Enhancing ethanol oxidation rate at PtRu electro-catalysts using metal-oxide additives

Electrochimica Acta

Volumn 191, Issue , 2016, Pages 183-191

  Zignani, S C ^a   Baglio, V ^a   Sebastian D ^a   Siracusano, S ^a   Arico A S ^a  

^a CNR ITAE   (Italy)

Author keywords

Direct ethanol fuel cells; ethanol electro oxidation; metal oxide promoters; PtRu C catalyst

Indexed keywords

ADDITIVES; CATALYSTS; CATALYTIC OXIDATION; DIRECT ETHANOL FUEL CELLS (DEFC); ELECTRODES; ELECTROOXIDATION; ETHANOL; ETHANOL FUELS; FUEL CELLS; METALLIC COMPOUNDS; METALS; OXIDATION; PLATINUM ALLOYS; TITANIUM DIOXIDE;

CATALYTIC INK PREPARATION; ELECTROACTIVE SURFACE AREAS; ELECTROCATALYTIC ACTIVITY; ETHANOL ELECTRO-OXIDATION; ETHANOL OXIDATION REACTION; METAL OXIDES; PRACTICAL OPERATING CONDITIONS; PTRU/C CATALYSTS;

CATALYST ACTIVITY;

EID: 84955485540     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2016.01.085     Document Type: Article

References (48)

