Silicon oxycarbide glass-graphene composite paper electrode for long-cycle lithium-ion batteries

Nature Communications

Volumn 7, Issue , 2016, Pages

  David, Lamuel ^a   Bhandavat, Romil ^a   Barrera, Uriel ^a   Singh, Gurpreet ^a  

^a Sunflower Networking Group   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

GRAPHENE; GRAPHENE OXIDE; LITHIUM ION; SILICON; SILICON OXYCARBIDE GLASS GRAPHENE; UNCLASSIFIED DRUG;

CARBON; CONDUCTIVITY; ELECTRODE; ION; LITHIUM; OXIDE; SILICON;

ARTICLE; CHEMICAL MODIFICATION; COMPOSITE MATERIAL; CURRENT DENSITY; ELECTRIC BATTERY; ELECTRIC CONDUCTIVITY; ELECTRODE; MECHANICS; NANOFABRICATION; PARTICLE SIZE;

EID: 84962406652     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms10998     Document Type: Article

References (60)

1. Xiong, P. et al. Chemically integrated two-dimensional hybrid zinc manganate/ graphene nanosheets with enhanced lithium storage capability. ACS Nano 8, 8610-8616 (2014).
2. Ko, M., Chae, S., Jeong, S., Oh, P. & Cho, J. Elastic a-silicon nanoparticle backboned graphene hybrid as a self-compacting anode for high-rate lithium ion batteries. ACS Nano 8, 8591-8599 (2014).
3. David, L., Bhandavat, R., Barrera, U. & Singh, G. Polymer-derived ceramic functionalized MoS2 composite paper as a stable lithium-ion battery electrode. Sci. Rep 5, 9792 (2015).
4. Raccichini, R., Varzi, A., Passerini, S. & Scrosati, B. The role of graphene for electrochemical energy storage. Nat. Mater. 14, 271-279 (2015).
5. Bhandavat, R., David, L. & Singh, G. Synthesis of surface-functionalized WS2 nanosheets and performance as Li-ion battery anodes. J. Phys. Chem. Lett. 3, 1523-1530 (2012).
6. Manthiram, A. Materials challenges and opportunities of lithium ion batteries. J. Phys. Chem. Lett. 2, 176-184 (2011).
7. Cui, L.-F., Hu, L., Choi, J. W. & Cui, Y. Light-weight free-standing carbon nanotube-silicon films for anodes of lithium ion batteries. ACS Nano 4, 3671-3678 (2010).
8. Luo, J. Y. et al. Crumpled graphene-encapsulated Si nanoparticles for lithium ion battery anodes. J. Phys. Chem. Lett. 3, 1824-1829 (2012).
9. Liu, N. et al. A pomegranate-inspired nanoscale design for large-volumechange lithium battery anodes. Nat. Nanotechnol 9, 187-192 (2014).
10. Hwang, T. H., Lee, Y. M., Kong, B. S., Seo, J. S. & Choi, J. W. Electrospun core-shell fibers for robust silicon nanoparticle-based lithium ion battery anodes. Nano Lett. 12, 802-807 (2012).
11. Pan, L. et al. Facile synthesis of yolk-shell structured Si-C nanocomposites as anodes for lithium-ion batteries. Chem. Commun. 50, 5878-5880 (2014).
12. Cui, L. F., Yang, Y., Hsu, C. M. & Cui, Y. Carbon-silicon core-shell nanowires as high capacity electrode for lithium ion batteries. Nano Lett. 9, 3370-3374 (2009).
13. Hertzberg, B., Alexeev, A. & Yushin, G. Deformations in Si-Li anodes upon electrochemical alloying in nano-confined space. J. Am. Chem. Soc. 132, 8548-8549 (2010).
14. Wang, B. et al. Adaptable silicon-carbon nanocables sandwiched between reduced graphene oxide sheets as lithium ion battery anodes. ACS Nano 7, 1437-1445 (2013).
15. Hu, T. et al. Flexible free-standing graphene-TiO2 hybrid paper for use as lithium ion battery anode materials. Carbon 51, 322-326 (2013).
16. Liang, J., Zhao, Y., Guo, L. & Li, L. Flexible free-standing graphene/SnO2 nanocomposites paper for Li-ion battery. ACS Appl. Mater. Interfaces 4, 5742-5748 (2012).
17. Jia, X. et al. Building robust architectures of carbon and metal oxide nanocrystals toward high-performance anodes for lithium-ion batteries. ACS Nano 6, 9911-9919 (2012).
