Biphasic water splitting by osmocene

Proceedings of the National Academy of Sciences of the United States of America

Volumn 109, Issue 29, 2012, Pages 11558-11563

  Ge, Peiyu ^a   Todorova, Tanya K ^a   Patir, Imren Hatay ^a   Olaya, Astrid J ^a   Vrubel, Heron ^a   Mendez, Manuel ^a   Hu, Xile ^a   Corminboeuf, Clémence ^a   Girault, Hubert H ^a  

^a EPFL   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

1,2 DICHLOROETHANE; CARBON DIOXIDE; HYDROGEN; OSMIUM; OSMOCENE; PROTON; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTROCHEMISTRY; GAS CHROMATOGRAPHY; POTENTIOMETRY; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; ULTRAVIOLET SPECTROSCOPY; WATER SPLITTING;

EID: 84961982042     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1203743109     Document Type: Article

References (40)

1. Pagliaro M, Konstandopoulos AG, Ciriminna R, Palmisano G (2010) Solar hydrogen: Fuel of the near future. Energy Environ Sci 3:279-287.
2. Walter MG, et al. (2010) Solar water splitting cells. Chem Rev 110:6446-6473.
3. Bard AJ, Fox MA (1995) Artificial photosynthesis: Solar splitting of water to hydrogen and oxygen. Acc Chem Res 28:141-145.
4. Cook TR, et al. (2010) Solar energy supply and storage for the legacy and nonlegacy worlds. Chem Rev 110:6474-6502.
5. Koelle U, Infelta PP, Grätzel M (1988) Kinetics and mechanism of the reduction of protons to hydrogen by cobaltocene. Inorg Chem 27:879-883.
6. Kunkely H, Vogler A (2009) Water splitting by light with osmocene as photocatalyst. Angew Chem Int Edit 48:1685-1687.
7. Hatay I, et al. (2009) Hydrogen evolution at liquid-liquid interfaces. Angew Chem Int Edit 48:5139-5142.
8. Hatay I, et al. (2009) Proton-coupled oxygen reduction at liquid-liquid interfaces catalyzed by cobalt porphine. J Am Chem Soc 131:13453-13459.
9. Partovi-Nia R, et al. (2009) Proton pump for O2 reduction catalyzed by 5, 10, 15, 20-tetraphenylporphyrinatocobalt(II). Chem Eur J 15:2335-2340.
10. Su B, et al. (2010) Molecular electrocatalysis for oxygen reduction by cobalt porphyrins adsorbed at liquid/liquid interfaces. J Am Chem Soc 132:2655-2662.
11. Schaming D, et al. (2011) Artificial photosynthesis at soft interfaces. CHIMIA Int J Chem 65:356-359.
12. Olaya AJ, et al. (2011) Four-electron oxygen reduction by tetrathiafulvalene. J Am Chem Soc 133:12115-12123.
13. Olaya AJ, et al. (2012) Self-assembled molecular rafts at liquid|liquid interfaces for four-electron oxygen reduction. J Am Chem Soc 134:498-506.
14. Swarts JC, Nafady A, Roudebush JH, Trupia S, Geiger WE (2009) One-electron oxidation of ruthenocene: Reactions of the ruthenocenium ion in gentle electrolyte media. Inorg Chem 48:2156-2165.
15. Droege MW, Harman WD, Taube H (1987) Higher oxidation state chemistry of osmocene: Dimeric nature of the osmocenium ion. Inorg Chem 26:1309-1315.
16. Kuwana T, Bublitz DE, Hoh G (1960) Chronopotentiometric studies on the oxidation of ferrocene, ruthenocene, osmocene and some of their derivatives. J Am Chem Soc 82:5811-5817.
17. Rogers EI, Lawrence NS, Compton RG (2011) The electrochemical oxidization of ruthenocene in various room temperature ionic liquids. J Electroanal Chem 657:144-149.
