Atomically Dispersed Pd, Ni, and Pt Species in Ceria-Based Catalysts: Principal Differences in Stability and Reactivity

Journal of Physical Chemistry C

Volumn 120, Issue 18, 2016, Pages 9852-9862

  Neitzel, Armin ^a   Figueroba, Alberto ^b   Lykhach, Yaroslava ^a   Skála, Tomáš ^c   Vorokhta, Mykhailo ^c   Tsud, Nataliya ^c   Mehl, Sascha ^a   Ševčíková, Klára ^c   Prince, Kevin C ^d   Neyman, Konstantin M ^b,e   Matolín, Vladimír ^c   Libuda, Jörg ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b UNIVERSITY OF BARCELONA   (Spain)

^c CHARLES UNIVERSITY   (Czech Republic)

^d SINCROTRONE TRIESTE   (Italy)

^e INSTITUCIÓ CATALANA DE RECERCA I ESTUDIS AVANÇATS ICREA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; METALLIC COMPOUNDS; METALS; NICKEL; PHOTOELECTRON SPECTROSCOPY; PLATINUM; SYNCHROTRON RADIATION; THIN FILMS;

ADSORPTION ENERGIES; CERIA-BASED CATALYSTS; EXPERIMENTAL CONDITIONS; HYDROGEN ACTIVATION; LOW CONCENTRATIONS; RESONANT PHOTOEMISSION SPECTROSCOPY; SYNCHROTRON RADIATION PHOTOELECTRON SPECTROSCOPY; ULTRAHIGH VACUUM CONDITIONS;

PALLADIUM;

EID: 84971255027     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.6b02264     Document Type: Article

References (54)

