Enhancing the energy density of safer Li-ion batteries by combining high-voltage lithium cobalt fluorophosphate cathodes and nanostructured titania anodes

Scientific Reports

Volumn 6, Issue , 2016, Pages

  Ortiz, Gregorio F ^a   López, Mariá C ^a   Li, Yixiao ^b   McDonald, Matthew J ^b   Cabello, Marta ^a   Tirado, José L ^a   Yang, Yong ^b  

^a UNIVERSITY OF CÓRDOBA   (Spain)

^b XIAMEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84958279532     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep20656     Document Type: Article

References (39)

1. Amine, K., Tukamoto, H., Yasuda, H., Fujita, Y. A new three-volt spinel Li1+xMn1.5Ni0.5O4 for secondary lithium batteries. J. Electrochem. Soc. 143, 1607-1613 (1996).
2. Kim, M. G., Cho, J. Reversible and High-Capacity Nanostructured Electrode Materials for Li-Ion Batteries. Adv. Funct. Mater. 19, 1497-1514 (2009).
3. Fey, G. T. K., Li, W., Dahn, J. R. LiNiVO4-A 4.8 volt electrode material for lithium cells. J. Electrochem. Soc. 141, 2279-2282 (1994).
4. Kraytsberg, A., Ein-Eli, Y. Higher, Stronger, Better ... A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries. Adv. Energy. Mater. 2, 922-939 (2012).
5. Amine, K., Yasuda, H., Yamachi, M. Olivine LiCoPO4 as 4.8 V electrode material for lithium batteries. Electrochem. Solid-State Lett. 3, 178-179 (2000).
6. Okada, S., Ueno, M., Uebou, Y., Yamaki J. I. Fluoride phosphate Li2CoPO4F as a high-voltage cathode in Li-ion batteries. J. Power Sources 146, 565-569 (2005).
7. Ohzuku, T., Ueda, A., Yamamoto, N. Zero-strain insertion material of Li[Li1/3Ti5/3]O4 for rechargeable lithium cells. J. Electrochem. Soc. 142, 1431-1435 (1995).
8. Sorensen, E. M., Barry, S. J., Jung, H. K., Rondinelli, J. R., Vaughey, J. T., Poeppelmeier, K. R. Three-dimensionally ordered macroporous Li4Ti5O12: Effect of wall structure on electrochemical properties. Chem. Mater. 18, 482-489 (2006).
9. Bruce, P. G., Scrosati, B., Tarascon, J. M. Nanomaterials for rechargeable lithium batteries. Angew. Chem.-Int. Edit. 47, 2930-2946 (2008).
10. Ortiz, G. F., Hanzu, I., Djenizian, T., Lavela, P., Tirado, J. L., Knauth, P. Alternative Li-Ion Battery Electrode Based on Self-Organized Titania Nanotubes. Chem. Mater. 21, 63-67 (2009).
11. Wu, X., Gong, Z., Tan, S., Yang, Y. Sol-gel synthesis of Li2CoPO4F/C nanocomposite as a high power cathode material for lithium ion batteries. J. Power Sources 220, 122-129 (2012).
12. Reale, P., Panero, S., Scrosati, B., Garche, J., Wohlfahrt-Mehrens, M., Wachtler, M. A safe, low-cost, and sustainable lithium-ion polymer battery. J. Electrochem. Soc. 151, A2138-A2142 (2004).
13. López, M. C., Ortiz, G. F., González, J. R., Alcántara, R., Tirado, J. L. Improving the Performance of Titania Nanotube Battery Materials by Surface Modification with Lithium Phosphate. ACS Appl. Mater. Interfaces 6, 5669-5678 (2014).
14. Cabello, M., Ortiz, G. F., López, M. C., Lavela, P., Alcántara, R., Tirado, J. L. Self-assembled Li4Ti5O12/TiO2/Li3PO4 for integrated Li-ion microbatteries Electrochem. Commun. 56, 61-64 (2015).
15. Wu, X., Wang, S., Lin, X., Zhong, G., Gong, Z., Yang, Y. Promoting long-term cycling performance of high-voltage Li2CoPO4F by the stabilization of electrode/electrolyte interface. J. Mater. Chem. A, 2, 1006-1013 (2014).
16. Truong, Q. D., Devaraju, M. K., Ganbe, Y., Tomai, T., Honma I. Structural Analysis and Electrochemical Performance of Li2CoPO4F Cathode Materials. Electrochim. Acta 127, 245-251 (2014).
17. Hadermann, J., Abakumov, A. M., Turner, S., Hafideddine, Z., Khasanova, N. R., Antipov, E. V., Tendeloo, G. V. Solving the Structure of Li Ion Battery Materials with Precession Electron Diffraction: Application to Li2CoPO4F. Chem. Mater. 23, 3540-3545 (2011).
18. Takada, K., Inada, T., Kajiyama, A., Sasaki, H., Kondo, S., Watanabe, M., Murayama, M., Kanno, R. Solid-state lithium battery with graphite anode. Solid State Ionics 158, 269-274 (2003).
19. Seki, S., Kobayashi, Y., Miyashiro, H., Mita, Y., Iwahori, T. Fabrication of high-voltage, high-capacity all-solid-state lithium polymer secondary batteries by application of the polymer electrolyte/inorganic electrolyte composite concept. Chem. Mater. 17, 2041-2045 (2005).
