Chemical routes toward long-lasting lithium/sulfur cells

Nano Research

Volumn 9, Issue 1, 2016, Pages 94-116

  Liu, Meinan ^a   Ye, Fangmin ^a   Li, Wanfei ^a   Li, Hongfei ^b   Zhang, Yuegang ^a,b  

^a SUZHOU INSTITUTE OF NANO TECH AND NANO BIONICS   (China)

^b TSINGHUA UNIVERSITY   (China)

Author keywords

additive; chemical bonding; functional group; lithium polysulfide; lithium sulfur battery

Indexed keywords

ADDITIVES; CARBON; CHEMICAL BONDS; FUNCTIONAL GROUPS; LITHIUM-ION BATTERIES; METAL WORKING; POLYSULFIDES;

CARBON NANOSTRUCTURES; CHEMICAL BONDINGS; CHEMICAL INTERACTIONS; CYCLING PERFORMANCE; LITHIUM/SULFUR BATTERIES; LITHIUM/SULFUR CELLS; POLYMER ADDITIVE; WORKING MECHANISMS;

LITHIUM COMPOUNDS;

EID: 84956908027     PISSN: 19980124     EISSN: 19980000     Source Type: Journal    
DOI: 10.1007/s12274-016-1027-8     Document Type: Review

References (87)

