Photochemical Reduction of Low Concentrations of CO2 in a Porous Coordination Polymer with a Ruthenium(II)-CO Complex

Angewandte Chemie - International Edition

Volumn 55, Issue 8, 2016, Pages 2697-2700

  Kajiwara, Takashi ^a   Fujii, MacHiko ^a   Tsujimoto, Masahiko ^a   Kobayashi, Katsuaki ^a   Higuchi, Masakazu ^a,b   Tanaka, Koji ^a   Kitagawa, Susumu ^a,b,c  

^a KYOTO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c KYOTO UNIVERSITY   (Japan)

Author keywords

carbon dioxide fixation; metal organic frameworks; microporous materials; photocatalysis; ruthenium

Indexed keywords

ADSORPTION; CARBON; CARBON DIOXIDE; CATALYSTS; COORDINATION REACTIONS; CRYSTALLINE MATERIALS; ENERGY CONSERVATION; GAS MIXTURES; GASES; MICROPOROUS MATERIALS; ORGANOMETALLICS; PHOTOCATALYSIS; RUTHENIUM; RUTHENIUM COMPOUNDS;

ADSORPTION BEHAVIOR; CARBON DIOXIDE FIXATION; HETEROGENEOUS CATALYST; LOW CONCENTRATIONS; METAL ORGANIC FRAMEWORK; PHOTOCHEMICAL REDUCTION; POROUS COORDINATION POLYMER; SYNERGISTIC EFFECT;

CATALYST ACTIVITY;

EID: 84956866954     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201508941     Document Type: Article

References (46)