18. Noerochim, L., Wang, J. Z., Chou, S. L., Wexler, D. & Liu, H. K. Free-standing single-walled carbon nanotube/SnO2 anode paper for flexible lithium-ion batteries. Carbon 50, 1289-1297 (2012).
19. Chockla, A. M. et al. Electrochemical lithiation of graphene-supported silicon and germanium for rechargeable batteries. J. Phys. Chem. C 116, 11917-11923 (2012).
20. Yue, L., Zhong, H. & Zhang, L. Enhanced reversible lithium storage in a nano- Si/MWCNT free-standing paper electrode prepared by a simple filtration and post sintering process. Electrochim. Acta 76, 326-332 (2012).
21. Chen, Z. et al. In situ generation of few-layer graphene coatings on SnO2-SiC core-shell nanoparticles for high-performance lithium-ion storage. Adv. Eng. Mater. 2, 95-102 (2012).
22. Ji, L. et al. Graphene/Si multilayer structure anodes for advanced half and full lithium-ion cells. Nano Energy 1, 164-171 (2012).
23. Zhang, B., Zheng, Q. B., Huang, Z. D., Oh, S. W. & Kim, J. K. SnO2-graphenecarbon nanotube mixture for anode material with improved rate capacities. Carbon 49, 4524-4534 (2011).
24. Ji, L. et al. Fe3O4 Nanoparticle-integrated graphene sheets for highperformance half and full lithium ion cells. Phys. Chem. Chem. Phys. 13, 7170-7177 (2011).
25. Yu, A. et al. Free-standing layer-by-layer hybrid thin film of graphene-MnO2 nanotube as anode for lithium ion batteries. J. Phys. Chem. Lett. 2, 1855-1860 (2011).
26. Xiao, J. et al. Electrochemically induced high capacity displacement reaction of PEO/MoS2/graphene nanocomposites with lithium. Adv. Funct. Mater. 21, 2840-2846 (2011).
27. Lee, J. K., Smith, K. B., Hayner, C. M. & Kung, H. H. Silicon nanoparticlesgraphene paper composites for Li ion battery anodes. Chem. Commun. 46, 2025-2027 (2010).
28. Wang, H. et al. Mn3O4-graphene hybrid as a high-capacity anode material for lithium ion batteries. J. Am. Chem. Soc. 132, 13978-13980 (2010).
29. Wu, Z. S. et al. Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. ACS Nano 4, 3187-3194 (2010).
30. Yang, S., Feng, X., Ivanovici, S. & Müllen, K. Fabrication of grapheneencapsulated oxide nanoparticles: Towards high-performance anode materials for lithium storage. Angew. Chem. Int. Ed. 49, 8408-8411 (2010).
31. Wang, D. et al. Ternary self-assembly of ordered metal oxide-graphene nanocomposites for electrochemical energy storage. ACS Nano 4, 1587-1595 (2010).
32. Wang, J. Z., Zhong, C., Chou, S. L. & Liu, H. K. Flexible free-standing graphene-silicon composite film for lithium-ion batteries. Electrochem. Commun. 12, 1467-1470 (2010).
33. Zhou, G. et al. Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries. Chem. Mater. 22, 5306-5313 (2010).
34. Wang, D. et al. Self-assembled TiO2-graphene hybrid nanostructures for enhanced Li-ion insertion. ACS Nano 3, 907-914 (2009).
35. Paek, S. M., Yoo, E. & Honma, I. Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with threedimensionally delaminated flexible structure. Nano Lett. 9, 72-75 (2008).
36. Kumar, A. et al. Direct synthesis of lithium-intercalated graphene for electrochemical energy storage application. ACS Nano 5, 4345-4349 (2011).
37. Li, X. et al. Superior cycle stability of nitrogen-doped graphene nanosheets as anodes for lithium ion batteries. Electrochem. Commun. 13, 822-825 (2011).
38. Zhao, X., Hayner, C. M., Kung, M. C. & Kung, H. H. Flexible holey graphene paper electrodes with enhanced rate capability for energy storage applications. ACS Nano 5, 8739-8749 (2011).