1. Turner, J. A. A realizable renewable energy future. Science1999, 285, 687–689.
2. Goodenough, J. B. Evolution of strategies for modern rechargeable batteries. Acc. Chem. Res.2013, 46, 1053–1061.
3. Li, N.; Weng, Z.; Wang, Y.; Li, F.; Cheng, H. M.; Zhou, H. An aqueous dissolved polysulfide cathode for lithium–sulfur batteries. Energy Environ. Sci.2014, 7, 3307–3312.
4. 2S@C nanocomposite cathode with a nitrogen-doped carbon nanotube top current collector. J. Mater. Chem. A2015, 3, 18913–18919.
5. Xu, J.; Shui, J.; Wang, J.; Wang, M.; Liu, H. K.; Dou, S. X.; Jeon, I. Y.; Seo, J. M.; Baek, J. B.; Dai, L. Sulfur-graphene nanostructured cathodes via ball-milling for high-performance lithium–sulfur batteries. ACS Nano2014, 8, 10920–10930.
6. Ji, X. L.; Lee, K. T.; Nazar, L. F. A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries. Nat. Mater.2009, 8, 500–506.
7. 2S core–shell spheres for high performance lithium/sulfur cells. J. Am. Chem. Soc.2014, 136, 4659–4663.
8. Moon, S.; Jung, Y. H.; Jung, W. K.; Jung, D. S.; Choi, J. W.; Kim, D. K. Encapsulated monoclinic sulfur for stable cycling of Li–S rechargeable batteries. Adv. Mater.2013, 25, 6547–6553.
9. Zhang, C. F.; Wu, H. B.; Yuan, C. Z.; Guo, Z. P.; Lou, X. W. Confining sulfur in double-shelled hollow carbon spheres for lithium–sulfur batteries. Angew. Chem., Int. Ed.2012, 51, 9592–9595.
10. Elazari, R.; Salitra, G.; Garsuch, A.; Panchenko, A.; Aurbach, D. Sulfur-impregnated activated carbon fiber cloth as a binder-free cathode for rechargeable Li–S batteries. Adv. Mater.2011, 23, 5641–5644.
11. Li, H. F.; Yang, X. W.; Wang, X. M.; Liu, M. N.; Ye, F. M.; Wang, J.; Qiu, Y. C.; Li, W. F.; Zhang, Y. G. Dense integration of graphene and sulfur through the soft approach for compact lithium/sulfur battery cathode. Nano Energy2015, 12, 468–475.
12. Ji, L. W.; Rao, M. M.; Aloni, S.; Wang, L.; Cairns, E. J.; Zhang, Y. G. Porous carbon nanofiber–sulfur composite electrodes for lithium/sulfur cells. Energy Environ. Sci.2011, 4, 5053–5059.
13. 2S cell cathodes. Nanoscale2015, 7, 9472–9476.
14. Zheng, G. Y.; Yang, Y.; Cha, J. J.; Hong, S. S.; Cui, Y. Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries. Nano Lett.2011, 11, 4462–4467.
15. Wang, H. L.; Yang, Y.; Liang, Y. Y.; Robinson, J. T.; Li, Y. G.; Jackson, A.; Cui, Y.; Dai, H. J. Graphene-wrapped sulfur particles as a rechargeable lithium–sulfur battery cathode material with high capacity and cycling stability. Nano Lett.2011, 11, 2644–2647.
16. Xin, S.; Gu, L.; Zhao, N. H.; Yin, Y. X.; Zhou, L. J.; Guo, Y. G.; Wan, L. J. Smaller sulfur molecules promise better lithium–sulfur batteries. J. Am. Chem. Soc.2012, 134, 18510–18513.
17. Yang, C. P.; Yin, Y. X.; Guo, Y. G.; Wan, L. J. Electrochemical (de)lithiation of 1D sulfur chains in Li–S batteries: Amodel system study. J. Am. Chem. Soc.2015, 137, 2215–2218.
18. Li, L.; Ruan, G.; Peng, Z.; Yang, Y.; Fei, H.; Raji, A. R. O.; Samuel, E. L. G.; Tour, J. M. Enhanced cycling stability of lithium sulfur batteries using sulfur-polyaniline-graphene nanoribbon composite cathodes. ACS Appl. Mater. Interfaces2014, 6, 15033–15039.
19. Zheng, S. Y.; Yi, F.; Li, Z. P.; Zhu, Y. J.; Xu, Y. H.; Luo, C.; Yang, J. H.; Wang, C. S. Copper-stabilized sulfur–microporous carbon cathodes for Li–S batteries. Adv. Funct. Mater.2014, 24, 4156–4163.