1. M.Z.F. Kamarudin, S.K. Kamarudin, M.S. Masdar, and W.R.W. Daud Review: Direct ethanol fuel cells Int. J. Hydrogen Energy 38 2013 9438 9453
2. E. Antolini Catalysts for direct ethanol fuel cells Journal of Power Sources 170 2007 1 12
3. S.Q. Brouzgou, and P. Song Tsiakaras Low and non-platinum electrocatalysts for PEMFCs: Current status, challenges and prospects Appl. Catal. B: Environ. 127 2012 371 388
4. R.F.B. De Souza, J.C.M. Silva, M.H.M.T. Assumção, A.O. Neto, and M.C. Santos Ethanol Oxidation Reaction Using PtSn/C plus Ce/C Electrocatalysts: Aspects of Ceria Contribution Electrochim. Acta 117 2014 292 298
5. A. Brouzgou, A. Podias, and P. Tsiakaras PEMFCs and AEMFCs directly fed with ethanol: a current status comparative review J. Appl. Electrochem. 43 2013 119 136
6. F. Vigier, S. Rousseau, C. Coutanceau, J.-M. Leger, and C. Lamy Electrocatalysis for the direct alcohol fuel cell Topics in Catalysis 40 2006 111 121
7. S. Song, and P. Tsiakaras Recent progress in direct ethanol proton exchange membrane fuel cells (DE-PEMFCs) Appl. Catal. B: Environ. 63 2006 187 193
8. xSn/C electro-catalysts for ethanol oxidation prepared by reduction with different formic acid concentrations Electrochim. Acta 70 2012 255 265
9. G.A. Camara, R.B. de Lima, and T. Iwasita Catalysis of ethanol electrooxidation by PtRu: the influence of catalyst composition Electrochem. Commun. 6 2004 812 815
10. A. Velázquez-Palenzuela, E. Brillas, C. Arias, F. Centellas, J.A. Garrido, R.M. Rodríguez, and P.-L. Cabot Carbon monoxide: methanol and ethanol electro-oxidation on Ru-decorated carbon-supported Pt nanoparticles prepared by spontaneous deposition J. Power Sources 225 2013 163 171
11. D. Sebastián, I. Suelves, E. Pastor, R. Moliner, and M.J. Lázaro The effect of carbon nanofiber properties as support for PtRu nanoparticles on the electrooxidation of alcohols Appl. Catal. B: Environ. 132 2013 13 21
12. W.J. Zhou, S.Q. Song, W.Z. Li, Z.H. Zhou, G.Q. Sun, Q. Xin, S. Douvartzides, and P. Tsiakaras Direct ethanol fuel cells based on PtSn anodes: the effect of Sn content on the fuel cell performance J. Power Sources 140 2005 50 58
13. S.C. Zignani, V. Baglio, E.R. Gonzalez, and A.S. Aricò Durability of a PtSn Ethanol Oxidation Electrocatalyst ChemElectroChem 1 2014 1403 1406
14. A.S. Aricò, P. Creti, P.L. Antonucci, and V. Antonucci Comparison of Ethanol and Methanol Oxidation in a LiquidòFeed Solid Polymer Electrolyte Fuel Cell at High Temperature Electrochem. Solid-State Lett. 1 1998 66 68
15. F. Vigier, C. Coutanceau, A. Perrard, E.M. Belgsir, and C. Lamy Development of anode catalysts for a direct ethanol fuel cell J. Appl. Electrochem. 34 2004 439 446
16. C. Alegre, D. Sebastián, M.E. Gálvez, R. Moliner, A. Stassi, A.S. Aricò, M.J. Lázaro, and V. Baglio PtRu Nanoparticles Deposited by the Sulfite Complex Method on Highly Porous Carbon Xerogels: Effect of the Thermal Treatment Catalysts 3 2013 744 756
17. 3Sn, Electrochim. Acta 48 2003 3731 3742
18. C. Lamy, S. Rousseau, E.M. Belgsir, C. Coutanceau, and J.-M. Leger Recent progress in the direct ethanol fuel cell: development of new platinum-tin electrocatalysts Electrochim. Acta 49 2004 3901 3908
19. S. Beyhan, C. Coutanceau, J.-M. Leger, T.W. Napporn, and F. Kadirgan Promising anode candidates for direct ethanol fuel cell: Carbon supported PtSn-based trimetallic catalysts prepared by Bonnemann method Int. J. Hydrogen Energy 38 2013 6830 6841
20. F. Colmati, E. Antolini, and E.R. Gonzalez Preparation: structural characterization and activity for ethanol oxidation of carbon supported ternary Pt-Sn-Rh catalysts J. Alloy Compd 456 2008 264 270
21. 2 Nat. Mater. 8 2009 325 330
22. A. Bonesi, G. Garaventa, W.E. Triaca, and A.M. Castro Luna Synthesis and characterization of new electrocatalysts for ethanol oxidation Int. J. Hydrogen Energy 33 2008 3499 3501
23. E.V. Spinace, M. Linardi, and A.O. Neto Preparation of PtSn/C and PtSnNi/C electrocatalysts using the alcohol-reduction process Mater. Lett. 62 2008 2099 2102
24. T.S. Almeida, K.B. Kokoh, and A.R. de Andrade Effect of Ni on Pt/C and PtSn/C prepared by the Pechini method Int. J. Hydrogen Energy 36 2011 3803 3810
