Speciation of Trace Metals in Sediments

Chemical Speciation in the Environment: Second Edition

Volumn , Issue , 2007, Pages 301-321

  Kersten, M ^a  

^a JOHANNES GUTENBERG UNIVERSITY   (Germany)

Author keywords

Chemical speciation; Sediments; Sequential extractions; Suspended particulate matter; Trace metals

Indexed keywords

CHEMICAL SPECIATION; SEDIMENTS; SUSPENDED SEDIMENTS;

SEQUENTIAL EXTRACTION; SUSPENDED PARTICULATE MATTERS; TRACE METAL;

TRACE ELEMENTS;

EID: 84954311345     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9780470988312.ch11     Document Type: Chapter

References (85)

1. Accomasso, G.M., Zelano, V, Daniele, P.G., Gastaldi, D., Ginepro, M. and Ostacoli, G. (1993) A study on the reproducibility of Tessier's extractions in a fluvial sediment and a comparison between different dissolution procedures in a reference material. Spectrochim. Acta, 49, 1205.
2. Bartlett, R. and James, B. (1980) Studying dried, stored soil samples - some pitfalls. Soil Sci. Soc. Am. J., 85, 721.
3. Belzile, N., Lecompte, P and Tessier, A. (1989) Testing readsorption of trace elements during partial chemical extractions of bottom sediments. Environ. Sci. Technol., 23, 1015.
4. Bernhard, M., Brinckman, F.E. and Irgolic, K.J. (1986a) Why speciation? In The Importance of Chemical Speciation in Environmental Processes (eds Bernhard, M., Brinckman, F.E. and Sadler, PJ.). Springer-Verlag, Berlin, p. 7
5. Bernhard, PC., Van Grieken, R.E. and Eisma, D. (1986b) Classification of estuarine particles using automated electron beam microprobe. J. Environ. Qual., 13, 337.
6. Bordas, F. and Bourg, A.C.M. (1998) A critical evaluation of sample pretreatment for storage of contaminated sediments to be investigated for the potential mobility of their heavy metal load. Water Air Soil Pollut., 103, 137.
7. Campbell, RG.C., Lewis, A.G., Chapman, A.A., Crowde, A.A., Fletcher, W.K., Imber, B., Luoma, S.N., Stokes, R.M. and Winfrey, M. (1988) Biologically Available Metals in Sediments. NRCC Report No. 27694, Ottawa, Canada, 305 pp.
8. Casas, A.M. and Crecelius, E.A. (1994) Relationship between acid volatile sulfide and the toxicity of lead, zinc, and copper in marine sediments. Environ. Toxicol. Chem., 13, 529.
9. Chester, R., Kudoja, W.M., Thomas, A. and Towner, J. (1985) Pollution reconnaissance in stream sediments using non-residual trace metals. Environ. Pollut. B, 10, 213.
10. Cooper, D.C. and Morse, J.W. (1998) Extractability of metal sulfide minerals in acidic solutions: application to environmental studies of trace metal contamination within anoxic sediments. Environ. Sci. Technol, 32, 1076.
11. Davison, W., Grime, G.W. and Woof, C. (1992) Characterization of lacustrine iron sulfate particles with proton-induced, X-ray emission. Limnol. Oceanogr, 37, 1770-1777.
12. Delaney, J.S., Bajt, S., Sutton, S.R. and Dyar, M.D. (1996) In situ microanalysis of Fe3+/XFe in amphibole by X-ray absorption near edge structure (XANES) spectroscopy. In Mineral Spectroscopy: A Tribute to Roger G. Burns (eds Dyar, M.D., McCammon, C. and Schaefer, M.W.). The Geochemical Society Special Publication No. 5, 165 pp.
13. Dyrssen, D. and Kremling, K. (1990) Increasing hydrogen sulfide concentration and trace metal behavior in the anoxic Baltic waters. Mar. Chem., 30, 193.