20. Du, Y. A., Holzwarth, N. A. W. Mechanisms of Li+diffusion in crystalline gamma-and beta-Li3PO4 electrolytes from first principles. Phys. Rev. B. 76, 174302 (2007).
21. Frayret, C., Masquelier, C., Villesuzanne, A., Morcrette, M., Tarascon, J. M. Comparative Studies on the Phase Stability, Electronic Structure, and Topology of the Charge Density in the Li3XO4 (X = P, As, V) Lithium Orthosalt Polymorphs. Chem. Mater. 21, 1861-1874 (2009).
22. Zemann J. Die kristallstruktur von lithiumphosphat, Li3PO4. Acta Crystallogr. 13, 863-867 (1960).
23. Keffer, C., Mighell, A., Mauer, F., Swanson, H., Block, S. Crystal structure of twinned low-temperature lithium phosphate. Inorg. Chem. 6, 119-125 (1967).
24. Laumann, ,A. Boysen, H., Bremholm, M., Fehr, K. T., Hoelzel, M., Holzapfel, M. Lithium Migration at High Temperatures in Li4Ti5O12 Studied by Neutron Diffraction. Chem. Mater. 23, 2753-2759 (2011).
25. Rezaee, M., Khoie, S. M. M., Liu, K. H. The role of brookite in mechanical activation of anatase-to-rutile transformation of nanocrystalline TiO2: An XRD and Raman spectroscopy investigation. Cryst Eng Comm, 13, 5055-5061 (2011).
26. Bondareva O. S., Simonov M. A., Belov N. V. The crystal structure of the synthetic analogue of the lithiophospate gamma-Li3PO4. Doklady Akademii Nauk SSSR 240, 75-77 (1978).
27. Wang, D., Xiao, J., Xu, W., Nie, Z., Wang, C., Graff, G., Zhang, J. G. Preparation and electrochemical investigation of Li2CoPO4F cathode material for lithium-ion batteries. J. Power Sources 196, 2241-2245 (2011).
28. Amaresh, S., Karthikeyan, K., Kim, K. J., Kim, M. C., Chung, K. Y., Cho, B. W., Lee, Y. S. Facile synthesis of ZrO2 coated Li2CoPO4F cathode materials for lithium secondary batteries with improved electrochemical properties. J. Power Sources 244, 395-402 (2013).
29. Amaresh, S., Karthikeyan, K., Kim, K. J., An, J. Y., Cho, S. J., Chung, K. Y., Cho, B. W., Nam, K. W., Lee Y. S. Metal Oxide Coated Lithium Cobalt Fluorophosphate Cathode Materials for Lithium Secondary Batteries-Effect of Aging and Temperature. J. Nanosci. Nanotechnol. 14, 7545-7552 (2014).
30. Okumura, T., Shikano, M., Yamaguchi, Y., Kobayashi, H. Structural Changes in Li2CoPO4F during Lithium-Ion Battery Reactions. Chem. Mater. 27, 2839-2847 (2015).
31. Jung, H. G., Jang, M. W., Hassoun, J., Sun, Y. K., Scrosati, B. A high-rate long-life Li4Ti5O12/Li[Ni0.45Co0.1Mn1.45]O4 lithium-ion battery. Nat. Commun. 2, 516 (2011).
32. Swiderska-Mocek A. Application of quaternary polymer electrolyte based on ionic liquid in LiFePO4/Li, Li4Ti5O12/Li and LiFePO4/Li4Ti5O12 batteries. Electrochim. Acta 139, 337-344 (2014).
33. Kim, J. W., Kim, D. H., Oh, D. Y., Lee, H., Kim, J. H., Lee, J. H., Jung, Y. S. Surface chemistry of LiNi0.5Mn1.5O4 particles coated by Al2O3 using atomic layer deposition for lithium-ion batteries. J. Power Sources 274, 1254-1262 (2015).
34. Prosini, P. P., Cento, C., Pozio, A. Lithium-ion batteries based on titanium oxide nanotubes and LiFePO4. J. Solid State Electrochem. 18, 795-804 (2014).
35. Hassoun, J., Bonaccorso, F., Agostini, M., Angelucci, M., Betti, M. G., Cingolani, R., Gemmi, M., Mariani, C., Panero, S., Pellegrini, V., Scrosati, B. An Advanced Lithium-Ion Battery Based on a Graphene Anode and a Lithium Iron Phosphate Cathode. Nano Lett. 14, 4901-4906 (2014).
36. Verrelli, R., Scrosati, B., Sun, Y. K., Hassoun J. Stable, High Voltage Li0.85Ni0.46Cu0.1Mn1.49O4 Spinel Cathode in a Lithium-Ion Battery Using a Conversion-Type CuO Anode. ACS Appl. Mater. Interfaces. 6, 5206-5211 (2014).
37. Zaghib, K., Simoneau, M., Armand, M., Gauthier, M. Electrochemical study of Li4Ti5O12 as negative electrode for Li-ion polymer rechargeable batteries. J. Power Sources 81-82, 300-305 (1999).
38. Ronci, F., Reale, P., Scrosati, B., Rossi Albertini, V., Perfietti, P., Di Michiel, M., Merino, J. M. High-Resolution In-Situ Structural Measurements of the Li4/3Ti5/3O4 "Zero-Strain" Insertion Material. J. Phys. Chem. B 106, 3082-3086 (2002).
39. Aldon, L., Kubiak, P., Womes, M., Jumas, J. C., Olivier-Fourcade, J., Tirado, J. L. Corredor, J. I., Pérez Vicente, C. Chemical and Electrochemical Li-Insertion into the Li4Ti5O12 Spinel. Chem. Mater. 16, 5721-5725 (2004).