Reliable dn/dc Values of Cellulose, Chitin, and Cellulose Triacetate Dissolved in LiCl/N,N-Dimethylacetamide for Molecular Mass Analysis

Biomacromolecules

Volumn 17, Issue 1, 2016, Pages 192-199

  Ono, Yuko ^a   Ishida, Takashi ^a   Soeta, Hiroto ^a   Saito, Tsuguyuki ^a   Isogai, Akira ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHITIN; LIGHT SCATTERING; MOLECULAR MASS; REFRACTIVE INDEX; SIZE EXCLUSION CHROMATOGRAPHY; STYRENE;

CELLULOSE TRIACETATE; DETERMINATION METHODS; DIMETHYLACETAMIDE; HYDROXYL GROUPS; LITHIUM CHLORIDE/N ,N-DIMETHYLACETAMIDE; MICROFIBRILLATED CELLULOSE (MFC); MULTIANGLE LASER LIGHT SCATTERING; REFRACTIVE INDEX INCREMENT;

CELLULOSE;

CELLOBIOSE; CELLULOSE DERIVATIVE; CELLULOSE TRIACETATE; CHITIN; HYDROXYL GROUP; LITHIUM CHLORIDE; N,N DIMETHYLACETAMIDE; POLYSTYRENE; ACETAMIDE DERIVATIVE; CELLULOSE; POLYSTYRENE DERIVATIVE; SOLVENT;

ARTICLE; CHEMICAL STRUCTURE; CONCENTRATION (PARAMETERS); CONFORMATION; CONTROLLED STUDY; COVALENT BOND; DEPOLYMERIZATION; DISSOLUTION; ELUTION; HEATING; MOLECULAR INTERACTION; MOLECULAR WEIGHT; PRIORITY JOURNAL; REFRACTION INDEX; ROOM TEMPERATURE; SIZE EXCLUSION CHROMATOGRAPHY; SOLUBILITY; VISCOSITY; ANALOGS AND DERIVATIVES; CHEMISTRY; PROCEDURES; REFRACTOMETRY;

CELLULOSE; CELLULOSE TRIACETATE; CHITIN;

ACETAMIDES; CELLOBIOSE; CELLULOSE; CHITIN; CHROMATOGRAPHY, GEL; LITHIUM CHLORIDE; MOLECULAR WEIGHT; POLYSTYRENES; REFRACTOMETRY; SOLUBILITY; SOLVENTS;

EID: 84954103777     PISSN: 15257797     EISSN: 15264602     Source Type: Journal    
DOI: 10.1021/acs.biomac.5b01302     Document Type: Article

References (27)