14. Engler, R.M., Brannon, J.M. and Rose, J. (1977) A practical selective extraction procedure for sediment characterization. In Chemistry of Marine Sediments (ed. Yen, T.F.). Ann Arbor Science Publishers, Ann Arbor, MI, p. 163.
15. Fiedler, H.D., Lopez-Sanchez, J.F., Rubio, R., Rauret, G., Quevauviller, Ph., Ure, A.M. and Muntau, H. (1994) Study on the stability of extractable trace metal contents in a river sediment using sequential extraction. Analyst, 119, 1109.
16. Flyhammer, P (1997) Estimation of heavy metal transformations in municipal solid waste. Sci. Total Environ., 198, 123.
17. Ginepro, M., Gulmini, M., Ostacoli, G. and Zelano, V (1996) Microwave desorption treatment after the oxidation step in Tessier's sequential extraction scheme. Int. J. Anal. Chem., 63, 147.
18. Grime, G.W. (1998) Analysis of individual environmental particles using microPIXE and nuclear microscopy. X-Ray Spectr., 27, 221.
19. Haese, R.R., Wallmann, K., Dahmke, A., Kretzmann, U., Müller, PJ. and Schulz, H.D. (1997) Iron species determination to investigate early diagenetic reactivity in marine sediments. Geochim. Cosmochim. Acta, 61, 63.
20. Hall, G.E.M., Vaive, J.E., Beer, R. and Hoashi, M. (1996) Selective leaches revisited, with emphasis on the amorphous Fe oxyhydroxide phase extraction. J. Geochem. Explor., 56, 59.
21. Helz, G.R., Miller, C.V, Charnock, J.M., Mosselmans, J.F.W., Pattrick, R.A.D., Garner, C.D. and Vaughan, D.J. (1996) Mechanism of molybdenum removal from the sea and its concentration in black shales: EXAFS evidence. Geochim. Cosmochim. Acta, 60, 3631.
22. Höfer, H.E., Brey, G.P, Schulz-Dobrick, B. and Oberhänsli, R. (1994) The determination of the oxidation state of iron by the electron microprobe. Eur. J. Miner, 6, 407.
23. Horowitz, A.J. (1991) A Primer on Trace Metal-Sediment Chemistry. Lewis, Chelsea, 136 pp.
24. Horowitz, A.J. and Eldrick, K.A. (1987) Surface area and its interrelation with grain size, geochemical phase and sediment-trace element chemistry. Appl. Geochem., 2, 437.
25. Howard, J.L. and Shu, J. (1996) Sequential extraction analysis of heavy metals using a chelating agent (NTA) to counteract resorption. Environ. Pollut., 91, 89.
26. Huerta-Diaz, M.A. and Morse, J.W. (1992) Pyritization of trace metals in anoxic marine sediments. Geochim. Cosmochim. Acta, 56, 2681.
27. Hug, S.J., Buerge, I.J. and Weidler, RG. (1997) Transformations of chromium in the environment. Analysis Mag., 25, 12.
28. Kersten, M. and Förstner, U. (1986) Chemical fractionation of heavy metals in anoxic estuarine and coastal sediments. Water Sci. Tech, 18, 121.
29. Kersten, M. and Förstner, U. (1987) Effect of sample pretreatment on the reliability of solid speciation data of heavy metals - implications for the study of early diagenetic processes. Mar. Chem., 22, 299.
30. Kersten, M. and Förstner, U. (1989) Speciation of trace elements in sediments. In Trace Elements Speciation: Analytical Methods and Problems (ed. Batley, G.). CRC Press, Boca Raton, FL, pp. 245-317.
31. Kersten, M. and Förstner, U. (1991) Geochemical characterization of pollutant mobility in cohesive sediments. Geomar. Letts, 11, 184-187.
32. Kersten, M. and Förstner, U. (1995) Speciation of trace metals in sediments and combustion wastes. In Chemical Speciation in the Environment, 1st edn (eds Ure, A.M. and Davidson, C.M.). Blackie, Glasgow, pp. 234-275.
