MCM-41 modified with iron by template ion-exchange method as effective catalyst for DeNOx and NH3-SCO processes

Chemical Engineering Journal

Volumn 295, Issue , 2016, Pages 167-180

  Kowalczyk, Andrzej ^a   Piwowarska, Zofia ^a   Macina, Daniel ^a   Kuśtrowski, Piotr ^a   Rokicińska, Anna ^a   Michalik, Marek ^a   Chmielarz, Lucjan ^a  

^a JAGIELLONIAN UNIVERSITY   (Poland)

Author keywords

Iron; MCM 41 mesoporous silica; Selective catalytic oxidation of ammonia; Selective catalytic reduction of NO with ammonia; Template ion exchange method

Indexed keywords

AMMONIA; CATALYST ACTIVITY; CATALYST SELECTIVITY; CATALYSTS; CATALYTIC OXIDATION; DEPOSITION; ION EXCHANGE; IONS; IRON; SELECTIVE CATALYTIC REDUCTION; SILICA;

CATALYTIC PERFORMANCE; HIGH TEMPERATURE RANGE; MCM-41 MESOPOROUS SILICAS; SELECTIVE CATALYTIC OXIDATION; SELECTIVE CATALYTIC REDUCTION OF NO; SELECTIVE OXIDATION; SPECIFIC SURFACE AREA AND POROSITIES; TEMPLATE ION-EXCHANGE METHODS;

MESOPOROUS MATERIALS;

EID: 84961239025     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2016.03.049     Document Type: Article

References (48)