1. S. N. Riduan, Y. Zhang, Dalton Trans. 2010, 39, 3347-3357;
2. C. Federsel, R. Jackstell, M. Beller, Angew. Chem. Int. Ed. 2010, 49, 6254-6257;
3. Angew. Chem. 2010, 122, 6392-6395.
4. P. Markewitz, W. Kuckshinrichs, W. Leitner, J. Linssen, P. Zapp, R. Bongartz, A. Schreiber, T. E. Müller, Energy Environ. Sci. 2012, 5, 7281-7305;
5. A. Goeppert, M. Czaun, J.-P. Jones, G. K. Surya Prakash, G. A. Olah, Chem. Soc. Rev. 2014, 43, 7995-8048.
6. S. Kitagawa, R. Kitaura, S.-i. Noro, Angew. Chem. Int. Ed. 2004, 43, 2334-2375;
7. Angew. Chem. 2004, 116, 2388-2430.
8. D. Farrusseng, S. Aguado, C. Pinel, Angew. Chem. Int. Ed. 2009, 48, 7502-7513;
9. Angew. Chem. 2009, 121, 7638-7649;
10. A. Dhakshinamoorthy, M. Alvaro, H. Garcia, Chem. Commun. 2012, 48, 11275-11288;
11. J. Gascon, A. Corma, F. Kapteijn, F. X. Llabrés i Xamena, ACS Catal. 2014, 4, 361-378.
12. For a recent review, see:, C.-C. Wang, Y.-Q. Zhang, J. Li, P. Wang, J. Mol. Struct. 2015, 1083, 127-136.
13. For PCPs with metal clusters of the frameworks as active sites, see:
14. Y. Fu, D. Sun, Y. Chen, R. Huang, Z. Ding, X. Fu, Z. Li, Angew. Chem. Int. Ed. 2012, 51, 3364-3367;
15. Angew. Chem. 2012, 124, 3420-3423;
16. S. Wang, W. Yao, J. Lin, Z. Ding, X. Wang, Angew. Chem. Int. Ed. 2014, 53, 1034-1038;
17. Angew. Chem. 2014, 126, 1052-1056;
18. Y. Lee, S. Kim, J. K. Kang, S. M. Cohen, Chem. Commun. 2015, 51, 5735-5738.
19. For PCPs with metallolinkers as active sites, see:
20. C. Wang, Z. Xie, K. E. deKrafft, W. Lin, J. Am. Chem. Soc. 2011, 133, 13445-13454;
21. L. Li, S. Zhang, L. Xu, J. Wang, L.-X. Shi, Z.-N. Chen, M. Hong, J. Luo, Chem. Sci. 2014, 5, 3808-3813;
22. A. Burgun, R. S. Crees, M. L. Cole, C. J. Doonan, C. J. Sumby, Chem. Commun. 2014, 50, 11760-11763;
23. D. Sun, Y. Gao, J. Fu, X. Zeng, Z. Chen, Z. Li, Chem. Commun. 2015, 51, 2645-2648;
24. M. B. Chambers, X. Wang, N. Elgrishi, C. H. Hendon, A. Walsh, J. Bonnefoy, J. Canivet, E. A. Quadrelli, D. Farrusseng, C. Mellot-Draznieks, M. Fontecave, ChemSusChem 2015, 8, 603-608;
25. H. Fei, M. D. Sampson, Y. Lee, C. P. Kubiak, S. M. Cohen, Inorg. Chem. 2015, 54, 6821-6828.
26. For PCP composites with inorganic materials as active sites, see:
27. R. Li, J. Hu, M. Deng, H. Wang, X. Wang, Y. Hu, H.-L. Jiang, J. Jiang, Q. Zhang, Y. Xie, Y. Xiong, Adv. Mater. 2014, 26, 4783-4788;
28. W. Zhen, B. Li, G. Lu, J. Ma, Chem. Commun. 2015, 51, 1728-1731.
29. K. Sumida, D. L. Rogow, J. A. Mason, T. M. McDonald, E. D. Bloch, Z. R. Herm, T.-H. Bae, J. R. Long, Chem. Rev. 2012, 112, 724-781.
30. H. Nagao, T. Mizukawa, K. Tanaka, Inorg. Chem. 1994, 33, 3415-3420.
31. J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851.
32. M. Kim, J. F. Cahill, Y. Su, K. A. Prather, S. M. Cohen, Chem. Sci. 2012, 3, 126-130;
33. O. Karagiaridi, W. Bury, A. A. Sarjeant, C. L. Stern, O. K. Farha, J. T. Hupp, Chem. Sci. 2012, 3, 3256-3260;
34. S. Takaishi, E. J. DeMarco, M. J. Pellin, O. K. Farha, J. T. Hupp, Chem. Sci. 2013, 4, 1509-1513;
35. H. Fei, S. M. Cohen, Chem. Commun. 2014, 50, 4810-4812.
36. P. Xydias, I. Spanopoulos, E. Klontzas, G. E. Froudakis, P. N. Trikalitis, Inorg. Chem. 2014, 53, 679-681;
37. B. Wang, H. Huang, X.-L. Lv, Y. Xie, M. Li, J.-R. Li, Inorg. Chem. 2014, 53, 9254-9259.
38. J. B. DeCoste, G. W. Peterson, H. Jasuja, T. G. Glover, Y.-g. Huang, K. S. Walton, J. Mater. Chem. A 2013, 1, 5642-5650;
39. L. Li, S. Tang, C. Wang, X. Lv, M. Jiang, H. Wu, X. Zhao, Chem. Commun. 2014, 50, 2304-2307.
40. [6b]
41. C. Gomes Silva, I. Luz, F. X. Llabrés i Xamena, A. Corma, H. García, Chem. Eur. J. 2010, 16, 11133-11138.
42. II composite and not a leached complex.
43. M. D. Doherty, D. C. Grills, J. T. Muckerman, D. E. Polyansky, E. Fujita, Coord. Chem. Rev. 2010, 254, 2472-2482;
44. K. Kobayashi, K. Tanaka, Phys. Chem. Chem. Phys. 2014, 16, 2240-2250.
45. A solvent effect on the CO/HCOOH ratio was observed for both 1 and 3 (Supporting Information, Table S7).
46. [7d,f] where the CO/HCOOH ratio was, in contrast to our results, lower in the case of PCP-based catalysts.