20. Xiao, L. F.; Cao, Y. L.; Xiao, J.; Schwezer, B.; Engelhard, M. H.; Saraf, L. V.; Nie, Z. M.; Exarhos, G. J.; Liu, J. A soft approach to encapsulate sulfur: Polyaniline nanotubes for lithium–sulfur batteries with long cycle life. Adv. Mater.2012, 24, 1176–1181.
21. Ji, L. W.; Rao, M. M.; Zheng, H. M.; Zhang, L.; Li, Y. C.; Duan, W. H.; Guo, J. H.; Cairns, E. J.; Zhang, Y. G. Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells. J. Am. Chem. Soc.2011, 133, 18522–18525.
22. Qiu, Y. C.; Rong, G. L.; Yang, J.; Li, G. Z.; Ma, S.; Wang, X. L.; Pan, Z. H.; Hou, Y.; Liu, M. N.; Ye, F. M. et al. Highly nitridated graphene–Li2S cathodes with stable modulated cycles. Adv. Energy Mater.2015, 5, 1501369.
23. Demir-Cakan, R.; Morcrette, M.; Nouar, F.; Davoisne, C.; Devic, T.; Gonbeau, D.; Dominko, R.; Serre, C.; Gerey, G.; Tarascon, J. M. Cathode composites for Li–S batteries via the use of oxygenated porous architectures. J. Am. Chem. Soc.2011, 133, 16154–16160.
24. Evers, S.; Yim, T.; Nazar, L. F. Understanding the nature of absorption/adsorption in nanoporous polysulfide sorbents for the Li–S battery. J. Phys. Chem. C2012, 116, 19653–19658.
25. Chung, S. H.; Manthiram, A. A natural carbonized leaf as polysulfide diffusion inhibitor for high-performance lithium–sulfur battery cells. ChemSusChem2014, 7, 1655–1661.
26. Song, M. K.; Zhang, Y. G.; Cairns, E. J. A long-life, high-rate lithium/sulfur cell: Amultifaceted approach to enhancing cell performance. Nano Lett.2013, 13, 5891–5899.
27. Qiu, Y. C.; Li, W. F.; Zhao, W.; Li, G. Z.; Hou, Y.; Liu, M. N.; Zhou, L. S.; Ye, F. M.; Li, H. F.; Wie, Z. H. et al. High-rate, ultralong cycle-life lithium/sulfur batteries enabled by nitrogen-doped graphene. Nano Lett.2014, 14, 4821–4827.
28. Manthiram, A.; Fu, Y.Z.; Chung, S. H.; Zu, C. X.; Su, Y. S. Rechargeable lithium–sulfur batteries. Chem. Rev.2014, 114, 11751–11787.
29. Song, M. K.; Cairns, E. J.; Zhang, Y. G. Lithium/sulfur batteries with high specific energy: Old challenges and new opportunities. Nanoscale2013, 5, 2186–2204.
30. Kim, H.; Lee, J. T.; Lee, D. C.; Magasinski, A.; Cho, W.; Yushin, G. Plasma-enhanced atomic layer deposition of ultrathin oxide coatings for stabilized lithium–sulfur batteries. Adv. Energy Mater.2013, 3, 1308–1315.
31. Yin, Y. X.; Xin, S.; Guo, Y. G.; Wan, L. J. Lithium–sulfur batteries: Electrochemistry, materials, and prospects. Angew. Chem., Int. Ed.2013, 52, 13186–13200.
32. Fronczek, D. N.; Bessler, W. G. Insight into lithium–sulfur batteries: Elementary kinetic modeling and impedance simulation. J. Power Source2013, 244, 183–188.
33. Fu, Y. Z.; Su, Y. S.; Manthiram, A. Highly reversible lithium/dissolved polysulfide batteries with carbon nanotube electrodes. Angew. Chem., Int. Ed.2013, 52, 6930–6935.
34. Chung, S. H.; Singhal, R.; Kalra, V.; Manthiram, A. Porous carbon mat as an electrochemical testing platform for investigating the polysulfide retention of various cathode configurations in Li–S cells. J. Phys. Chem. Lett.2015, 6, 2163–2169.
35. Su, Y. S.; Fu, Y. Z.; Guo, B. K.; Dai, S.; Manthiram, A. Fast, reversible lithium storage with a sulfur/long-chainpolysulfide redox couple. Chem.—Eur. J.2013, 19, 8621–8626.
36. Xu, R.; Lu, J.; Amine, K. Progress in mechanistic understanding and characterization techniques of Li–S batteries. Adv. Energy Mater.2015, 5, 1500408.
37. Zhang, S. G.; Ueno, K.; Dokko, K.; Watanabe M. Recent advances in electrolytes for lithium–sulfur batteries. Adv. Energy Mater.2015, 5, 1500117.
