, A. T.; Bercaw, J. E.; Creutz, C.; Dinjus, E.; Dixon, D. A.; Domen, K.; DuBois, D. L.; Eckert, J.; Fujita, E.; Gibson, D. H.; Goddard, W. A.; Goodman, D. W.; Keller, J.; Kubas, G. J.; Kung, H. H.; Lyons, J. E.; Manzer, L. E.; Marks, T. J.; Morokuma, K.; Nicholas, K. M.; Periana, R.; Que, L.; Rostrup-Nielson, J.; Sachtler, W. M. H.; Schmidt, L. D.; Sen, A.; Somorjai, G. A.; Stair, P. C.; Stults, B. R.; Tumas, W. Chem. Rev. 2001, 101, 953-996 10.1021/cr000018s
3. Graves, C.; Ebbesen, S. D.; Mogensen, M.; Lackner, K. S. Renewable Sustainable Energy Rev. 2011, 15, 1-23 10.1016/j.rser.2010.07.014
4. Benson, E. E.; Kubiak, C. P.; Sathrum, A. J.; Smieja, J. M. Chem. Soc. Rev. 2009, 38, 89-99 10.1039/B804323J
5. Whipple, D. T.; Kenis, P. J. A. J. Phys. Chem. Lett. 2010, 1, 3451-3458 10.1021/jz1012627
6. Savéant, J. M. Chem. Rev. 2008, 108, 2348-2378 10.1021/cr068079z
7. Gattrell, M.; Gupta, N.; Co, A. J. Electroanal. Chem. 2006, 594, 1-19 10.1016/j.jelechem.2006.05.013
8. Elschenbroich, C.; Salzer, A. In Organometallics: a concise introduction, 2 nd ed.; VCH Publishers: Weinheim, 1992; p 1.
9. Verma, A.; Hirsch, D. J.; Glatt, C. E.; Ronnett, G. V.; Snyder, S. H. Science 1993, 259, 381-384 10.1126/science.7678352
10. Ionin, A. A.; Kinyaevskiy, I. O.; Klimachev, Y. M.; Kotkov, A. A.; Kozlov, A. Y.; Andreev, Y. M.; Lanskii, G. V.; Shaiduko, A. V.; Soluyanov, A. V. Opt. Lett. 2012, 37, 2838-2840 10.1364/OL.37.002838
11. Hori, Y.; Wakebe, H.; Tsukamoto, T.; Koga, O. Electrochim. Acta 1994, 39, 1833-1839 10.1016/0013-4686(94)85172-7
12. Chen, Y.; Li, C. W.; Kanan, M. W. J. Am. Chem. Soc. 2012, 134, 19969-19972 10.1021/ja309317u
13. Feng, X.; Jiang, K.; Fan, S.; Kanan, M. W. J. Am. Chem. Soc. 2015, 137, 4606-4609 10.1021/ja5130513
14. Gavrilov, A. N.; Savinova, E. R.; Simonov, P. A.; Zaikovskii, V. I.; Cherepanova, S. V.; Tsirlina, G. A.; Parmon, V. N. Phys. Chem. Chem. Phys. 2007, 9, 5476-5489 10.1039/b707598g
15. Wang, S.; Jiang, S. P.; White, T. J.; Guo, J.; Wang, X. J. Phys. Chem. C 2009, 113, 18935-18945 10.1021/jp906923z
16. Li, C. W.; Ciston, J.; Kanan, M. W. Nature 2014, 508, 504-507 10.1038/nature13249
17. Min, X.; Chen, Y.; Kanan, M. W. Phys. Chem. Chem. Phys. 2014, 16, 13601-13604 10.1039/c4cp01337a
18. Radetic, T.; Lançon, F.; Dahmen, U. Phys. Rev. Lett. 2002, 89, 085502 10.1103/PhysRevLett.89.085502
19. Vidruk, R.; Landau, M. V.; Herskowitz, M.; Talianker, M.; Frage, N.; Ezersky, V.; Froumin, N. J. Catal. 2009, 263, 196-204 10.1016/j.jcat.2009.02.014
20. Vidruk, R.; Landau, M. V.; Herskowitz, M.; Ezersky, V.; Goldbourt, A. J. Catal. 2011, 282, 215-227 10.1016/j.jcat.2011.06.018
21. Molotskii, M. I. Kinet. Catal. 1974, 15, 758-764
22. Tsybulya, S. V.; Kryukova, G. N.; Goncharova, S. N.; Shmakov, A. N.; Bal'zhinimaev, B. S. J. Catal. 1995, 154, 194-200 10.1006/jcat.1995.1160
23. Lim, H. K.; Shin, H.; Goddard, W. A.; Hwang, Y. J.; Min, B. K.; Kim, H. J. Am. Chem. Soc. 2014, 136, 11355-11361 10.1021/ja503782w
24. Lucadamo, G.; Medlin, D. L. Microsc. Microanal. 2002, 8, 1402CD-1403CD 10.1017/S1431927602103126
25. Ichinose, H.; Ishida, Y. J. Phys. Colloques 1985, 46, C4-39-C4-49 10.1051/jphyscol:1985403
26. Ichinose, H.; Ishida, Y.; Baba, N.; Kanaya, K. Philos. Mag. A 1985, 52, 51-59 10.1080/01418618508237605
27. Kobayashi, S.; Takagi, H.; Watanabe, T. Philos. Mag. 2013, 93, 1425-1442 10.1080/14786435.2012.756991
28. Soler, J. M.; Artacho, E.; Gale, J. D.; García, A.; Junquera, J.; Ordejón, P.; Sánchez-Portal, D. J. Phys.: Condens. Matter 2002, 14, 2745-2779 10.1088/0953-8984/14/11/302
29. Perdew, J. P.; Burke, K.; Ernzerhof, M. Phys. Rev. Lett. 1996, 77, 3865-3868 10.1103/PhysRevLett.77.3865
30. Rocchia, W.; Alexov, E.; Honig, B. J. Phys. Chem. B 2001, 105, 6507-6514 10.1021/jp010454y
31. Rocchia, W.; Sridharan, S.; Nicholls, A.; Alexov, E.; Chiabrera, A.; Honig, B. J. Comput. Chem. 2002, 23, 128-137 10.1002/jcc.1161
32. Hansen, H. A.; Varley, J. B.; Peterson, A. A.; Nørskov, J. K. J. Phys. Chem. Lett. 2013, 4, 388-392 10.1021/jz3021155
33. Keene, F. R. In Electrochemical and Electrocatalytic Reactions of Carbon Dioxide; Sullivan, B. P., Eds.; Elsevier: Amsterdam, 1993; p 1.
34. Hammer, B.; Nørskov, J. K. Surf. Sci. 1995, 343, 211-220 10.1016/0039-6028(96)80007-0
35. Dunnington, B. D.; Schmidt, J. R. J. Catal. 2015, 324, 50-58 10.1016/j.jcat.2015.01.017
36. Suntivich, J.; May, K. J.; Gasteiger, H. A.; Goodenough, J. B.; Shao-Horn, Y. Science 2011, 334, 1383-1385 10.1126/science.1212858
37. Vojvodic, A.; Nørskov, J. K. Science 2011, 334, 1355-1356 10.1126/science.1215081