1. Wang, Y.; Chen, K. S.; Mishler, J.; Cho, S. C.; Adroher, X. C. A Review of Polymer Electrolyte Membrane Fuel Cells: Technology, Applications, and Needs on Fundamental Research Appl. Energy 2011, 88, 981-1007 10.1016/j.apenergy.2010.09.030
2. Liu, H.; Song, C.; Zhang, L.; Zhang, J.; Wang, H.; Wilkinson, D. P. A Review of Anode Catalysis in the Direct Methanol Fuel Cell J. Power Sources 2006, 155, 95-110 10.1016/j.jpowsour.2006.01.030
3. Carrette, L.; Friedrich, K. A.; Stimming, U. Fuel Cells: Principles, Types, Fuels, and Applications ChemPhysChem 2000, 1, 162-193 10.1002/1439-7641(20001215)1:4<162::AID-CPHC162>3.3.CO;2-Q
4. Stamenkovic, V. R.; Mun, B. S.; Arenz, M.; Mayrhofer, K. J. J.; Lucas, C. A.; Wang, G. F.; Ross, P. N.; Markovic, N. M. Trends in Electrocatalysis on Extended and Nanoscale Pt-Bimetallic Alloy Surfaces Nat. Mater. 2007, 6, 241-247 10.1038/nmat1840
5. Tang, J. M.; Jensen, K.; Waje, M.; Li, W.; Larsen, P.; Pauley, K.; Chen, Z.; Ramesh, P.; Itkis, M. E.; Yan, Y. et al. High Performance Hydrogen Fuel Cells with Ultralow Pt Loading Carbon Nanotube Thin Film Catalysts J. Phys. Chem. C 2007, 111, 17901-17904 10.1021/jp071469k
6. Lefèvre, M.; Proietti, E.; Jaouen, F.; Dodelet, J.-P. Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells Science 2009, 324, 71-74 10.1126/science.1170051
7. x and Pt-Co Thin Film Catalysts J. Power Sources 2015, 273, 105-109 10.1016/j.jpowsour.2014.08.093
8. Bruix, A.; Lykhach, Y.; Matolínová, I.; Neitzel, A.; Skála, T.; Tsud, N.; Vorokhta, M.; Stetsovych, V.; Ševčiková, K.; Mysliveček, J. et al. Maximum Noble Metal Efficiency in Catalytic Materials: Atomically Dispersed Surface Platinum Angew. Chem., Int. Ed. 2014, 53, 10525-10530 10.1002/anie.201402342
9. 2 Nanocubes-Graphene Oxide as Durable and Highly Active Catalyst Support for Proton Exchange Membrane Fuel Cell Sci. Rep. 2014, 4, 7415 10.1038/srep07415
10. Aleksandrov, H. A.; Neyman, K. M.; Vayssilov, G. N. The Structure and Stability of Reduced and Oxidized Mononuclear Platinum Species on Nanostructured Ceria from Density Functional Modeling Phys. Chem. Chem. Phys. 2015, 17, 14551-14560 10.1039/C5CP01685A
11. 2 Novel Thin Film Catalyst as Anode for Proton Exchange Membrane Fuel Cells Appl. Catal., B 2016, 10.1016/j.apcatb.2016.02.036
12. Hegde, M. S.; Madras, G.; Patil, K. C. Noble Metal Ionic Catalysts Acc. Chem. Res. 2009, 42, 704-712 10.1021/ar800209s
13. 2â' (M = Pt or Pd, 0 ≤ x ≤ 0.10) Nanocrystallites: Redox Properties and Methanol Electro-Oxidation Activity Cryst. Growth Des. 2010, 10, 2995-3004 10.1021/cg1000649
14. 2-y Mixed Oxide in Oxidizing and Reducing Atmosphere: Reduction-Induced Activity in Low-Temperature CO Oxidation Appl. Catal., B 2012, 117-118, 135-147 10.1016/j.apcatb.2011.12.034
15. 2 by Combustion Method: Effect of Metal-Ceria Interaction on Catalytic Activities for NO Reduction and CO and Hydrocarbon Oxidation J. Catal. 2000, 196, 293-301 10.1006/jcat.2000.3048
16. 2: Substituted Ions versus Reduced Species Chem. Mater. 2011, 23, 5432-5439 10.1021/cm202709y
17. 2â' Catalysts Appl. Catal., B 2012, 119-120, 117-122 10.1016/j.apcatb.2012.02.036
18. 2-x-d Solid Solutions Phys. Chem. Chem. Phys. 2014, 16, 13523-13539 10.1039/c4cp01033g
19. x Composite Catalysts for Low-Temperature CO Oxidation, Prepared by Plasma-Arc Synthesis Appl. Catal., B 2014, 147, 132-143 10.1016/j.apcatb.2013.08.043
