Poly(N-isopropylacrylamide)-clay hydrogels: Control of mechanical properties and structure by the initiating conditions of polymerization

European Polymer Journal

Volumn 77, Issue , 2016, Pages 1-15

  Strachota, Beata ^a   Hodan, Jiří ^a   Matějka, Libor ^a  

^a INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Czech Republic)

Author keywords

Clay; Mechanical properties; N isopropylacrylamide; Nanocomposite; Polymer clay hydrogel; Thermoresponsive hydrogel

Indexed keywords

ACRYLIC MONOMERS; AMIDES; AMMONIUM PERSULFATE; CLAY; GELS; MECHANICAL PROPERTIES; NANOCOMPOSITES; POLYMERIZATION;

N- ISOPROPYLACRYLAMIDE; POLY(N-ISOPROPYLACRYLAMIDE); POLYMERIZATION PROCESS; PROPERTIES OF COMPOSITES; REDOX INITIATING SYSTEMS; TETRAMETHYLETHYLENEDIAMINE; THEORY OF ELASTICITY; THERMO-RESPONSIVE HYDROGELS;

HYDROGELS;

EID: 84958758682     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2016.02.011     Document Type: Article

References (38)

1. Y. Tanaka, Y. Kagami, A. Masuda, and Y. Osada Thermoreversible transition of tensile modulus of hydrogel with ordered aggregates Macromolecules 28 1995 2574 2576
2. J. Sun, W.Q. Xiao, Y.J. Tang, K.F. Li, and H.S. Fan Biomimetic interpenetrating polymer network hydrogels based on methacrylated alginate and collagen for 3D pre-osteoblast spreading and osteogenic differentiation Soft Matter 8 2012 2398 2404
3. J.T. Zhang, S.W. Huang, S.X. Cheng, and R.X. Zhuo Preparation and properties of poly(N-isopropylacrylamide)/poly(N-isopropylacrylamide) interpenetrating polymer networks for drug delivery J. Polym. Sci. Part A - Polym. Chem. 42 2004 1249 1254
4. J.P. Gong, Y. Katsuyama, T. Kurokawa, and Y. Osada Double-network hydrogels with extremely high mechanical strength Adv. Mater. 15 2003 1155 1158
5. Y. Okumura, and K. Ito The polyrotaxane gel: a topological gel by figure-of-eight cross-links Adv. Mater. 13 2001 485 487
6. M. Lutecki, B. Strachotová, M. Uchman, J. Brus, J. Pleštil, M. Šlouf, A. Strachota, and L. Matějka Thermosensitive PNIPA-based organic-inorganic hydrogels Polym. J. 38 2006 527 541
7. Y. Wu, M. Xia, Q. Fan, and M. Zhu Designable synthesis of nanocomposite hydrogels with excellent mechanical properties based on chemical cross-linked interactions Chem. Commun. 46 2010 7790 7792
8. B. Strachotová, A. Strachota, M. Uchman, M. Šlouf, J. Brus, J. Pleštil, and L. Matějka Super porous organic-inorganic poly(N-isopropylacrylamide)-based hydrogel with a very fast temperature response Polymer 48 2007 1471 1482
9. G. Huerta-Angeles, K. Hishchak, A. Strachota, B. Strachota, M. Šlouf, and L. Matějka Super-porous nanocomposite PNIPAm hydrogels reinforced with titania nanoparticles, displaying a very fast temperature response as well as pH-sensitivity Eur. Polymer J. 59 2014 341 352
10. K. Depa, A. Strachota, M. Šlouf, and J. Hromadková Fast temperature-responsive nanocomposite PNIPAM hydrogels with controlled pore wall thickness: force and rate of T-response Eur. Polymer J. 48 2012 1997 2007
11. K. Haraguchi, and T. Takehisa Nanocomposite hydrogels: a unique organic-inorganic network structure with extraordinary mechanical, optical, and swelling/de-swelling properties Adv. Mater. 14 2002 1120 1124
12. K. Haraguchi Stimuli-responsive nanocomposite gels Colloid Polym. Sci. 289 2011 455 473
13. K. Haraguchi, H.J. Li, K. Masuda, T. Takehisa, and E. Elliott Mechanism of forming organic/inorganic network structures during in-situ free-radical polymerization in PNIPA-clay nanocomposite hydrogels Macromolecules 38 2005 3482 3490
14. K. Haraguchi, and H.J. Li Control of the coil-to-globule transition and ultrahigh mechanical properties of PNIPA in nanocomposite hydrogels Angew. Chem. Int. Ed. 44 2005 6500 6504
15. Y. Liu, M.F. Zhu, X.L. Liu, W. Zhang, B. Sun, Y.M. Chen, and H.-J.P. Adler High clay content nanocomposite hydrogels with surprising mechanical strength and interesting deswelling kinetics Polymer 47 2006 1 5
16. M. Zhu, Y. Liu, B. Sun, W. Zhang, X. Liu, H. Yu, Y. Zhang, D. Kuckling, and H.-J.P. Adler A novel highly resilient nanocomposite hydrogel with low hysteresis and ultrahigh elongation Macromol. Rapid Commun. 27 2006 1023 1028