38. Evers, S.; Nazar, L. F. New approaches for high energy density lithium–sulfur battery cathodes. Acc. Chem. Res.2013, 46, 1135–1143.
39. Manthiram, A.; Fu, Y. Z.; Su, Y. S. Challenges and prospects of lithium–sulfur batteries. Acc. Chem. Res.2013, 46, 1125–1134.
40. Zheng, G. Y.; Zhang, Q. F.; Cha, J. J.; Yang, Y.; Li, W. Y.; Seh, Z. W.; Cui, Y. Amphiphilic surface modification of hollow carbon nanofibers for improved cycle life of lithium sulfur batteries. Nano Lett.2013, 13, 1265–1270.
41. Zhou, W. D.; Yu, Y. C.; Chen, H.; Disalvo, F. J.; Abruña, H. D. Yolk–shell structure of polyaniline-coated sulfur for lithium–sulfur batteries. J. Am. Chem. Soc.2013, 135, 16736–16743.
42. Barchasz, C.; Lepretre, J. C.; Alloin, F.; Patoux, S. New insights into the limiting parameters of the Li/S rechargeable cell. J. Power Sources2012, 199, 322–330.
43. Sun, H.; Xu, G. L.; Xu, Y. F.; Sun, S. G.; Zhang, X. F.; Qiu, Y. C.; Yang, S. H. A composite material of uniformly dispersed sulfur on reduced graphene oxide: Aqueous one-pot synthesis, characterization and excellent performance as the cathode in rechargeable lithium–sulfur batteries. Nano Res.2012, 5, 726–738.
44. Zhao, C. Y.; Liu, L. J.; Zhao, H. L.; Krall, A.; Wen, Z. H.; Chen, J. H.; Hurley, P.; Jiang, J. W.; Li, Y. Sulfur-infiltrated porous carbon microspheres with controllable multi-modal pore size distribution for high energy lithium–sulfur batteries. Nanoscale2014, 6, 882–888.
45. Chung, S. H.; Han, P.; Singhal, R.; Kalra, V.; Manthiram, A. Electrochemically stable rechargeable lithium–sulfur batteries with a microporous carbon nanofiber filter for polysulfide. Adv. Energy Mater.2015, 5, 1500738.
46. Chung, S. H.; Manthiram, A. Bifunctional separator with a light-weight carbon-coating for dynamically and statically stable lithium–sulfur batteries. Adv. Funct. Mater.2014, 24, 5299–5306.
47. Chung, S. H.; Manthiram, A. High-performance Li–S batteries with an ultra-lightweight MWCNT-coated separator. J. Phys. Chem. Lett.2014, 5, 1978–1983.
48. Chung, S. H.; Manthiram, A. A polyethylene glycolsupported microporous carbon coating as a polysulfide trap for utilizing pure sulfur cathodes in lithium–sulfur batteries. Adv. Mater.2014, 26, 7352–7357.
49. Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Li–O2 and Li–S batteries with high energy storage. Nat. Mater.2012, 11, 19–29.
50. Mikhaylik, Y. V.; Akridge, J. R. Polysulfide shuttle study in the Li/S battery system. J. Electrochem. Soc.2004, 151, A1969?A1976.
51. Huang, J. Q.; Zhang, Q.; Peng, H. J.; Liu, X. Y.; Qian, W. Z.; Wie, F. Ionic shield for polysulfides towards highly-stable lithium–sulfur batteries. Energy Environ. Sci.2014, 7, 347–353.
52. Liang, X.; Hart, C.; Pang, Q.; Garsuch, A.; Weiss, T.; Nazar, L. F. A highly efficient polysulfide mediator for lithium–sulfur batteries. Nat. Commun.2015, 6, 5682.
53. Oschatz, M.; Borchardt, L.; Pinkert, K.; Thieme, S.; Lohe, M. R.; Hoffmann, C.; Benusch, M.; Wisser, F. M.; Ziegler, C.; Giebeler, L. et al. Hierarchical carbide-derived carbon foams with advanced mesostructure as a versatile electrochemical energy-storage material. Adv. Energy Mater.2014, 4, 1300645.
54. Li, Z.; Jiang, Y.; Yuan, L. X.; Yi, Z. Q.; Wu, C.; Liu, Y.; Strasser, P.; Huang, Y. H. A highly ordered meso@microporous carbon-supported sulfur@smaller sulfur core–shell structured cathode for Li–S batteries. ACS Nano2014, 8, 9295–9303.