1. Wyatt, P. J. Light scattering and the absolute characterization of macromolecules Anal. Chim. Acta 1993, 272, 1-40 10.1016/0003-2670(93)80373-S
2. Dupont, A.-L.; Harrison, G. Conformation and dn/dc determination of cellulose in N,N-dimethylacetamide containing lithium chloride Carbohydr. Polym. 2004, 58, 233-243 10.1016/j.carbpol.2004.07.016
3. Yanagisawa, M.; Isogai, A. SEC-MALS-QELS Study on the Molecular Conformation of Cellulose in LiCl/Amide Solutions Biomacromolecules 2005, 6, 1258-1265 10.1021/bm049386m
4. Potthast, A.; Radosta, S.; Saake, B.; Lebioda, S.; Heinze, T.; Henniges, U.; Isogai, A.; Koschella, A.; Kosma, P.; Rosenau, T.; Schiehser, S.; Sixta, H.; Strlić, M.; Strobin, G.; Vorwerg, W.; Wetzel, H. Comparison testing of methods for gel permeation chromatography of cellulose: coming closer to a standard protocol Cellulose 2015, 22, 1591-1613 10.1007/s10570-015-0586-2
5. Berggren, R.; Berthold, F.; Sjöholm, E.; Lindström, M. Improved methods for evaluating the molar mass distributions of cellulose in kraft pulp J. Appl. Polym. Sci. 2003, 88, 1170-1179 10.1002/app.11767
6. McCormick, C. L.; Callais, P. A.; Hutchinson, B. H. R. Solution studies of cellulose in lithium chloride and N,N-dimethylacetamide Macromolecules 1985, 18, 2394-2401 10.1021/ma00154a010
7. Terbojevich, M.; Cosani, A.; Conio, G.; Ciferri, A.; Bianchi, E. Mesophase formation and chain rigidity in cellulose and derivatives. 3. Aggregation of cellulose in N,N-dimethylacetamide-lithium chloride Macromolecules 1985, 18, 640-646 10.1021/ma00146a011
8. Sjöholm, E.; Gustafsson, K.; Eriksson, B.; Brown, W.; Colmsjö, A. Aggregation of cellulose in lithium chloride/N,N-dimethylacetamide Carbohydr. Polym. 2000, 41, 153-161 10.1016/S0144-8617(99)00080-6
9. Schult, T.; Hjerde, T.; Optun, O. I.; Kleppe, P. J.; Moe, S. Characterization of cellulose by SEC-MALLS Cellulose 2002, 9, 149-158 10.1023/A:1020139409903
10. Röhrling, J.; Potthast, A.; Rosenau, T.; Lange, T.; Ebner, G.; Sixta, H.; Kosma, P. A novel method for the determination of carbonyl groups in cellulosics by fluorescence labeling. 1. Method development Biomacromolecules 2002, 3, 959-968 10.1021/bm020029q
11. Siller, M.; Ahn, K.; Pircher, N.; Rosenau, T.; Potthast, A. Dissolution of rayon fibers for size exclusion chromatography: a challenge Cellulose 2014, 21, 3291-3301 10.1007/s10570-014-0356-6
12. Ishii, D.; Isogai, A. The residual amide content of cellulose sequentially solvent-exchanged and then vacuum-dried Cellulose 2008, 15, 547-553 10.1007/s10570-008-9211-y
13. Kuramae, R.; Saito, T.; Isogai, A. TEMPO-oxidized cellulose nanofibrils prepared from various plant holocelluloses React. Funct. Polym. 2014, 85, 126-133 10.1016/j.reactfunctpolym.2014.06.011
14. Shi, Z.; Yang, Q.; Ono, Y.; Funahashi, R.; Saito, T.; Isogai, A. Creation of a new material stream from Japanese cedar resources to cellulose nanofibrils React. Funct. Polym. 2015, 95, 19-24 10.1016/j.reactfunctpolym.2015.08.005
15. Yanagisawa, M.; Shibata, I.; Isogai, A. SEC-MALLS analysis of cellulose using LiCl/1,3-dimethyl-2-imidazolidinone as an eluent Cellulose 2004, 11, 169-176 10.1023/B:CELL.0000025388.92043.ec
16. Matsumoto, T.; Tatsumi, D.; Tamai, N.; Takaki, T. Solution properties of celluloses from different biological origins in LiCl DMAc Cellulose 2001, 8, 275-282 10.1023/A:1015162027350
17. Yanagisawa, M.; Shibata, I.; Isogai, A. SEC-MALLS analysis of softwood kraft pulp using LiCl/1,3-dimethyl-2-imidazolidinone as an eluent Cellulose 2005, 12, 151-158 10.1007/s10570-004-0866-8
18. Ishii, D.; Tatsumi, D.; Matsumoto, T. Effect of solvent exchange on the solid structure and dissolution behavior of cellulose Biomacromolecules 2003, 4, 1238-1243 10.1021/bm034065g
19. Yamamoto, M.; Kuramae, R.; Yanagisawa, M.; Ishii, D.; Isogai, A. Light-scattering analysis of native wood holocelluloses totally dissolved in LiCl-DMI solutions: high probability of branched structures in inherent cellulose Biomacromolecules 2011, 12, 3982-3988 10.1021/bm201211z
20. Ono, Y.; Hiraoki, R.; Fujisawa, S.; Saito, T.; Isogai, A. SEC-MALLS analysis of wood holocelluloses dissolved in 8% LiCl/1,3-dimethyl-2-imidazolidinone: challenges and suitable analytical conditions Cellulose 2015, 22, 3347-3357 10.1007/s10570-015-0694-z
21. Potthast, A.; Rosenau, T.; Sixta, H.; Kosma, P. Degradation of cellulosic materials by heating in DMAc/LiCl Tetrahedron Lett. 2002, 43, 7757-7759 10.1016/S0040-4039(02)01767-7
22. Potthast, A.; Rosenau, T.; Sartori, J.; Sixta, H.; Kosma, P. Hydrolytic processes and condensation reactions in the cellulose solvent system N,N-dimethylacetamide/lithium chloride. Part 2: degradation of cellulose Polymer 2003, 44, 7-17 10.1016/S0032-3861(02)00751-6
23. Isogai, T.; Yanagisawa, M.; Isogai, A. Degrees of polymerization (DP) and DP distribution of dilute acid-hydrolyzed products of alkali-treated native and regenerated celluloses Cellulose 2008, 15, 815-823 10.1007/s10570-008-9231-7
24. McCormick, C. L.; Callais, P. A.; Hutchinson, B. H., Jr. Solution studies on cellulose in lithium chloride and N,N-dimethylacetamide Macromolecules 1985, 18, 2394-2401 10.1021/ma00154a010
25. Spange, S.; Reuter, A.; Vilsmeier, E.; Heinze, T.; Keutel, D.; Linert, W. Determination of empirical polarity parameters of the cellulose solvent N,N-dimethylacetamide/LiCl by means of the solvatochromic technique J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 1945-1955 10.1002/(SICI)1099-0518(199808)36:11<1945::AID-POLA30>3.3.CO;2-V
26. Striegel, A. M. Advances in the understanding of the dissolution mechanism of cellulose in DMAc/LiCl Journal of the Chilean Chemical Society 2003, 48, 73-77 10.4067/S0717-97072003000100013
27. Yanagisawa, M.; Shibata, I.; Isogai, A. SEC-MALLS analysis of cellulose using LiCl/1,3-dimethyl-2-imidazolidinone as an eluent Cellulose 2004, 11, 169-176 10.1023/B:CELL.0000025388.92043.ec