Poly(dimethylsiloxane) chains at a silica surface

Organosilicon Chemistry II: From Molecules to Materials

Volumn , Issue , 1996, Pages 779-814

  Litvinov, V M ^a  

^a DSM RESEARCH   (Netherlands)

Author keywords

Adsorption; Dimethylsiloxane; Elasticity; Mobility; Stress strain

Indexed keywords

ADSORPTION; CARRIER MOBILITY; DEFORMATION; ELASTICITY; ELASTOMERS; FILLERS; GLASS TRANSITION; HYDROPHILICITY; HYDROPHOBICITY; MATRIX ALGEBRA; MICROCHANNELS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PLASTICS; RUBBER; SILICA; TEMPERATURE; TENSILE STRENGTH; TOPOLOGY;

DIMETHYLSILOXANE; HYDROPHILIC AND HYDROPHOBIC; HYDROPHOBIC AND HYDROPHILIC; INCREASING TEMPERATURES; MOLECULAR CHARACTERISTICS; STRESS STRAIN; STRESS-STRAIN BEHAVIORS; WIDE TEMPERATURE RANGES;

CHAINS;

EID: 84955693176     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527619894.ch92     Document Type: Chapter

References (61)

1. M.-J. Wang, S. Wolff, Rubber Chem. Techn. 1991, 64, 559
2. J.-B. Donnet, Kautschuk, Gummi, Kunststoffe 1994, 47, 628.
3. M.-J. Wang, S. Wolff, J.-B. Donnet, Kautschuk, Gummi, Kunststoffe 1992, 45, 11
4. S. Wolf, E. E. Tan, J.-B. Donnet, Kautschuk Gummi, Kunststoffe 1994, 47, 485.
5. A. Yim, R. S. Chahal, L. E. St. Pierre, J. Colloid Interface Sci. 1973, 43, 583.
6. T. Cosgrove, P. C. Griffiths, Adv. in Colloid Interface Sci. 1992, 42, 175; and references therein.
7. B. V. Deryagin, V. V. Karasev, I. A. Lavygin, I. I. Skorokhodov, E. N. Khomova, Dokl. Akad. Nauk USSR 1969, 187, 846.
8. I. Bitsanis, G. Hadziioannou, J. Chem. Phys. 1990, 92, 3827.
9. V. M. Litvinov, A. A. Zhdanov, Dokl. Phys. Chem. 1985, 283, 811
10. Dokl. Phys. Chem 1986, 290, 916.
11. V. M. Litvinov, A. A. Zhdanov, Polym. Sci. USSR 1987, 29, 1133.
12. V. M. Litvinov, Polym. Sci. USSR 1988, 30, 2250.
13. V. M. Litvinov, M. Wobst, D. Reichert, H. Schneider, A. A. Zhdanov, Acta Polymerica 1988, 39, 243.
14. V. M. Litvinov, A. A. Zhdanov, Dokl. Phys. Chem. 1986, 289, 759.
15. V. M. Litvinov, A. A. Zhdanov, Polym. Sci. USSR 1988, 30, 1000.
16. V. M. Litvinov, V. S. Papkov, A. A. Zhdanov, Vysokomol. Soed. 1988, B30, 343.
17. V. M. Litvinov, V. G. Vasilev, Polym. Sci. USSR 1990, 32, 2231.
18. V. M. Litvinov, Int. Polym. Sci. Technol. 1988, 15, T/28.
19. O. Girard, J. P. Cohen-Addad, Polymer 1991, 32, 860.
20. J. P. Cohen-Addad, P. Huchot, P. Jost, A. Pouchelon, Polymer 1989, 30, 143.
21. J. P. Cohen-Addad, Polymer 1989, 30, 1820
22. Polymer 1992, 33, 2762.
23. J. P. Cohen-Addad, R. Ebengou, Polymer 1992, 33, 379.
24. J. P. Cohen-Addad, S. Touzet, Polymer 1993, 34, 3490.
25. V. M. Litvinov, H. W. Spiess, Makromol. Chem. 1991, 192, 3005
26. Makromol. Chem 1992, 193, 1181.
27. J. Van Alsten, Macromolecules 1991, 24, 5320
28. D. G. Rethwisch, J. Van Alsten, C. R. Dybowski, Macromol. Symp. 1994, 86, 171.
29. V. J. McBrierty, J. C. Kenny, Kautschuk Gummi Kunststoffe 1994 47, 342; and refs. therein