55. Jayaprakash, N.; Shen, J.; Moganty, S. S.; Corona, A.; Archer, L. A. Porous hollow carbon@sulfur composites for high-power lithium–sulfur batteries. Angew. Chem., Int. Ed.2011, 50, 5904–5908.
56. He, G.; Evers, S.; Liang, X.; Cuisinier, M.; Garsuch, A.; Nazar, L. F. Tailoring porosity in carbon nanospheres for lithium–sulfur battery cathodes. ACS Nano2013, 7, 10920–10930.
57. Zhou, G. M.; Li, L.; Wang, D. W.; Shan, X. Y.; Pei, S. F.; Li, F.; Cheng, H. M. A flexible sulfur-graphene-polypropylene separator integrated electrode for advanced Li–S batteries. Adv. Mater.2015, 27, 641–647.
58. Chen, H. W.; Dong, W. L.; Ge, J.; Wang, C. H.; Wu, X. D.; Lu, W.; Chen, L. W. Ultrafine sulfur nanoparticles in conducting polymer shell as cathode materials for high performance lithium/sulfur batteries. Sci. Rep.2013, 3, 1910.
59. Chen, Y. M.; Li, X. Y.; Park, K. S.; Hong, J. H.; Song, J.; Zhou, L. M.; Mai, Y. W.; Huang, H. T.; Goodenough, J. B. Sulfur encapsulated in porous hollow CNTs@CNFs for high-performance lithium–sulfur batteries. J. Mater. Chem. A2014, 2, 10126–10130.
60. Zhang, L.; Ji, L. W.; Glans, P. A.; Zhang, Y. G.; Zhu, J. F.; Guo, J. H. Electronic structure and chemical bonding of a graphene oxide–sulfur nanocomposite for use in superior performance lithium–sulfur cells. Phys. Chem. Chem. Phys.2012, 14, 13670–13675.
61. Zhou, G. M.; Yin, L. C.; Wang, D. W.; Li, L.; Pei, S. F.; Gentle, I. R.; Li, F.; Cheng, H. M. Fibrous hybrid of graphene and sulfur nanocrystals for high-performance lithium–sulfur batteries. ACS Nano2013, 7, 5367–5375.
62. Feng, X. F.; Song, M. K.; Stolte, W. C.; Gardenghi, D.; Zhang, D.; Sun, X. H.; Zhu, J. F.; Cairns, E. J.; Guo, J. H. Understanding the degradation mechanism of rechargeable lithium/sulfur cells: A comprehensive study of the sulfur–graphene oxide cathode after discharge–charge cycling. Phys. Chem. Chem. Phys.2014, 16, 16931–16940.
63. Yang, C. P.; Yin, Y. X.; Ye, H.; Jiang, K. C.; Zhang, J.; Guo, Y. G. Insight into the effect of boron doping on sulfur/carbon cathode in lithium–sulfur batteries. ACS Appl. Mater. Interfaces2014, 6, 8789–8795.
64. Seh, Z. W.; Wang, H. T.; Hsu, P. C.; Zhang, Q. F.; Li, W. Y.; Zheng, G. Y.; Yao, H. B.; Cui, Y. Facile synthesis of Li2S–polypyrrole composite structures for high-performance Li2S cathodes. Energy Environ. Sci.2014, 7, 672–676.
65. Song, J. X.; Xu, T.; Gordin, M. L.; Zhu, P. Y.; Lv, D. P.; Jiang, Y. B.; Chen, Y. S.; Duan, Y. H.; Wang, D. H. Nitrogendoped mesoporous carbon promoted chemical adsorption of sulfur and fabrication of high-areal-capacity sulfur cathode with exceptional cycling stability for lithium–sulfur batteries. Adv. Funct. Mater.2014, 24, 1243–1250.
66. Guo, J. C.; Yang, Z. C.; Yu, Y. C.; Abruña, H. D.; Archer, L. A. Lithium–sulfur battery cathode enabled by lithium–nitrile interaction. J. Am. Chem. Soc.2013, 135, 763–767.
67. Song, J. X.; Gordin, M. L.; Xu, T.; Chen, S. R.; Yu, Z. X.; Sohn, H.; Lu, J.; Ren, Y.; Duan, Y. H.; Wang, D. H. Strong lithium polysulfide chemisorption on electroactive sites of nitrogen-doped carbon composites for high-performance lithium–sulfur battery cathodes. Angew. Chem., Int. Ed.2015, 54, 4325–4329.
68. Tang, C.; Zhang, Q.; Zhao, M. Q.; Huang, J. Q.; Cheng, X. B.; Tian, G. L.; Peng, H. J.; Wei, F. Nitrogen-doped aligned carbon nanotube/graphene sandwiches: Facile catalytic growth on bifunctional natural catalysts and their applications as scaffolds for high-rate lithium–sulfur batteries. Adv. Mater.2014, 26, 6100–6105.