1. Meynen V., Cool P., Vansant E.F. Verified syntheses of mesoporous materials. Microporous Mesoporous Mater. 2009, 125:170-223.
2. Kresge C.T., Leonowicz M.E., Roth W.J., Vartuli J.C., Beck J.S. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 1992, 359:710-712.
3. Ng T.N., Chen X.Q., Yeung K.L. Direct manipulation of particle size and morphology of ordered mesoporous silica by flow synthesis. RCS Adv. 2015, 5:13331-13340.
4. Arruebo M., Ho W.Y., Lam K.F., Chen X., Arbiol J., Santamaría J., Yeung K.L. Preparation of magnetic nanoparticles encapsulated by an ultrathin silica shell via transformation of magnetic Fe-MCM-41. Chem. Mater. 2008, 20:486-493.
5. x catalysts. Microporous Mesoporous Mater. 2010, 127:133-141.
6. Baltes M., Collart O., Van Der Voort P., Vansant E.F. Synthesis of supported transition metal oxide catalysts by the designed deposition of acetylacetonate complexes. Langmuir 1999, 15:5841-5845.
7. Segura Y., Chmielarz L., Kuśtrowski P., Cool P., Dziembaj R., Vansant E.F. Characterisation and reactivity of vanadia-titania supported SBA-15 in the SCR of NO with ammonia. Appl. Catal. B Environ. 2015, 61:69-78.
8. D.D. Whitehurst, Method to recover organic templates from freshly synthesized molecular sieves, US Patent 5143879 A (1992).
9. Yonemitsu M., Tanaka Y., Iwamoto M. Metal ion-planted MCM-41. Planting of manganese (II) ion into MCM-41 by a newly developed template-ion exchange method. Chem. Mater. 1997, 9:2679-2681.
10. Yonemitsu M., Tanaka Y., Iwamoto M. Metal ion-planted MCM-41: 2. Catalytic epoxidation of stilbene and its derivatives with tert-butyl hydroperoxide on Mn-MCM-41. J. Catal. 1998, 178:207-213.
11. Tanev P.T., Pinnavaia T.J. Mesoporous silica molecular sieves prepared by ionic and neutral surfactant templating: a comparison of physical properties. Chem. Mater. 1996, 8:2068-2074.
12. Bourlinos A.B., Karakassides M.A., Petridis D. Synthesis and characterization of iron-containing MCM-41 porous silica by the exchange method of the template. J. Phys. Chem. B 2000, 114:4375-4380.
13. Wang Y., Zhang Q., Shishido T., Takehira K. Characterizations of iron-containing MCM-41 and its catalytic properties in epoxidation of styrene with hydrogen peroxide. J. Catal. 2002, 209:186-196.
14. Zhang Q., Guoa Q., Wang X., Shishido T., Wang Y. Iron-catalyzed propylene epoxidation by nitrous oxide: toward understanding the nature of active iron sites with modified Fe-MFI and Fe-MCM-41 catalysts. J. Catal. 2006, 239:105-116.
15. Zhang Q., Wangb Y., Itsuki S., Shishido T., Takehira K. Manganese-containing MCM-41 for epoxidation of styrene and stilbene. J. Mol. Catal. A Chem. 2002, 188:189-200.
16. Derylo-Marczewska A., Gac W., Popivnyak N., Zukocinski G., Pasieczna S. The influence of preparation method on the structure and redox properties of mesoporous Mn-MCM-41 materials. Catal. Today 2006, 114:293-306.
17. Wang Y., Ohishi Y., Shishido T., Zhang Q., Yang W., Guo Q., Wan H., Takehira K. Characterizations and catalytic properties of Cr-MCM-41 prepared by direct hydrothermal synthesis and template-ion exchange. J. Catal. 2003, 220:347-357.
18. Ohtsuka Y., Takahashi Y., Noguchi M., Arai T., Takasaki S., Tsubouchi N., Wang Y. Novel utilization of mesoporous molecular sieves as supports of cobalt catalysts in Fischer-Tropsch synthesis. Catal. Today 2004, 89:419-429.
19. Lang N., Aouine M., Tuel A. Incorporation of Co in various MCM-41 compounds by ion exchange of the template. Stud. Surf. Sci. Catal. 2005, 158:439-446.
20. Blanco A.A.G., Amaya M.G., Jalil M.E.R., Nazzarro M., Oliva M.I., Sapag K. Effect of the synthesis method on Co-catalysts based on MCM-41 for the Fischer-Tropsch reaction. Top. Catal. 2011, 54:190-200.
21. 3-comparison of different Cu-loading methods. Appl. Catal. B Environ. 2005, 58:69-77.
22. Canepa A.L., Chanquia C.M., Eimer G.A., Casuscelli S.G. Oxidation of olefins employing mesoporous molecular sieves modified with copper. Appl. Catal. A Gen. 2013, 462-463:8-14.
23. Tanaka M., Itadani A., Kuroda Y., Iwamoto M. Effect of pore size and nickel content of Ni-MCM-41 on catalytic activity for ethene dimerization and local structures of nickel ions. J. Phys. Chem. C 2012, 116:5664-5672.
24. Lehmann T., Wolff T., Hamel C., Veit P., Garke B., Seidel-Morgenstern A. Physico-chemical characterization of Ni/MCM-41 synthesized by a template ion exchange approach. Microporous Mesoporous Mater. 2012, 151:113-125.
25. Pirouzmand M., Nikzad-Kojanag B., Seyed-Rasulzade S.K. Surfactant containing Ca/MCM-41 as a highly active, green and reusable catalyst for the transesterification of canola oil. Catal. Commun. 2015, 69:196-201.
26. Iwamoto M., Tanaka Y. Preparation of metal ion-planted mesoporous silica by template ion-exchange method and its catalytic activity for asymmetric oxidation of sulphide. Catal. Surv. Jpn. 2001, 5:25-36.
27. ISO 22241-4:2009 Online, <>, (Accessed February 2016). https://www.iso.org/obp/ui/#iso:std:iso:22241:-4:ed-1:v1:en.
28. 2+-MCM-41 mesoporous materials with copper ions in the framework as precursors. Catal. Commun. 2013, 31:21-24.
29. 3. Microporous Mesoporous Mater. 2012, 151:44-55.
30. 2O with CO over FeMFI zeolites: influence of the preparation method on the iron species and catalytic behaviour. J. Catal. 2004, 223:13-27.
31. 3-slip oxidation activity of composite [Fe-Beta + Fe(Mn)MCM-48] catalysts. Mendeleev Commun. 2014, 24:313-315.
32. 3-pillared clays synthesized using the trinuclear Fe(III)-acetato complex as pillaring precursor. Mesoporous Mater. 1995, 4:43-51.
33. Leofanti G., Padovan M., Tozzola G., Venturelli B. Surface area and pore texture of catalysts. Catal. Today 1998, 41:207-219.
34. Corma A. From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem. Rev. 1997, 97:2373-2420.
35. Blanco T., Corma A., Navarro M.T., Perez-Pariente J. Synthesis, characterization, and catalytic activity of Ti-MCM-41 structures. J. Catal. 1995, 156:65-74.
36. Li X.F., Gao H.X., Jin G.J., Chen L., Ding L., Yang H.Y., Chen Q.L. Characterization and catalytic performance of methyl-grafted Ti-HMS catalysts prepared by the CVD method. J. Mol. Struct. 2008, 872:10.
37. x catalysts: new insights by a combined EPR and UV/VIS spectroscopic approach. J. Catal. 2004, 227:384-397.
38. 2O over Fe-silicalite and Fe-SBA-15 with the same iron constitution. Appl. Catal. B 2006, 62:244-254.
39. 2O emission. Fuel Process. Technol. 1993, 34:1-71.
40. Suzuki E., Nakashiro K., Ono Y. Hydroxylation of benzene with dinitrogen monoxide over H-ZSM-5 zeolite. Chem. Lett. 1988, 953-956.
41. Bailly L.M., Chizallet C., Costentin G., Krafft J.M., Pernot L.H., Che M. A spectroscopy and catalysis study of the nature of active sites of MgO catalysts: thermodynamic Brønsted basicity versus reactivity of basic sites. J. Catal. 2005, 235:413-422.
42. McIntyre N.S., Zetaruk D.G. X-ray photoelectron spectroscopic studies of iron oxides. Anal. Chem. 1977, 49:1521-1529.
43. Biesinger M.C., Payne B.P., Grosvenor A.P., Lau L.W.M., Gerson A.R., Smart R.C. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni. Appl. Surf. Sci. 2011, 257:2717-2730.
44. 2 catalysts. J. Catal. 2005, 231:365-380.
45. x/SBA-15 catalyst for selective oxidation of methane by oxygen. Appl. Catal. A Gen. 2009, 356:103-111.
46. x by ammonia over oxide catalysts: a review. Appl. Catal. B Environ. 1998, 18:1-36.
47. Chmielarz L., Jabłońska M. Advances in selective catalytic oxidation of ammonia to dinitrogen: a review. RSC Adv. 2015, 5:43408-43431.
48. Benjelloun M., Van Der Voort P., Cool P., Collart O., Vansant E.F. Reproducible synthesis of high quality MCM-48 by extraction and recuperation of the gemini surfactant. Phys. Chem. Chem. Phys. 2001, 3:127-131.