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Volumn 358, Issue 9, 2016, Pages 1526-1533

Domino Meyer-Schuster/Arylation Reaction of Alkynols or Alkynyl Hydroperoxides with Diazonium Salts Promoted by Visible Light under Dual Gold and Ruthenium Catalysis

Author keywords

alcohols; alkynes; diazo compounds; gold; photocatalysis

Indexed keywords


EID: 84965082718     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201600158     Document Type: Article
Times cited : (77)

References (98)
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    • After initiation of our efforts, a related contribution from Shin and co-workers appeared, see:, DOI:./acs.orglett. 5b 03531. Worthy of note, while 4 equiv. of diazonium salts were required in Shin's work, the diazonium salt loading could be reduced considerably (just 1 equiv.) with our optimized protocol in this manuscript. Besides, our protocol allows challenging primary propargylic alcohols and alkynyl hydroperoxides to successfully participate in the arylative rearrangement sequence.
    • After initiation of our efforts, a related contribution from Shin and co-workers appeared, see:, J. Um, H. Yun, S. Shin, Org. Lett. 2016, 18, DOI: 10./acs.orglett. 5b 03531. Worthy of note, while 4 equiv. of diazonium salts were required in Shin's work, the diazonium salt loading could be reduced considerably (just 1 equiv.) with our optimized protocol in this manuscript. Besides, our protocol allows challenging primary propargylic alcohols and alkynyl hydroperoxides to successfully participate in the arylative rearrangement sequence
    • (2016) Org. Lett. , vol.18 , pp. 10
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