33. Kersten, M., Irion, G. and Förstner, U. (1991) Particulate trace metals in surface waters of the North Sea. In Heavy Metals in the Environment (ed. Vernet, J.-R). Elsevier, Amsterdam, pp.137-160.
34. Kersten, M., Garbe-Schönberg, C.-D., Thomsen, S., Anagnostou, Ch. and Sioulas, A. (1997) Source apportionment of Pb pollution in the coastal waters of Elefsis Bay, Greece. Environ. Sci. Technol., 31, 1295.
35. Kheboian, C. and Bauer, Ch.F. (1987) Accuracy of selective extraction procedures for metal speciation in model aquatic sediments. Anal. Chem., 59, 1417.
36. Kim, N.D. and Fergusson, J.E. (1991) Effectiveness of a commonly used sequential extraction technique in determining the speciation of cadmium in soils. Sci. Total Environ., 105, 191.
37. Kiratli, N. and Ergin, M. (1996) Partitioning of heavy metals in surface Black Sea sediments. Appl. Geochem., 11.
38. König, I. and Hollatz, R. (1990) A fingerprint technique using Mössbauer spectroscopy for the determination of individual chemical iron species in young sediments. Hypefine Interact., 57, 2245.
39. Lead, J.R., Davison, W., Hamilton-Taylor, J. and Buffle, J. (1997) Characterizing colloidal material in natural waters. Aquat. Geochem., 3, 213.
40. Lead, J.R., Hamilton-Taylor, J. and Davison, W. (1998) The effect of sequential extractions of suspended particulate matter on trace metal sorption and microbial cell stability. Sci. Total Environ., 209, 193.
41. Lee, F.Y. and Kittrick, J.A. (1984) Elements associated with the cadmium phase in a harbor sediment as determined with the electron beam microprobe. J. Environ. Qual., 13, 337.
42. Li, X., Coles, B., Ramsey, M.H. and Thornton, I. (1995) Sequential extraction of soils for multielement analysis by ICP-AES. Chem. Geol., 124, 109.
43. Lion, L.W., Altmann, R.S. and Leckie, J.O. (1982) Trace-metal adsorption characteristics of estuarine particulate matter: evaluation of contributions of Fe/Mn oxide and organic surface coatings. Environ. Sci. Technol, 16, 660.
44. Lovely, D.E. and Phillips, E.J.P (1986) Organic matter mineralization with reduction of ferric iron in anaerobic sediments. Appl. Environ. Microbiol., 51, 683.
45. Maiz, I., Esnaola, M.V and Millan, E. (1997) Evaluation of heavy metal availability in contaminated soils by a short sequential extraction procedure. Sci. Total Environ, 206, 107.
46. Manceau, A., Charlet, L., Boisset, M.-C., Didier, B. and Spadini, L. (1992) Sorption and speciation of heavy metals on hydrous Fe and Mn oxides: from microscopic to macroscopic. Appl. Clay Sci., 7, 201.
47. Manceau, A., Boisset, M.-C., Sarret, G., Hazemann, J.-L., Mench, M., Cambier, Ph. and Prost, R. (1996) Direct determination of lead speciation in contaminated soils by EXAFS spectroscopy. Environ. Sci. Technol, 30, 1540.
48. Martens, D.A. and Suarez, D.L. (1997) Selenium speciation of soil/sediment determined with sequential extractions and hydride generation atomic absorption spectrometry. Environ. Sci. Technol., 31, 133.
49. Martin, J.M., Nirel, P and Thomas, AJ. (1987) Sequential extraction techniques: promises and problems. Mar. Chem, 22, 313.
50. Mattigot, S.V and Ervin, J. (1983) Scheme for density separation and identification of compound forms in size fractionated fly ash. Fuel, 62, 927.
