Kinetic studies of the methanation of CO over a Ni/γ-Al2O3 catalyst using a batch reactor

Chemical Engineering Science

Volumn 146, Issue , 2016, Pages 316-336

  Lim, Jin Yang ^a   McGregor, James ^b   Sederman, Andrew J ^a   Dennis, John S ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

Batch reactor experiments; Catalyst; Methanation of CO; Modelling; Ni gamma alumina; Reaction kinetics

Indexed keywords

ADSORPTION; ALUMINA; BATCH REACTORS; CARBON DIOXIDE; CATALYSTS; HYDROGENATION; METHANATION; MODELS; NICKEL; REACTION KINETICS;

ALUMINA SUPPORT; CARBONACEOUS SPECIES; CARBONYL GROUPS; NICKEL CLUSTERS; RATE OF PRODUCTIONS; RATE-LIMITING STEPS; SPINNING BASKETS; TEMPERATURE PROGRAMMED;

CATALYST SELECTIVITY;

EID: 84961256934     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2016.02.001     Document Type: Article

References (31)

1. 2-induced CO dissociation on nickel surfaces. J. Catal. 2008, 255(1):6-19.
2. Araki M., Ponec V. Methanation of carbon monoxide on nickel and nickel-copper alloys. J. Catal. 1976, 44(3):439-448.
3. 2 methanation. Appl. Catal. A: Gen. 1997, 164(1):225-236.
4. Fujita S.I., Nakamura M., Doi T., Takezawa N. Mechanisms of methanation of carbon dioxide and carbon monoxide over nickel/alumina catalysts. Appl. Catal. A: Gen. 1993, 104(1):87-100.
5. 2 methanation reactions. Chem. Eng. J. 1997, 68(1):63-68.
6. Gardes G.E.E., Pajonk G.M., Teichner S.J. Catalytic demonstration of hydrogen spillover from nickel-alumina catalyst to alumina. J. Catal. 1974, 33(1):145-148.
7. Gardner D.C., Bartholomew C.H. Kinetics of carbon deposition during methanation of carbon monoxide. Ind. Eng. Chem. Prod. Res. Dev. 1981, 20(1):80-87.
8. Huang C.P., Richardson J.T. Alkali promotion of nickel catalysts for carbon monoxide methanation. J. Catal. 1978, 51(1):1-8.
9. 3: multiple reaction sites. J. Catal. 1984, 89(2):380-391.
10. Khodakov A.Y., Chu W., Fongarland P. Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels. Chem. Rev. 2007, 107(5):1692-1744.
11. Kikuchi E., Morita Y. Hydrogenolysis of n-pentane on nickel catalyst. J. Catal. 1969, 15(3):217-223.
12. Klose J., Baerns M. Kinetics of the methanation of carbon monoxide on an alumina-supported nickel catalyst. J. Catal. 1984, 85(1):105-116.
13. Kramer R., Andre M. Adsorption of atomic hydrogen on alumina by hydrogen spillover. J. Catal. 1979, 58(2):287-295.
14. Lim J.Y., Dennis J.S. Modelling reaction and diffusion in a spherical catalyst pellet using multicomponent flux models. Ind. Eng. Chem. Res. 2012, 51:15901-15911.
15. 3 catalyst. Chem. Eng. Sci. 2015, 10.1016/j.ces.2015.10.026.
16. Lim, J.Y., McGregor, J., Sederman, A.J., York, A.P.E., Dennis, J.S., 2016. Investigations of the Boudouard and the water-gas shift reaction over a Ni/γ-Al2O3 catalyst using a batch reactor. Paper in Preparation, Copy Available from Authors on Request.
17. McGregor J., Canning A.S., Mitchell S., Jackson S.D., Gladden L.F. The influence of carbon laydown on selectivity in the hydrogenation of pentenenitriles over supported-nickel catalysts. Appl. Catal. A: Gen. 2010, 384(1):192-200.
18. Neilsen J.R., Trimm D.L. Mechanisms of carbon formation on nickel-containing catalysts. J. Catal. 1977, 48:155-165.
19. Sanchez-Escribano V., Vargas L., Finocchio E., Busca G. On the mechanisms and the selectivity determining steps in syngas conversion over supported metal catalysts: an IR study. Appl. Catal. A: Gen. 2007, 316(1):68-74.
20. Sughrue E.L., Bartholomew C.H. Kinetics of carbon monoxide methanation on nickel monolithic catalysts. Appl. Catal. 1982, 2:239-256.
21. Tøttrup P.B. Kinetics of decomposition of carbon monoxide on a supported nickel catalyst. J. Catal. 1976, 42(1):29-36.
22. Tada S., Kikuchi R. Catal. Sci. Technol. 2015, 5:2061.
23. 2 on a nickel catalyst. J. Catal. 1973, 28(3):391-402.
24. Vance C.K., Bartholomew C.H. Hydrogenation of carbon dioxide on group VIII metals: III, effects of support on activity/selectivity and adsorption properties of nickel. Appl. Catal. 1983, 7(2):169-177.
25. Vanho S., Harriott P. The kinetics of methanation on nickel catalysts. J. Catal. 1980, 64(2):272-283.
26. Vannice M.A. The catalytic synthesis of hydrocarbons from H2CO mixtures over the group VIII metals: II. The kinetics of the methanation reaction over supported metals. J. Catal. 1975, 37(3):462-473.
27. 2 hydrogenation on nickel. J. Catal. 1982, 77(2):460-472.
28. Weisz P.B., Prater C.D. Interpretation of measurements in experimental catalysis. Advan. Catal. Relat. Sub. 1954, 6:143.
29. Xu J., Froment G.F. Methane steam reforming, methanation and water-gas shift: 1. Intrinsic kinetics. AIChE J. 1989, 35:88-96.
30. Young J.B., Todd B. Modelling of multi-component gas flows in capillaries and porous solids. Int. J. Heat Mass Transf. 2005, 48(25-26):5338-5353.
31. Zhang J., Fatah N., Capela S., Kara Y., Guerrini O., Khodakov A.Y. Kinetic investigation of carbon monoxide hydrogenation under realistic conditions of methanation of biomass derived syngas. Fuel 2013, 111:845-854.