20. Boronin, A. I.; Slavinskaya, E. M.; Danilova, I. G.; Gulyaev, R. V.; Amosov, Y. I.; Kuznetsov, P. A.; Polukhina, I. A.; Koscheev, S. V.; Zaikovskii, V. I.; Noskov, A. S. Investigation of Palladium Interaction with Cerium Oxide and Its State in Catalysts for Low-Temperature CO Oxidation Catal. Today 2009, 144, 201-211 10.1016/j.cattod.2009.01.035
21. 2-y Oxides: Structural Characterization and Catalytic Activity for the Water Gas Shift Reaction J. Phys. Chem. C 2010, 114, 12689-12697 10.1021/jp103958u
22. Figueroba, A.; Kovacs, G.; Bruix, A.; Neyman, K. M. Towards Stable Single-Atom Catalysts: Strong Binding of Atomically Dispersed Transition Metals on the Surface of Nanostructured Ceria Catal. Sci. Technol. 2016, 10.1039/C6CY00294C
23. Perdew, J. P.; Chevary, J. A.; Vosko, S. H.; Jackson, K. A.; Pederson, M. R.; Singh, D. J.; Fiolhais, C. Atoms, Molecules, Solids, and Surfaces: Applications of the Generalized Gradient Approximation for Exchange and Correlation Phys. Rev. B: Condens. Matter Mater. Phys. 1992, 46, 6671-6687 10.1103/PhysRevB.46.6671
24. Kresse, G.; Furthmüller, J. Efficient Iterative Schemes for Ab Initio Total-Energy Calculations Using a Plane-Wave Basis Set Phys. Rev. B: Condens. Matter Mater. Phys. 1996, 54, 11169-11186 10.1103/PhysRevB.54.11169
25. Migani, A.; Vayssilov, G. N.; Bromley, S. T.; Illas, F.; Neyman, K. M. Greatly Facilitated Oxygen Vacancy Formation in Ceria Nanocrystallites Chem. Commun. 2010, 46, 5936-5938 10.1039/c0cc01091j
26. Paier, J.; Penschke, C.; Sauer, J. Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment Chem. Rev. 2013, 113, 3949-3985 10.1021/cr3004949
27. Anisimov, V. I.; Aryasetiawan, F.; Lichtenstein, A. I. First-Principles Calculations of the Electronic Structure and Spectra of Strongly Correlated Systems: The LDA+U Method J. Phys.: Condens. Matter 1997, 9, 767-808 10.1088/0953-8984/9/4/002
28. Blöchl, P. E. Projector Augmented-Wave Method Phys. Rev. B: Condens. Matter Mater. Phys. 1994, 50, 17953-17979 10.1103/PhysRevB.50.17953
29. Migani, A.; Vayssilov, G. N.; Bromley, S. T.; Illas, F.; Neyman, K. M. Dramatic Reduction of the Oxygen Vacancy Formation Energy in Ceria Particles: A Possible Key to Their Remarkable Reactivity at the Nanoscale J. Mater. Chem. 2010, 20, 10535-10546 10.1039/c0jm01908a
30. 2(111) Ultra-Thin Films on Cu(111) Thin Solid Films 2008, 516, 6120-6124 10.1016/j.tsf.2007.11.013
31. Matolin, V.; Matolinova, I.; Sedlacek, L.; Prince, K. C.; Skala, T. A Resonant Photoemission Applied to Cerium Oxide Based Nanocrystals Nanotechnology 2009, 20, 215706 10.1088/0957-4484/20/21/215706
32. Vayssilov, G. N.; Lykhach, Y.; Migani, A.; Staudt, T.; Petrova, G. P.; Tsud, N.; Skála, T.; Bruix, A.; Illas, F.; Prince, K. C. et al. Support Nanostructure Boosts Oxygen Transfer to Catalytically Active Platinum Nanoparticles Nat. Mater. 2011, 10, 310-315 10.1038/nmat2976
33. Lykhach, Y.; Kozlov, S. M.; Skála, T.; Tovt, A.; Stetsovych, V.; Tsud, N.; Dvořák, F.; Johánek, V.; Neitzel, A.; Mysliveček, J. et al. Counting Electrons on Supported Nanoparticles Nat. Mater. 2016, 15, 284-288 10.1038/nmat4500
34. Libra, J. KolXPD: Spectroscopy Data Measurement and Processing; http://www.kolibrik.net/science/kolxpd/ (accessed March 15, 2015).
35. Kittel, C. Introduction to Solid State Physics, 8 th ed.; Wiley: New York, 2004.
