Weak-Acid Sites Catalyze the Hydrolysis of Crystalline Cellulose to Glucose in Water: Importance of Post-Synthetic Functionalization of the Carbon Surface

Angewandte Chemie - International Edition

Volumn 54, Issue 38, 2015, Pages 11050-11053

  To, Anh The ^a   Chung, Po Wen ^a   Katz, Alexander ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

biofuels; carbon; cellulose depolymerization; glucan hydrolysis; heterogeneous catalysis

Indexed keywords

BIOFUELS; CARBON; CATALYSIS; CATALYSTS; GLUCOSE; HYDROLYSIS; NANOCRYSTALLINE MATERIALS;

ADSORPTION CAPACITIES; CATALYTIC HYDROLYSIS; CELLULOSE CRYSTALS; CRYSTALLINE CELLULOSE; FUNCTIONALIZATIONS; NANOPOROUS CARBONS; OVERALL EFFICIENCY; SITE CHARACTERISTICS;

CELLULOSE;

ACID; CARBON; CELLULOSE; GLUCOSE; WATER;

CATALYSIS; CHEMISTRY; CRYSTALLIZATION; HYDROLYSIS;

ACIDS; CARBON; CATALYSIS; CELLULOSE; CRYSTALLIZATION; GLUCOSE; HYDROLYSIS; WATER;

EID: 84973408754     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201504865     Document Type: Article

References (25)

1. C. E. Wyman, Annu. Rev. Energy Environment 1999, 24, 189–226.
2. E. Lam, J. H. T. Luong, ACS Catal. 2014, 4, 3393–3410.
3. J. R. Ziolkowska, Biotechnol. Rep. 2014, 4, 94–98.
4. A. Onda, T. Ochi, K. Yanagisawa, Green Chem. 2008, 10, 1033–1037.
5. S. Suganuma, K. Nakajima, M. Kitano, D. Yamaguchi, H. Kato, S. Hayashi, M. Hara, J. Am. Chem. Soc. 2008, 130, 12787–12793.
6. A. Onda, T. Ochi, K. Yanagisawa, Top. Catal. 2009, 52, 801–807.
7. J. Pang, A. Wang, M. Zheng, T. Zhang, Chem. Commun. 2010, 46, 6935–6937.
8. Z. Fang, F. Zhang, H. Y. Zeng, F. Guo, Bioresour. Technol. 2011, 102, 8017–8021.
9. H. Kobayashi, M. Yabushita, T. Komanoya, K. Hara, I. Fujita, A. Fukuoka, ACS Catal. 2013, 3, 581–587.
10. M. Yabushita, H. Kobayashi, K. Hara, A. Fukuoka, Catal. Sci. Technol. 2014, 4, 2312–2317.
11. X. Zhao, J. Wang, C. Chen, Y. Huang, A. Wang, T. Zhang, Chem. Commun. 2014, 50, 3439–3442.
12. P. V. Harris, F. Xu, N. E. Kreel, C. Kang, S. Fukuyama, Curr. Opin. Chem. Biol. 2014, 19, 162–170.
13. X. Meng, A. J. Ragauskas, Curr. Opin. Biotechnol. 2014, 27, 150–158.
14. A. Charmot, P. W. Chung, A. Katz, ACS Sustainable Chem. Eng. 2014, 2, 2866–2872.
15. P. W. Chung, A. Charmot, O. A. Olatunji-Ojo, K. A. Durkin, A. Katz, ACS Catal. 2014, 4, 302–310.
16. P. W. Chung, A. Charmot, O. M. Gazit, A. Katz, Langmuir 2012, 28, 15222–15232;
17. P.-W. Chung, A. Charmot, T. Click, Y. Lin, Y. Bae, J.-W. Chu, A. Katz, Langmuir 2015, 31, 7288-7295.
18. M. Yabushita, H. Kobayashi, J. Y. Hasegawa, K. Hara, A. Fukuoka, ChemSusChem 2014, 7, 1443–1450.
19. O. M. Gazit, A. Katz, J. Am. Chem. Soc. 2013, 135, 4398–4402.
20. Y. Otake, R. G. Jenkins, Carbon 1993, 31, 109–121.
21. P. Vinke, M. van der Eijk, M. Verbree, A. F. Voskamp, H. van Bekkum, Carbon 1994, 32, 675–686.
22. J. D. Bass, A. Solovyov, A. J. Pascall, A. Katz, J. Am. Chem. Soc. 2006, 128, 3737–3747.
23. B. Capon, Chem. Rev. 1969, 69, 407–498.
24. B. Capon, M. C. Smith, E. Anderson, R. H. Dahm, G. H. Sankey, J. Chem. Soc. B 1969, 1038–1047.
25. R. Rinaldi, N. Meine, J. vom Stein, R. Palkovits, F. Schüth, ChemSusChem 2010, 3, 266–276.