69. Pang, Q.; Tang, J. T.; Huang, H.; Liang, X.; Hart, C.; Tam, K. C.; Nazar, L. F. A nitrogen and sulfur dual-doped carbon derived from polyrhodanine@cellulose for advanced lithium–sulfur batteries. Adv. Mater.2015, 27, 6021–6028.
70. Zhou, G. M.; Paek, E.; Hwang, G. S.; Manthiram, A. Longlife Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphurcodoped graphene sponge. Nat. Commun.2015, 6, 7760.
71. 2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulfur batteries. Nat. Commun.2013, 4, 1331.
72. Yao, H. B.; Zheng, G. Y.; Hsu, P. C.; Kong, D. S.; Cha, J. J.; Li, W. Y.; Seh, Z. W.; McDowell, M. T.; Yan, K.; Liang, Z. et al. Improving lithium–sulphur batteries through spatial control of sulphur species deposition on a hybrid electrode surface. Nat. Commun.2014, 5, 3943.
73. 2n–1 nanomaterials for improving lithium–sulfur batteries. Nano Lett.2014, 14, 5288–5294.
74. Pang, Q.; Kundu, D.; Cuisinier, M.; Naza, L. F. Surfaceenhanced redox chemistry of polysulphides on a metallic and polar host for lithium–sulphur batteries. Nat. Commun.2015, 5, 4759.
75. Song, M. S.; Han, S. C.; Kim, H. S.; Kim, J. H.; Kim, K. T.; Kang, Y. M.; Ahn, H. J.; Dou, S. X.; Lee, J. Y. Effects of nanosized adsorbing material on electrochemical properties of sulfur cathodes for Li/S secondary batteries. J. Electrochem. Soc.2004, 151, A791–A795.
76. 0.4O composite cathodes for high performance lithium/sulfur batteries. J. Mater. Chem. A2013, 1, 295–301.
77. 3 for lithium/sulfur cell. Phys. Scr.2007, T129, 62.
78. Ji, X. L.; Evers, S.; Black, R.; Nazar, L. F. Stabilizing lithium–sulphur cathodes using polysulphide reservoirs. Nat. Commun.2011, 2, 325.
79. Liang, Z.; Zheng, G. Y.; Li, W. Y.; Seh, Z. W.; Yao, H. B.; Yan, K.; Kong, D. S.; Cui, Y. Sulfur cathodes with hydrogen reduced titanium dioxide inverse opal structure. ACS Nano2014, 8, 5249–5256.
80. 3 nanoparticles. J. Mater. Chem. A2013, 1, 13283–13289.
81. 2 matrix for enhancing Li–S battery performance. Adv. Mater. Interfaces2015, 2, 1500048.
82. Liang, X.; Garsuch, A.; Nazar, L. F. Sulfur cathodes based on conductive MXene nanosheets for high-performance lithium–sulfur batteries. Angew. Chem., Int. Ed.2015, 54, 3907–3911.
83. Zhang, Q. F.; Wang, Y. F.; Seh, Z. W.; Fu, Z. H.; Zhang, R. F.; Cui, Y. Understanding the anchoring effect of twodimensional layered materials for lithium–sulfur batteries. Nano Lett.2015, 15, 3780–3786.
84. Gu, M. S.; Lee, J.; Kim, Y.; Kim, J. S.; Jang, B. Y.; Lee, K. T.; Kim, B. S. Inhibiting the shuttle effect in lithium–sulfur batteries using a layer-by-layer assembled ion-permselective separator. RSC Adv.2014, 4, 46940–46946.
85. She, Z. W.; Zhang, Q. F.; Li, W. Y.; Zheng, G. Y.; Yao, H. B.; Cui, Y. Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder. Chem. Sci.2013, 4, 3673–3677.
86. Park, K.; Cho, J. H.; Jang, J. H.; Yu, B. C.; De La Hoz, A. T.; Miller, K. M.; Ellison, C. J.; Goodenough, J. B. Trapping lithium polysulfides of a Li–S battery by forming lithium bonds in a polymer matrix. Energy Environ. Sci.2015, 8, 2389–2395.
87. Chen, H. W.; Wang, C. H.; Dai, Y. F.; Qiu, S. Q.; Yang, J. L.; Lu, W.; Chen, L. W. Rational design of cathode structure for high rate performance lithium-sulfur batteries. Nano Lett.2015, 15, 5443–5448.