30. N. K. Dutta, N. R. Choudhury, B. Haidar, A. Vidal, J. B. Donnet, L. Delmotte, J. M. Chezeau, Polymer 1994, 35, 4293; and refs. therein.
31. V. M. Litvinov, B. D. Lavrukhin, V. S. Papkov, A. A. Zhdanov, Doklady Phys. Chem. 1983, 271, 543
32. Polym. Sci. USSR 1985, 27, 1715.
33. H. W. Spiess, Adv. Polym. Sci. 1985, 66, 23.
34. V. M. Litvinov, B. D. Lavrukhin, A. A. Zhdanov, K. A. Andrianov, Polym. Sci. USSR 1977, 19, 2330.
35. K. U. Kirst, F. Kremer, V. M. Litvinov, Macromolecules 1993, 26, 975.
36. H. Pfeifer, NMR Basic Principles and Progress, Springer, Berlin, 1972, p. 53.
37. J. R. Zimmerman, W. E. Brittin, J. Phys. Chem. 1957, 61, 1328.
38. A. A. Kalachev, V. M. Litvinov, G. Wegner, Makromol. Chem., Macromol. Symp. 1991, 46, 365.
39. V. M. Litvinov, unpublished results.
40. M. Moller, Adv. Polym. Sci. 1985, 66, 59.
41. A. E. Tonelli, NMR Spectroscopy and Polymer Microstructure, The Conformational Connection, VCH, New York, 1989.
42. S. Hayashi, T. Ueda, K. Hayamizy, E. Akiba, J. Phys. Chem. 1992, 96, 10922; and references therein.
43. J. E. Mark, B. Erman, Rubberlike Elasticity. A Molecular Primer, Wiley, New York, 1988.
44. G. Simon, K. Baumann, W. Gronski, Macromolecules 1992, 25, 3624.
45. K. E. Polmanteer, C. W. Lentz, Rubber Chem. Techn. 1975, 48, 795.
46. A. Charlesby, R. Folland, J. H. Steven, Proc. Roy. SOC. (London), 1977, A 335, 189.
47. G. Kraus, Reinforcement of Elastomers, Wiley, New York, 1965.
48. E. M. Danneberg, Rubber Chem. Technol. 1975, 48, 410.
49. J. B. Donnet, A. Voet, Carbon Black Physics, Chemistry, and Elastomer Reinforcement, Marcel Dekker, New York, 1976.
50. Z. Rigbi, Adv. Polym. Sci. 1980, 36, 21.
51. J. B. Donnet, A. Vidal, Adv. Polym. Sci. 1986, 76, 103.
52. D. C. Edwards, J. Mater. Sci. 1990, 25, 4175.
53. V. M. Litvinov, presented at Symposium Measuring Techniques in Rubber Research, Twente, The Netherlands, 1992, p. 12.
54. V. M. Litvinov, A. F. Bulkin, V. S. Papkov, to be published.
55. M. G. Gerspacher, C. P. O'Farrell, Kautschuk, Gummi, Kunststoffe 1992, 45, 97
56. M. G. Gerspacher, C. P. O'Farrell, H. H. Yang, Kautschuk, Gummi, Kunststoffe 1994, 47, 349.
57. The experiments were performed at the MPI für Polymerforschung, Maim, Germany.
58. 29Si NMR spectrum. The NMR line for the filled sample is broadened and has a low field shoulder. The shift of the resonance to the lower field can be caused by an increase in trans-trans conformations [32,33], and/or by an increase in the mean Si-O-Si angle due to flattening of adsorbed chain fragments [34].
59. 2 relaxation. On the other hand, the dielectric relaxation is caused by the reorientations of the Si-O dipoles of the main chain. A few adjacent adsorbed units might be involved in the relaxation caused by adsorption-desorption.
60. The experiments were performed at the Institute für Makromolekulare Chemie, Universität Freiburg, Germany.
61. -1) (Ah460). The weight ratio filler/elastomer is 30: 100.