51. Mattigot, S.V, Page, A.L. and Thornton, I. (1986) Identification of some trace metal minerals in a mine-waste contaminated soil. Soil Sci. Soc. Am. J., 50, 254.
52. McCarty, D.K., Moore, J.N. and Marcus, W.A. (1998) Mineralogy and trace element association in an acid mine drainage iron oxide precipitate; comparison of selective extractions. Appl. Geochem., 13, 165.
53. Morel, F.M.M. and Hering, J.G. (1993) Principles and Applications of Aquatic Chemistry. Wiley Interscience, New York, 374 pp.
54. Müller, B. (1993) MacjiQL - A program to calculate chemical speciation and adsorption. Manual, EAWAG Limnological Research Center, Kastanienbaum, Switzerland, 15 pp.
55. Norrish, K., Rosser, H. and Warren, LJ. (1986) A geochemical study of the forms of metals present in sediments from Spencer Gulf, South Australia. Appl. Geochem., 1, 117.
56. Pai, S., Lin, F., Tseng, C. and Sheu, D. (1993) Optimization of heating programs of GFAAS for the determination of Cd, Cu, Ni and Pb in sediments using sequential extraction technique. Int. J. Environ. Anal. Chem, 50, 193.
57. Perret, D., Leppard, G.G., Müller, M., Belzile, N., De Vitre, R. and Buffle, J. (1991) Electron microscopy of aquatic colloids: non-perturbing preparation of specimens in the field. Wat. Res, 25, 1333.
58. Peterson, M.L., Brown, G.E., Jr, Parks, G.A. and Stein, C.L. (1997) Differential redox and sorption of Cr(III/VI) on natural silicate and oxide minerals: EXAFS and XANES results. Geochim. Cosmochim. Acta, 61, 3399.
59. Pham, M.K. and Garnier, J.-M. (1998) Distribution of trace elements associated with dissolved compounds (0.45p,m-1 nm) in freshwater using coupled (frontal cascade) ultrafiltration and chromatographic separations. Environ. Sci. Tehnol., 32, 440.
60. Pickering, W.F. (1986) Metal ion speciation - soils and sediments. Ore Geol. Rev., 1, 83.
61. Quevauviller, P., Rauret, G., Lopez-Sanchez, J.F., Rubio, R., Ure, A.M. and Muntau, H. (1997) Certification of trace metal extractable contents in a sediment reference material (CRM 601) following a three-step sequential extraction procedure. Sci. Total Environ., 205, 223.
62. Rapin, F., Tessier, A., Campbell, PG.C. and Carignan, R. (1986) Potential artifacts in the determination of metal partitioning in sediments by a sequential extraction procedure. Environ. Sci. Technol., 20, 836.
63. Rauret, G., Rubio, R., Pineda, L., Lopez-Sanchez, J.F. and Beltran, J.L. (1991) Different strategies to assess Cu and Pb mobilization in polluted river sediments. Fresenius'J. Anal. Chem, 341, 631.
64. Real, C., Barreiro, R. and Carballeira, A. (1994) The application of microwave heating in sequential extractions of heavy metals in estuarine sediments. Sci. Total Environ, 152, 135.
65. Reardon, E.J., Czank, C.A., Warren, C.J., Dayal, R. and Johnston, H.M. (1995) Determining controls on element concentrations in fly ash leachate. Waste Manage. Res., 13, 435.
66. Rule, J.H. and Alden, R.W. (1992) Partitioning of Cd in geochemical fractions of anaerobic estuarine sediments. Estuar. Coastal Shelf Sci., 34, 487.
67. Scheidegger, A.M. and Sparks, D.L. (1996) A critical assessment of sorption-desorption mechanisms at the soil mineral/water interface. Soil Sci., 161, 813.
68. Shannon, R.D. and White, J.R. (1991) The selectivity of a sequential extraction procedure for the determination of iron oxyhydroxides and iron sulfides in lake sediments. Biogeochemistry, 14, 193.