17. K. Haraguchi, T. Takehisa, and S. Fan Effects of clay content on the properties of nanocomposite hydrogels composed of poly(N-isopropylacrylamide) and clay Macromolecules 35 2002 10162 10171
18. K. Haraguchi, R. Farnworth, A. Ohbayashi, and T. Takehisa Compositional effects on mechanical properties of nanocomposite hydrogels composed of poly(N,N-dimethylacrylamide) and clay Macromolecules 36 2003 5732 5741
19. B. Strachota, L. Matějka, A. Zhigunov, R. Konefał, J. Spěváček, J. Dybal, and R. Puffr Poly(N-isopropylacrylamide)-clay based hydrogels controlled by the initiating conditions: evolution of structure and gel formation Soft Matter 11 2015 9291 9306
20. Y. Wang, J. Ma, S. Yang, and J. Xu PDMAA/clay nanocomposite hydrogels based on two different initiations Colloids Surf. A 390 2011 20 24
21. B. Ferse, S. Richter, F. Eckert, A. Kulkarni, C.M. Papadakis, and K.F. Arndt Gelation mechanism of poly(N-isopropylacrylamide)-clay nanocomposite hydrogels synthesized by photopolymerization Langmuir 24 2008 12627 12635
22. R. Nigmatullin, M. Bencsik, and F. Gao Influence of polymerisation conditions on the properties of polymer/clay nanocomposite hydrogels Soft Matter 10 2014 2035 2046
23. L.J. Xiong, X.B. Hu, X.X. Liu, and Z. Tong Network chain density and relaxation of in situ synthesized polyacrylamide/hectorite clay nanocomposite hydrogels with ultrahigh tensibility Polymer 49 2008 5064 5071
24. X.B. Hu, L.J. Xiong, T. Wang, Z.M. Lin, X.X. Liu, and Z. Tong Synthesis and dual response of ionic nanocomposite hydrogels with ultrahigh tensibility and transparence Polymer 50 2009 1933 1938
25. X.B. Hu, T. Wang, L.J. Xiong, C.Y. Wang, X.X. Liu, and Z. Tong Preferential adsorption of poly(ethylene glycol) on hectorite clay and effects on poly(N-isopropylacrylamide)/hectorite nanocomposite hydrogels Langmuir 26 2010 4233 4238
26. K. Haraguchi Synthesis and properties of soft nanocomposite materials with novel organic/inorganic network structures Polymer J. 43 2011 223 241
27. V. Can, S. Abdurrahmanoglu, and O. Okay Unusual swelling behavior of polymer-clay nanocomposite hydrogels Polymer 48 2007 5016 5023
28. S. Miyazaki, T. Karino, H. Endo, K. Haraguchi, and M. Shibayama Clay concentration dependence of microstructure in deformed poly(N-isopropylacrylamide)-clay nanocomposite gels Macromolecules 39 2006 8112 8120
29. J. Nie, B. Du, and W. Oppermann Swelling, elasticity, and spatial inhomogeneity of poly(N-isopropylacrylamide)/clay nanocomposite hydrogels Macromolecules 38 2005 5729 5736
30. O. Okay, and W. Oppermann Polyacrylamide-clay nanocomposite hydrogels: rheological and light scattering characterization Macromolecules 40 2007 3378 3387
31. S. Abdurrahmanoglu, V. Can, and O. Okay Equilibrium swelling behavior and elastic properties of polymer-clay nanocomposite hydrogels J. Appl. Polym. Sci. 109 2008 3714 3724
32. M. Ilavský Effect of phase transition on swelling and mechanical behavior of synthetic hydrogels Adv. Polym. Sci. 109 1993 173 206
33. D.S. Pearson, and W.W. Graessley Elastic properties of well-characterized ethylene-propylene copolymer networks Macromolecules 13 1980 1001 1009
34. Y. Xu, G. Li, and K. Haraguchi Gel formation and molecular characteristics of poly(N-isopropylacrylamide) prepared by free-radical redox polymerization in aqueous solution Macromol. Chem. Phys. 211 2010 977 987
35. H. Mauroy, Z. Rozynek, T.S. Plivelic, J.O. Fossum, G. Helgesen, and K.D. Knudsen Oxygen-controlled phase segregation in poly(N-isopropylacrylamide)/laponite nanocomposite hydrogels Langmuir 29 2013 371 379
36. K. Kabiri, M.J. Zohuriaan-Mehr, H. Bouhendi, A. Jamshidi, and F. Ahmad-Khanbeigi Residual monomer in superabsorbent polymers: effects of the initiating system J. Appl. Polym. Sci. 114 2009 2533 2540
37. K. Haraguchi, Y. Xu, and G. Li Molecular characteristics of poly(N-isopropylacrylamide) separated from nanocomposite gels by removal of clay from the polymer/clay network Macromol. Rapid Commun. 31 2010 718 723
38. X.D. Feng, X.Q. Guo, and K.Y. Qiu Study of the initiation mechanism of the vinyl polymerization with the system persulfate/N,N,N′,N′-tetramethylethylenediamine Makromol. Chem. 189 1988 77 83