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Volumn 28, Issue 4, 2016, Pages 1213-1219

Synthetic Access to Atomically Dispersed Metals in Metal-Organic Frameworks via a Combined Atomic-Layer-Deposition-in-MOF and Metal-Exchange Approach

Author keywords

[No Author keywords available]

Indexed keywords

ATOMIC LAYER DEPOSITION; ATOMS; CRYSTALLINE MATERIALS; DEPOSITION; JAVA PROGRAMMING LANGUAGE; ORGANOMETALLICS; POROUS MATERIALS; SYNTHETIC METALS; ZINC;

EID: 84959161024     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/acs.chemmater.5b04887     Document Type: Article
Times cited : (88)

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    • note
    • 2 (possibly due to steric effects), so calculations were performed with the full compound.
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    • note
    • Also conceivable are structures in which the exothermicity of the AIM "B step" (hydrolysis step) is sufficiently large and negative that added metal atoms may move between node faces and form more compact cluster structures. This possibility is under active investigation by synchrotron X-ray techniques with metals that are better X-ray scatterers than zinc. The results of these studies will be reported in due course. The details of the final arrangement of zinc ions in Zn-AIM NU-1000 samples, while likely important for certain potential catalysis applications, are not of central importance to the interpretation of experimental metal-exchange studies.
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    • note
    • 2+ salts led to leaching. See the SI for details.
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    • note
    • 2O upon longer exposure times (44 h). See the SI for details.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.