69. Simpson, S.L., Apte, S.C. and Batley, G.E. (1998) Effect of short-term resuspension events on trace metal speciation in polluted anoxic sediments. Environ. Sci. Technol, 32, 620.
70. Smith, R.M. and Martell, A.E. (1987) Critical stability constants, enthalpies and entropies for the formation of metal complexes of aminopolycarboxylic acids and carboxylic acids. Sci. Total Environ., 64, 125.
71. Szulczewski, M.D., Helmke, Ph.A. and Bleam, W.F. (1997) Comparison of XANES analyses and extractions to determine chromium speciation in contaminated soils. Environ. Sci. Technol., 31, 2954.
72. Tack, F.M.G., Vossius, H.A.H. and Verloo, M.G. (1996) A comparison between sediment metal fractions, obtained from sequential extraction and estimated from single extractions. Int. J. Environ. Anal. Chem., 63, 61.
73. Tessier, A., Campbell, P.G.C. and Bisson, M. (1979) Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem, 51, 844.
74. Thomson, E.A., Luoma, S.N., Cain, D.J. and Johansson, C. (1980) The effect of sample storage on the extraction of Cu, Zn, Fe, Mn and organic materials from oxidized estu- arine sediments. Water Air Soil Pollut., 14, 215.
75. Tillekeratne, S., Hiraide, M. and Mizuike, A. (1984) Selective leaching of trace heavy metals associated with suspended matter in fresh waters. Microchim. Acta, 1984 III, 69.
76. Tipping, E., Hetherington, N.B., Hilton, J., Thompson, D.W., Bowles, E. and HamiltonTaylor, J. (1985) Artifacts in the use of selective chemical extraction to determine distributions of metals between oxides of maganese and iron. Anal. Chem., 57, 1944-1946.
77. Tokunaga, T.K., Sutton, S.R., Bajt, S., Nuessle, P and Shea-McCarthy, G. (1998) Selenium diffusion and reduction at the water-sediment boundary: micro-XANES spectroscopy of reactive transport. Environ. Sci. Technol., 32, 1092.
78. Ure, A.M. (1990) Methods of analysis for heavy metals in soils. In Heavy Metals in Soils (ed. Alloway, B.J.). Blackie, Glasgow, pp. 40-80.
79. Van Aken, PA., Liebscher, B. and Styrsa, VJ. (1998) Quantitative determination of iron oxidation states in minerals using Fe L23-edge electron energy-loss near-edge structure spectroscopy. Phys. Chem. Miner., 25, 323.
80. Van der Sloot, H.A., Heasman, L. and Quevauviller, Ph. (1997) Harmonization of Leaching/ Extraction Tests. Elsevier Studies in Environmental Science 70, Amsterdam, 281 pp.
81. Van Valin, R. and Morse, J.W. (1982) An investigation of methods commonly used for the selective removal and characterization of trace metals in sediments. Mar. Chem., 11, 535.
82. Wallmann, W., Kersten, M., Gruber, J. and Förstner, U. (1993a) Artifacts in the determination of trace metal binding forms in anoxic sediments by sequential extractions. Int. J. Environ. Anal. Chem., 51, 187.
83. Wallmann, K., Hennies, K., König, I., Petersen, W. and Knauth, H.-D. (1993b) A new procedure for determining reactive Fe111 and Fe11 minerals in sediments. Limnol. Oceanogr., 38, 1803.
84. Zaggia, L. and Zonta, R. (1997) Metal-sulfide formation in the contaminated anoxic sludge of the Venice canals. Appl. Geochem., 12, 527.
85. Zhang, H., Davison, W., Miller, S. and Tych, W. (1995) In situ high resolution measurements of fluxes of Ni, Cu, Fe, and Mn and concentration of Zn and Cd in porewaters by DGT. Geochim. Cosmochim. Acta, 59, 4181.