18. Shao Y, Stewart AA, Girault HH (1991) Determination of the half-wave potential of the species limiting the potential window. Measurement of Gibbs transfer energies at the water/1,2-dichloroethane interface. J Chem Soc Faraday T 87:2593-2597.
19. Shubina ES, Krylov AN, Kreindlin AZ, Rybinskaya MI, Epstein LM (1994) Hydrogenbonded complexes involving the metal atom and protonation of metallocenes of the iron subgroup. J Organomet Chem 465:259-262.
20. Su B, et al. (2008) H2O2 generation by decamethylferrocene at a liquid|liquid interface. Angew Chem Int Edit 47:4675-4678.
21. 4+. Proc Natl Acad Sci USA 105:17632-17635.
22. Fischer EO, Grubert H (1959) Über Aromatenkomplexe von Metallen, XXIX. Di-cyclopentadienyl-osmium. Chem Ber 92:2302-2309.
23. 4[dcpe = 1,2-bis(dicyclohexylphosphino)ethane]. J Chem Soc Chem Comm 1597-1598.
24. Wandlowski T, Mareček V, Samec Z (1990) Galvani potential scales for water-nitrobenzene and water-1,2-dichloroethane interfaces. Electrochim Acta 35:1173-1175.
25. Schmidt MW, et al. (1993) General atomic and molecular electronic structure system. J Comput Chem 14:1347-1363.
26. Gordon MS, Schmidt MW (2005) Advances in electronic structure theory: GAMESS a decade later. Theory and Applications of Computational Chemistry, The First Forty Years, eds CE Dykstra, G Frenking, KS Kim, and GE Scuseria (Elsevier, Amsterdam), pp 1167-1189.
27. Miertuš S, Scrocco E, Tomasi J (1981) Electrostatic interaction of a solute with a continuum. A direct utilizaion of ab initio molecular potentials for the prevision of solvent effects. Chem Phys 55:117-129.
28. Stephens PJ, Devlin FJ, Chabalowski CF, Frisch MJ (1994) Ab initio calculation of vibrational absorption and circular dichroism spectra using density functional force fields. J Phys Chem 98:11623-11627.
29. Steinmann SN, Corminboeuf C (2010) A system-dependent density-based dispersion correction. J Chem Theory Comput 6:1990-2001.
30. Steinmann SN, Corminboeuf C (2011) A generalized-gradient approximation exchange hole model for dispersion coefficients. J Chem Phys 134:044117.
31. Dunning TH, Jr (1989) Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen. J Chem Phys 90:1007-1023.
32. Balabanov NB, Peterson KA (2005) Systematically convergent basis sets for transition metals. I. All-electron correlation consistent basis sets for the 3d elements Sc-Zn. J Chem Phys 123:064107.
33. Steinmann SN, Corminboeuf C (2011) Comprehensive benchmarking of a densitydependent dispersion correction. J Chem Theory Comput 7:3567-3577.
34. Zhao Y, Truhlar DG (2006) A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions. J Chem Phys 125:194101.
35. Frisch MJ, et al. (2009) Gaussian 09 (Gaussian, Inc, Wallingford, CT).
36. Runge E, Gross EKU (1984) Density-functional theory for time-dependent systems. Phys Rev Lett 52:997-1000.
37. Gross EKU, Kohn W (1985) Local density-functional theory of frequency-dependent linear response. Phys Rev Lett 55:2850-2852.
38. Cramer CJ (2004) Essentials of Computational Chemistry (Wiley, Chichester, U.K.), 2nd Ed.
39. Ditchfield R (1974) Self-consistent perturbation-theory of diamagnetism. 1. Gauge-invariant LCAO method for NMR chemical-shifts. Mol Phys 27:789-807.
40. Huzinaga S, Klobukowski M (1993) Well-tempered Gaussian basis sets for the calculation of matrix Hartree-Fock wave functions. Chem Phys Lett 212:260-264.