Cu-Mg-Al hydrotalcite-like materials as precursors of effective catalysts for selective oxidation of ammonia to dinitrogen — The influence of Mg/Al ratio and calcination temperature

Applied Clay Science

Volumn 129, Issue , 2016, Pages 122-130

  Basąg, Sylwia ^a   Piwowarska, Zofia ^a   Kowalczyk, Andrzej ^a   Węgrzyn, Agnieszka ^a   Baran, Rafał ^b   Gil, Barbara ^a   Michalik, Marek ^a   Chmielarz, Lucjan ^a  

^a JAGIELLONIAN UNIVERSITY   (Poland)

^b AGH UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Poland)

Author keywords

Copper; Hydrotalcite like materials; Mixed metal oxides; NH3 SCO

Indexed keywords

AMMONIA; CALCINATION; CATALYST SELECTIVITY; CATALYSTS; COPPER; OXIDATION;

CALCINATION TEMPERATURE; COPRECIPITATION METHOD; HIGH TEMPERATURE RANGE; HYDROTALCITE-LIKE MATERIALS; MIXED METAL OXIDE; NH3-SCO; SELECTIVE OXIDATION; SYNTHESIS PARAMETERS;

ALUMINUM;

EID: 84970024731     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2016.05.019     Document Type: Article

References (33)

