Principles and mechanisms of isotope fractionation

Environmental Isotopes in Biodegradation and Bioremediation

Volumn , Issue , 2009, Pages 43-78

  Hunkeler, Daniel ^a   Elsner, Martin ^b  

^a UNIVERSITY OF NEUCHÂTEL   (Switzerland)

^b INSTITUTE OF EPIDEMIOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84962111958     PISSN: None     EISSN: None     Source Type: Book    
DOI: None     Document Type: Chapter

References (29)

1. Abe, Y., J. Zopfi, and D. Hunkeler. 2009. Effect of molecule size on carbon isotope fractionation during biodegradation of chlorinated alkanes by Xanthobacter autotrophicus GJ10. Isotopes in Environmental and Health Studies 45 (1):18-26.
2. Bouchard, D., P. Höhener, and D. Hunkeler. 2008. Carbon isotope fractionation during volatilization of a petroleum hydrocarbon source and diffusion across a porous medium: A column experiment. Environmental Science & Technology 42 (21):7801-6.
3. Bouchard, D., D. Hunkeler, P. Gaganis, R. Aravena, P. Höhener, and P. Kjeldsen. 2008. Carbon isotope fractionation during migration of petroleum hydrocarbon vapors in the unsaturated zone: Field experiment at Værløse Airbase, Denmark, and modeling. Environmental Science & Technology 42:596-601.
4. Bourg, I. C. 2008. Comment on “Modeling sulfur isotope fractionation and differential diffusion during sulfate reduction in sediments of the Cariaco Basin” by M. A. Donahue, J. P. Werne, C. Meile, and T. W. Lyons. Geochimica Cosmochimica Acta 72 (23):5852-54.
5. Bourg, I. C., and G. Sposito. 2008. Isotopic fractionation of noble gases by diffusion in liquid water: Molecular dynamics simulations and hydrologic applications. Geochimica Cosmochimica Acta 72 (9):2237-47.
6. Cerling, T. E., D. K. Solomon, J. Quade, and J. R. Bowman. 1991. On the isotopic composition of carbon in soil carbon dioxide. Geochimica Cosmochimica. Acta 55:3403-5.
7. Clark, I. D., and P. Fritz. 1997. Environmental isotopes in hydrogeology. Boca Raton, FL: Lewis Publishers.
8. Conant, B. H., R. W. Gillham, and C. A. Mendoza. 1996. Vapor transport of trichloroethylene in the unsaturated zone: Field and numerical modeling investigations. Water Resources Research 32 (1):9-22.
9. Cook, P. F., ed. 1991. Enzyme mechanism from isotope effects. Boca Raton, FL: CRC Press.
10. Cornish-Bowden, A. 1995. Fundamentals of enzyme kinetics. London: Portland Press.
11. Elsner, M., L. Zwank, D. Hunkeler, and R. P. Schwarzenbach. 2005. A new concept linking observable stable isotope fractionation to transformation pathways of organic groundwater contaminants. Environmental Science & Technology 39:6896-916.
12. Falta, R. W., I. Javandel, K. Pruess, and P. A. Witherspoon. 1989. Density-driven flow of gas in the unsaturated zone due to the evaporation of volatile organic compounds. Water Resources Research 25 (10):2159-69.
13. Freeze, R. A., and J. A. Cherry. 1979. Groundwater. Upper Saddle River, NJ: Prentice Hall.
14. Hartshorn, S. R., and V. J. Shiner. 1972. Calculation of H/D, C-12/C-13, and C-12/C-14 fractionation factors from valence force fields derived for a series of simple organic-molecules. Journal of the American Chemical Society 94 (26):9002-12.
15. Huang, L., N. C. Sturchio, T. Abrajano, L. J. Heraty, and B. D. Holt. 1999. Carbon and chlorine isotope fractionation of chlorinated aliphatic hydrocarbons by evaporation. Organic Geochemistry 30:777-85.
16. Hunkeler, D. 2002. Quantification of isotope fractionation in experiments with deuteriumlabeled substances. Applied and Environmental Microbiology 68 (10):5205-7.
17. Hunkeler, D., B. M. Van Breukelen, and M. Elsner. 2009. Modeling chlorine isotope trends during sequential transformation of chlorinated ethenes, Environmental Science and Technology, in press.
18. Huskey, W. P. 1991. Origin and interpretation of heavy-isotope effects. In Enzyme mechanism from isotope effects, ed. P. F. Cook, pp. 37-72, Boca Raton: FL: CRC Press.
19. Kohen, A., and H. H. Limbach, eds. 2006. Isotope effects in chemistry and biology. Boca Raton: FL: CRC Press.
20. Kopinke, F. D., A. Georgi, M. Voskamp, and H. H. Richnow. 2005. Carbon isotope fractionation of organic contaminants due to retardation on humic substances: Implications for natural attenuation studies in aquifers. Environmental Science & Technology 39 (16):6052-62.
21. Kuder, T., P. Philp, and J. Allen. 2009. Effects of volatilization on carbon and hydrogen isotope ratios of MTBE. Environmental Science and Technology 43 (6): 1763-1768.
22. LaBolle, E. M., G. E. Fogg, J. B. Eweis, J. Gravner, and D. G. Leaist. 2008. Isotopic fractionation by diffusion in groundwater. Water Resources Research 44, W07405.
23. Melander, L., and W. H. Saunders. 1980. Reaction rates of isotopic molecules. New York: John Wiley.
24. Paneth, P. 1985. On the application of the steady state to kinetic isotope effects. Journal of the American Chemical Society 107:7070-71.
25. Poulson, S. R., and J. I. Drever. 1999. Stable isotope (C, Cl, and H) fractionation during vaporization of trichloroethylene. Environmental Science & Technology 33 (20):3689-94.
26. Schüth, C., H. Taubald, N. Bolano, and K. Maciejczyk. 2003. Carbon and hydrogen isotope effects during sorption of organic contaminants on carbonaceous materials. Journal Contaminant Hydrology 64:269-81.
27. Scott, K. M., X. Lu, C. M. Cavanaugh, and J. S. Liu. 2004. Optimal methods for estimating kinetic isotope effects from different forms of the Rayleigh distillation equation. Geochimica Cosmochimica Acta 68:433-42.
28. Slater, G. F., J. M. E. Ahad, B. Sherwood Lollar, R. Allen-King, and B. Sleep. 2000. Carbon isotope effects resulting from equilibrium sorption of dissolved VOCs. Analytical Chemistry 72:5669-72.
29. Wittko, G., and W. Kohler. 2006. Influence of isotopic substitution on the diffusion and thermal diffusion coefficient of binary liquids. European Physical Journal E 21 (4):283-91.