Efficient transformation of DDT by peroxymonosulfate activated with cobalt in aqueous systems: Kinetics, products, and reactive species identification

Chemosphere

Volumn 148, Issue , 2016, Pages 68-76

  Qin, Wenxiu ^a,b   Fang, Guodong ^a   Wang, Yujun ^a   Wu, Tongliang ^a,b   Zhu, Changyin ^a,b   Zhou, Dongmei ^a  

^a INSTITUTE OF GEOLOGY AND GEOPHYSICS   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Catalytic degradation; DDT; Free radicals; Intermediates

Indexed keywords

ACTIVATION ENERGY; DEGRADATION; DISSOLVED OXYGEN; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICALS; GROUNDWATER; GROUNDWATER POLLUTION; MASS SPECTROMETRY; MOLAR CONCENTRATION; MOLAR RATIO; PARAMAGNETIC RESONANCE; REMEDIATION; SOIL POLLUTION; SULFUR COMPOUNDS;

4-CHLOROBENZOIC ACIDS; ADVANCED OXIDATION TECHNOLOGY; CATALYTIC DEGRADATION; DEGRADATION EFFICIENCY; DEGRADATION KINETICS; DEGRADATION PATHWAYS; ELECTRON PARAMAGNETIC RESONANCES (EPR); INTERMEDIATES;

COBALT COMPOUNDS;

4 CHLOROBENZOIC ACID; 4 HYDROXYBENZOIC ACID; BENZOIC ACID; BENZYL ALCOHOL; COBALT; DISSOLVED OXYGEN; ETHANE; FREE RADICAL; NITRATE; SULFATE; 4-CHLOROBENZOIC ACID; BENZOPHENONE DERIVATIVE; CHLOROBENZOIC ACID DERIVATIVE; CHLORPHENOTANE; PEROXIDE; PEROXYMONOSULFATE; SOLUTION AND SOLUBILITY; WATER POLLUTANT;

ACTIVATION ENERGY; AQUEOUS SOLUTION; CATALYSIS; CHEMICAL COMPOUND; COBALT; CONCENTRATION (COMPOSITION); DDT; DEGRADATION; FREE RADICAL; REACTION KINETICS; SULFATE;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; COMPARATIVE STUDY; CONTROLLED STUDY; DECHLORINATION; DECOMPOSITION; DEGRADATION; DEGRADATION KINETICS; ELECTRON SPIN RESONANCE; HYDROXYLATION; MASS FRAGMENTOGRAPHY; PH; RATE CONSTANT; REACTION TIME; TEMPERATURE SENSITIVITY; ANALYSIS; CHEMISTRY; ECOSYSTEM RESTORATION; KINETICS; OXIDATION REDUCTION REACTION; SOLUTION AND SOLUBILITY; THEORETICAL MODEL; WATER POLLUTANT;

BENZOPHENONES; BENZYL ALCOHOL; CATALYSIS; CHLOROBENZOATES; COBALT; DDT; ELECTRON SPIN RESONANCE SPECTROSCOPY; ENVIRONMENTAL RESTORATION AND REMEDIATION; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; KINETICS; MODELS, THEORETICAL; OXIDATION-REDUCTION; PEROXIDES; SOLUTIONS; WATER POLLUTANTS, CHEMICAL;

EID: 84960400834     PISSN: 00456535     EISSN: 18791298     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2016.01.020     Document Type: Article

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