1. Alejandre, A., Medina, F., Rodriguez, X., Salagre, P., Sueiras, J.E., Preparation and study of Cu-Al mixed oxides via hydrotalcite-like precursors. J. Catal. 188 (1999), 311–324.
2. Amores, J.M.G., Escribano, V.S., Ramis, G., Busca, G., An FT-IR study of ammonia adsorption and oxidation over anatase-supported metal oxides. Appl. Catal. B 13 (1997), 45–58.
3. Cavani, F., Trifiro, F., Vaccari, A., Hydrotalcite-type anionic clays: preparation, properties and applications. Catal. Today 11 (1991), 173–301.
4. Chmielarz, L., Jabłońska, M., Advances in selective catalytic oxidation of ammonia to dinitrogen: a review. RSC Adv. 54 (2015), 43408–43431.
5. Chmielarz, L., Jabłońska, M., Strumiński, A., Piwowarska, Z., Węgrzyn, A., Witkowski, S., Michalik, M., Selective catalytic oxidation of ammonia to nitrogen over Mg-Al, Cu-Mg-Al and Fe-Mg-Al mixed metal oxides doped with noble metals. Appl. Catal. B 130-131 (2013), 152–162.
6. Chmielarz, L., Kuśtrowski, P., Rafalska-Łasocha, A., Dziembaj, R., Selective oxidation of ammonia to nitrogen on transition metal containing mixed metal oxides. Appl. Catal. B 58 (2005), 235–244.
7. Chmielarz, L., Piwowarska, Z., Rutkowska, M., Wojciechowska, M., Dudek, B., Witkowski, S., Michalik, M., Total oxidation of selected mono-carbon VOCs over hydrotalcite originated metal oxide catalysts. Catal. Commun. 17 (2012), 118–125.
8. Chmielarz, L., Węgrzyn, A., Wojciechowska, M., Witkowski, S., Michalik, M., Selective catalytic oxidation (SCO) of ammonia to nitrogen over hydrotalcite originated Mg-Cu-Fe mixed metal oxides. Catal. Lett. 141 (2011), 1345–1354.
9. Das, S.K., Mukherjee, S., Lopes, L.M.F., Ilharco, L.M., Ferraria, A.M., Botelho do Regob, A.M., Pombeiro, A.J.L., Synthesis, characterization and heterogeneous catalytic application of copper integrated mesoporous matrices. Dalton Trans. 43 (2014), 3215–3226.
10. Dixit, M., Mishra, M., Joshi, P.A., Shah, D.O., Physico-chemical and catalytic properties of Mg–Al hydrotalcite and Mg–Al mixed oxide supported copper catalysts. J. Ind. Eng. Chem. 19 (2013), 458–468.
11. 2O from agricultural land., 2001 (online) http://www.fao.org/docrep/004/Y2780E/y2780e00.htm (accessed March 2016).
12. Hadjiivanov, K.I., Vayssilov, G.N., Characterization of oxide surfaces and zeolites by carbon monoxide as an IR probe molecule. Adv. Catal. 47 (2002), 307–511.
13. Jabłońska, M., Palkovits, R., Copper based catalysts for the selective ammonia oxidation into nitrogen and water vapour — recent trends and open challenges. Appl. Catal. B 181 (2016), 332–351.
14. Jabłońska, M., Chmielarz, L., Węgrzyn, A., Góra-Marek, K., Piwowarska, Z., Witkowski, S., Bidzińska, E., Kuśtrowski, P., Wach, A., Majda, D., Hydrotalcite derived (Cu, Mn)-Mg-Al metal oxide systems doped with palladium as catalysts for low-temperature methanol incineration. Appl. Clay Sci. 114 (2015), 273–282.
15. Jabłońska, M., Chmielarz, L., Węgrzyn, A., Guzik, K., Piwowarska, Z., Witkowski, S., Walton, R.I., Dunne, P.W., Kovanda, F., Thermal transformations of Cu–Mg (Zn)–Al(Fe) hydrotalcite-like materials into metal oxide systems and their catalytic activity in selective oxidation of ammonia to dinitrogen. J. Therm. Anal. Calorim. 114 (2013), 731–747.
16. Kannan, S., Rivers, V., Knözinger, H., High-temperature transformations of Cu-rich hydrotalcites. J. Solid State Chem. 177 (2004), 319–331.
17. 2 methanation. RSC Adv. 4 (2014), 17420–17428.
18. Luggren, P.J., Apesteguía, C.R., Di Cosimo, J.I., Liquid transportation fuels from biomass-derived oxygenates: gas-phase 2-hexanol upgrading on Cu-based mixed oxides. Appl. Catal. A 504 (2015), 256–265.
19. 3 catalysts for CO oxidation. J. Mol. Catal. A Chem. 239 (2005), 243–248.
20. Marion, M.C., Garbowski, E., Primet, M., Physicochemical properties of copper oxide loaded alumina in methane combustion. J. Chem. Soc. Faraday Trans. 86 (1990), 3027–3032.
21. Martins, L., Peguin, R.P.S., Wallau, M., Urquieta González, E.A., Cu-, Co-, Cu/Ca- and Co/Ca-exchanged ZSM-5 zeolites: activity in the reduction of NO with methane or propane. Stud. Surf. Sci. Catal. 154:C (2004), 2475–2483.
22. 3 catalysts part 1. Characterization of the catalyst. Appl. Catal. A 151 (1997), 393–408.
23. 3. Appl. Catal. B 16 (1996), 205–213.
24. Nishida, K., Li, D., Zhan, Y., Shishido, T., Oumi, Y., Sano, T., Takehira, K., Effective MgO surface doping of Cu/Zn/Al oxides as water-gas shift catalysts. Appl. Clay Sci. 44 (2009), 211–217.
25. 3 solids during redox treatments. Correlation with the selective reduction of nitric oxide by hydrocarbons. Appl. Catal. B 6 (1998), 359–374.
26. 3. J. Catal. 226 (2004), 120–128.
27. Sutton, M.A., Dragosits, U., Tang, Y.S., Fowler, D., Ammonia emissions from nonagricultural sources in the UK. Atmos. Environ. 34 (2000), 855–869.
28. Taguchi, M., Nakane, T., Hashi, K., Ohki, S., Shimizu, T., Sakka, Y., Matsushita, A., Abe, H., Funazukuri, T., Naka, T., Reaction temperature variations on the crystallographic state of spinel cobalt aluminate. Dalton Trans. 42 (2013), 7167–7176.
29. Tanaka, Y., Utaka, T., Kikuchi, R., Sasaki, K., Eguchi, K., Water gas shift reaction over Cu-based mixed oxides for CO removal from the reformed fuels. Appl. Catal. A 242 (2003), 287–295.
30. Xu, S., Liao, M.-C., Zeng, H.-Y., Chen, C.-R., Duan, H.-Z., Liu, X.-J., Du, J.-Z., Magnetic hydrotalcites as solid basic catalysts for cellulose hydrolysis. Appl. Clay Sci. 115 (2015), 124–131.
31. Zawadzki, J., The mechanism of ammonia oxidation and certain analogous reactions. Discuss. Faraday Soc. 8 (1950), 140–152.
32. Zhang, L.H., Li, F., Evans, D.G., Duan, X., Cu-Zn-(Mn)-(Fe)-Al layered double hydroxides and their mixed metal oxides: physicochemical and catalytic properties in wet hydrogen peroxide oxidation of phenol. Ind. Eng. Chem. Res. 49 (2010), 5959–5968.
33. Zhao, D., Wang, A., Estimation of anthropogenic ammonia emissions in Asia. Atmos. Environ. 28 (1994), 689–694.