25. S. Beyhan, J.-M. Leger, and F. Kadirgan Pronounced synergetic effect of the nano-sized PtSnNi/C catalyst for ethanol oxidation in direct ethanol fuel cell Appl. Catal. B Environ. 130 2013 305 313
26. J. Ribeiro, D.M. dos Anjos, J.-M. Leger, F. Hahn, P. Olivi, A.R. de Andrade, and et al. Effect of W on PtSn/C catalysts for ethanol electrooxidation J. Appl. Electrochem. 38 2008 653 662
27. E. Lee, A. Murthy, and A. Manthiram Effect of Mo addition on the electrocatalytic activity of Pt-Sn-Mo/C for direct ethanol fuel cells Electrochim. Acta 56 2011 1611 1618
28. G. García, N. Tsiouvaras, E. Pastor, M.A. Peña, J.L.G. Fierro, and M.V. Martínez-Huerta Ethanol oxidation on PtRuMo/C catalysts: In situ FTIR spectroscopy and DEMS studies Int. J. Hydrogen Energy 37 2012 7131 7140
29. R.F.B. de Souza, L.S. Parreira, J.C.M. Silva, F.C. Simoes, M.L. Calegaro, M.J. Giz, and et al. PtSnCe/C electrocatalysts for ethanol oxidation: DEFC and FTIR in-situ studies Int. J. Hydrogen Energy 36 2011 11519 11527
30. J. Tayal, B. Rawat, and S. Basu Effect of addition of rhenium to Pt-based anode catalysts in electro-oxidation of ethanol in direct ethanol PEM fuel cell Int. J. Hydrogen Energy 37 2012 4597 4605
31. J.M. Jacob, P.G. Corradini, E. Antolini, N.A. Santos, and J. Perez Electro-oxidation of ethanol on ternary Pt-Sn-Ce/C catalysts Appl. Catal. B: Environ. 165 2015 176 184
32. S. Tanaka, M. Umeda, H. Ojima, Y. Usui, O. Kimura, and I. Uchida Preparation and evaluation of a multi-component catalyst by using a co-sputtering system for anodic oxidation of ethanol J. Power Sources 152 2005 34 39
33. V. Baglio, S.C. Zignani, S. Siracusano, A. Stassi, C. D'Urso, and A.S. Aricò Composite Anode Electrocatalyst for Direct Methanol Fuel Cells Electrocatal. 4 2013 235 240
34. V. Baglio, D. Sebastián, C. D'Urso, A. Stassi, R.S. Amin, K.M. El-Khatib, and A.S. Aricò Composite anode electrode based on iridium oxide promoter for direct methanol fuel cells Electrochim. Acta 128 2014 304 310
35. A. Bonesi, M.S. Moreno, W.E. Triaca, and A.M. Castro Luna Modified catalytic materials for ethanol oxidation Int. J. Hydrogen Energy 35 2010 5999 6004
36. 3Sn/C as catalysts J. Appl. Electrochem. 43 2013 147 158
37. J.P. Pereira, D.S. Falcão, V.B. Oliveira, and A.M.F.R. Pinto Performance of a passive direct ethanol fuel cell J. Power Sources 256 2014 14 19
38. A.S. Aricò, V. Baglio, A. Di Blasi, E. Modica, P.L. Antonucci, and V. Antonucci Analysis of the high-temperature methanol oxidation behaviour at carbon-supported Pt-Ru catalysts J. Electroanal. Chem. 557 2003 167 176
39. G. García, V. Baglio, A. Stassi, E. Pastor, V. Antonucci, and A.S. Aricò Investigation of Pt-Ru nanoparticle catalysts for low temperature methanol electro-oxidation J.Solid State Electrochem. 11 2007 1229 1238
40. W. Qian, D.P. Wilkinson, J. Shen, H. Wang, and J. Zhang Architecture for portable direct liquid fuel cells J. Power Sources 154 2006 202 213
41. 40) electrolyte J. Appl. Electrochem. 28 1998 881 887
42. 2/C catalyst Electrochem. Commun. 7 2005 1087 1090
43. M.M. Ottakam Thotiyl, and S. Sampath Electrochemical oxidation of ethanol in acid media on titanium nitride supported fuel cell catalysts Electrochim. Acta 56 2011 3549 3554
44. 2/C composite prepared by the sol-gel technique and supported on boron-doped diamond J. Power Sources 158 2006 124 128
45. S. Song, W. Zhou, Z. Liang, R. Cai, G. Sun, Q. Xin, V. Stergiopoulos, and P. Tsiakaras The effect of methanol and ethanol cross-over on the performance of PtRu/C-based anode DAFCs Appl. Catal. B: Environ. 55 2005 65 72
46. W. Zhou, Z. Zhou, S. Song, W. Li, G. Sun, P. Tsiakaras, and Q. Xin Pt based anode catalysts for direct ethanol fuel cells Appl. Catal. B: Environ. 46 2003 273 285
47. L. Yu, and J. Xi TiO2 nanoparticles promoted Pt/C catalyst for ethanol electro-oxidation Electrochim. Acta 67 2012 166 171
48. S. García-Rodríguez, T. Herranz, and S. Rojas Electrocatalysts for the Electrooxidation of Ethanol S.L. Suib, New and Future Developments in Catalysis: Batteries, Hydrogen Storage and Fuel Cells 2013 Elsevier 33 67 Ch. 3