39. David, L. & Singh, G. Reduced graphene oxide paper electrode: opposing effect of thermal annealing on Li and Na cyclability. J. Phys. Chem. C 118, 28401-28408 (2014).
40. Bhandavat, R. & Singh, G. Improved electrochemical capacity of precursorderived Si(B)CN-carbon nanotube composite as Li-ion battery anode. ACS Appl. Mater. Interfaces 4, 5092-5097 (2012).
41. Bhandavat, R. & Singh, G. Stable and efficient Li-ion battery anodes prepared from polymer-derived silicon oxycarbide-carbon nanotube shell/core composites. J. Phys. Chem. C 117, 11899-11905 (2013).
42. Saha, A., Raj, R. & Williamson, D. L. A model for the nanodomains in polymer-derived SiCO. J. Am. Ceram. Soc. 89, 2188-2195 (2006).
43. Sanchez-Jimenez, P. E. & Raj, R. Lithium insertion in polymer-derived silicon oxycarbide ceramics. J. Am. Ceram. Soc. 93, 1127-1135 (2010).
44. Kaspar, J., Graczyk-Zajac, M. & Riedel, R. Determination of the chemical diffusion coefficient of Li-ions in carbon-rich silicon oxycarbide anodes by electro-analytical methods. Electrochim. Acta 115, 665-670 (2014).
45. Konno, H. et al. Si-C-O glass-like compound/exfoliated graphite composites for negative electrode of lithium ion battery. Carbon 45, 477-483 (2007).
46. Ahn, D. & Raj, R. Cyclic stability and C-rate performance of amorphous silicon and carbon based anodes for electrochemical storage of lithium. J. Power Sources 196, 2179-2186 (2011).
47. Ahn, D., Lee, M. & Shah, S. R. (2009). U.S. Patent Application 12/483, 631.
48. Feng, Y., Feng, N., Wei, Y. & Bai, Y. Preparation and improved electrochemical performance of SiCN-graphene composite derived from poly(silylcarbondiimide) as Li-ion battery anode. J. Mater. Chem. A 2, 4168-4177 (2014).
49. Graczyk-Zajac, M., Fasel, C. & Riedel, R. Polymer-derived-SiCN ceramic/ graphite composite as anode material with enhanced rate capability for lithium ion batteries. J. Power Sources 196, 6412-6418 (2011).
50. Xing, W., Wilson, A. M., Eguchi, K., Zank, G. & Dahn, J. R. Pyrolyzed polysiloxanes for use as anode materials in lithium- ion batteries. J. Electrochem. Soc. 144, 2410-2416 (1997).
51. Marcano, D. C. et al. Improved synthesis of graphene oxide. ACS Nano 4, 4806-4814 (2010).
52. Sadezky, A., Muckenhuber, H., Grothe, H., Niessner, R. & Poschl, U. Raman micro spectroscopy of soot and related carbonaceous materials: Spectral analysis and structural information. Carbon 43, 1731-1742 (2005).
53. Compton, O. C., Dikin, D. A., Putz, K. W., Brinson, L. C. & Nguyen, S. T. Electrically conductive "alkylated" graphene paper via chemical reduction of amine-functionalized graphene oxide paper. Adv. Mater. 22, 892-896 (2010).
54. Compton, O. C. & Nguyen, S. T. Graphene oxide, highly reduced graphene oxide, and graphene: versatile building blocks for carbon-based materials. Small 6, 711-723 (2010).
55. Park, S. et al. Aqueous suspension and characterization of chemically modified graphene sheets. Chem. Mater. 20, 6592-6594 (2008).
56. Park, S. et al. Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents. Nano Lett. 9, 1593-1597 (2009).
57. Ganguly, A., Sharma, S., Papakonstantinou, P. & Hamilton, J. Probing the thermal deoxygenation of graphene oxide using high-resolution in situ X-ray-based spectroscopies. J. Phys. Chem. C 115, 17009-17019 (2011).
58. Haubner, K. et al. The route to functional graphene oxide. ChemPhysChem 11, 2131-2139 (2010).
59. Park, S. et al. Hydrazine-reduction of graphite- and graphene oxide. Carbon 49, 3019-3023 (2011).
60. Zheng, T., McKinnon, W. R. & Dahn, J. R. Hysteresis during lithium insertion in hydrogen-containing carbons. J. Electrochem. Soc. 143, 2137-2145 (1996).