36. Hu, A. G.; Neyman, K. M.; Staufer, M.; Belling, T.; Gates, B. C.; Rösch, N. A Surface Site as Polydentate Ligand of a Metal Complex: Density Functional Studies of Rhenium Subcarbonyls Supported on Magnesium Oxide J. Am. Chem. Soc. 1999, 121, 4522-4523 10.1021/ja990083n
37. Nagano, Y. Standard Enthalpy of Formation of Platinum Hydrous Oxide J. Therm. Anal. Calorim. 2002, 69, 831-839 10.1023/A:1020651805170
38. Warner, J. S. The Free Energy of Formation of Palladium Oxide J. Electrochem. Soc. 1967, 114, 68-71 10.1149/1.2426509
39. Masterton, W. L.; Slowinski, E. J.; Stanitski, C. L. Chemical Principles, 6 th ed.; Saunders College Pub.: Philadelphia, PA, 1985; p 946.
40. 2 Fuel Cell Catalyst Phys. Chem. Chem. Phys. 2016, 18, 7672-7679 10.1039/C6CP00627B
41. 2 Mixed Oxide Catalysts Probed by CO Adsorption: A Synchrotron Radiation Photoelectron Spectroscopy Study Phys. Chem. Chem. Phys. 2014, 16, 24747-24754 10.1039/C4CP03346A
42. 2 Thin Film Catalysts Prepared by Magnetron Sputtering Langmuir 2010, 26, 12824-12831 10.1021/la100399t
43. 4+ Species: Spectroscopic and Structural Aspects, Thermal Stability, and Reactivity J. Phys. Chem. C 2012, 116, 19342-19348 10.1021/jp305166k
44. Ahrens, L. H. The Use of Ionization Potentials. Part 1. Ionic Radii of the Elements Geochim. Cosmochim. Acta 1952, 2, 155-169 10.1016/0016-7037(52)90004-5
45. Shannon, R. D.; Prewitt, C. T. Effective Ionic Radii in Oxides and Fluorides Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1969, B25, 925-946 10.1107/S0567740869003220
46. 2-x/Pt(111) J. Phys. Chem. C 2008, 112, 10918-10922 10.1021/jp8004103
47. van Veenendaal, M. A.; Sawatzky, G. A. Nonlocal Screening Effects in 2p X-Ray Photoemission Spectroscopy Core-Level Line Shapes of Transition Metal Compounds Phys. Rev. Lett. 1993, 70, 2459-2462 10.1103/PhysRevLett.70.2459
48. Sanz, J. M.; Tyuliev, G. T. An XPS Study of Thin NiO Films Deposited on MgO(100) Surf. Sci. 1996, 367, 196-202 10.1016/S0039-6028(96)00818-7
49. Preda, I.; Mossanek, R. J. O.; Abbate, M.; Alvarez, L.; Méndez, J.; Gutiérrez, A.; Soriano, L. Surface Contributions to the XPS Spectra of Nanostructured NiO Deposited on HOPG Surf. Sci. 2012, 606, 1426-1430 10.1016/j.susc.2012.05.005
50. Lykhach, Y.; Johánek, V.; Aleksandrov, H.; Kozlov, S. M.; Happel, M.; Skála, T.; Petkov, P. S.; Tsud, N.; Vayssilov, G. N.; Prince, K. C. et al. Water Chemistry on Model Ceria and Pt/Ceria Catalysts J. Phys. Chem. C 2012, 116, 12103-12113 10.1021/jp302229x
51. Miller, D. J.; Öberg, H.; Kaya, S.; Sanchez Casalongue, H.; Friebel, D.; Anniyev, T.; Ogasawara, H.; Bluhm, H.; Pettersson, L. G. M.; Nilsson, A. Oxidation of Pt(111) under Near-Ambient Conditions Phys. Rev. Lett. 2011, 107, 195502 10.1103/PhysRevLett.107.195502
52. Hatanaka, M.; Takahashi, N.; Takahashi, N.; Tanabe, T.; Nagai, Y.; Suda, A.; Shinjoh, H. Reversible Changes in the Pt Oxidation State and Nanostructure on a Ceria-Based Supported Pt J. Catal. 2009, 266, 182-190 10.1016/j.jcat.2009.06.005
53. Wu, T.; Pan, X.; Zhang, Y.; Miao, Z.; Zhang, B.; Li, J.; Yang, X. Investigation of the Redispersion of Pt Nanoparticles on Polyhedral Ceria Nanoparticles J. Phys. Chem. Lett. 2014, 5, 2479-2483 10.1021/jz500839u
54. Kim, K. S.; Winograd, N. X-Ray Photoelectron Spectroscopic Studies of Nickel-Oxygen Surfaces Using Oxygen and Argon Ion-Bombardment Surf. Sci. 1974, 43, 625-643 10.1016/0039-6028(74)90281-7