Basic ionic liquid supported on mesoporous SBA-15 silica as an efficient heterogeneous catalyst for biodiesel production

Industrial and Engineering Chemistry Research

Volumn 54, Issue 5, 2015, Pages 1505-1512

  Xie, Wenlei ^a   Hu, Libing ^a   Yang, Xinli ^a  

^a HENAN UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BIODIESEL; CATALYSTS; GRAFTING (CHEMICAL); IONIC LIQUIDS; LIQUIDS; METHANOL; OIL SHALE; REUSABILITY; SILICA; SOYBEAN OIL; TITRATION; TRANSESTERIFICATION;

ADSORPTION DESORPTION; BASIC IONIC LIQUID; BIODIESEL PRODUCTION; CATALYST REUSABILITY; HETEROGENEOUS CATALYST; MESOPOROUS SBA-15; ORDERED MESOPOROUS STRUCTURES; TRANSESTERIFICATION REACTION;

CATALYST ACTIVITY;

EID: 84949116320     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie5045007     Document Type: Article

References (37)

1. Sharma, Y. C.; Singh, B.; Upadhyay, S. N. Advancements in Development and Characterization of Biodiesel: a Review. Fuel 2008, 87, 2355-2373.
2. Helwani, Z.; Othman, M. R.; Aziz, N.; Fernando, W. J. N.; Kim, J. Technologies for Production of Biodiesel Focusing on Green Catalytic Techniques: a Review. Fuel Process. Technol. 2009, 90, 1502-1514.
3. Xie, W.; Zhao, L. Production of Biodiesel by Transesterification of Soybean Oil Using Calcium Supported Tin Oxides as Heterogeneous Catalysts. Energy Convers. Manage. 2013, 76, 55-62.
4. Xie, W.; Wang, H.; Li, H. Silica-Supported Tin Oxides as Heterogeneous Acid Catalysts for Transesterification of Soybean Oil with Methanol. Ind. Eng. Chem. Res. 2012, 51, 225-231.
5. Yang, Z.; Xie, W. Soybean Oil Transesterification over Zinc Oxide Modified with Alkali Earth Metals. Fuel Process. Technol. 2007, 88, 631-638.
6. Mutreja, V.; Singh, S.; Ali, A. Potassium Impregnated Nanocrystalline Mixed Oxides of La and Mg as Heterogeneous Catalysts for Transesterification. Renewable Energy 2014, 62, 226-233.
7. Kumar, R.; Tiwari, P.; Garg, S. Alkali Transesterification of Linseed Oil for Biodiesel Production. Fuel 2013, 104, 553-560.
8. 3-SBA-15 Catalysts for Biodiesel Production from Soybean Oil. Energy Convers. Manage. 2014, 79, 34-42.
9. Dias, J. M.; Alvim-Ferraz, M. C. M.; Almeida, M. F.; Méndez Díaz, J. D.; Sánchez Polo, M.; Rivera Utrilla, J. Biodiesel Production Using Calcium Manganese Oxide as Catalyst and Different Raw Materials. Energy Convers. Manage. 2013, 65, 647-653.
10. Xie, W.; Yang, Z.; Chun, H. Catalytic Properties of Lithiumdoped ZnO Catalysts Used for Biodiesel Preparations. Ind. Eng. Chem. Res. 2007, 46, 7942-7949.
11. 6 Nanocomposite as Catalyst for Biodiesel Production. Bioresour. Technol. 2014, 154, 32-37.
12. 3 and KOH/NaY Catalysts for Biodiesel Production via Transesterification from Palm Oil. Renewable Energy 2009, 34, 1145-1150.
13. Granados, M. L.; Alonso, D. M.; Sadaba, I.; Mariscal, R.; Ocon, P. Leaching and Homogeneous Contribution in Liquid Phase Reaction Catalyzed by Solids: the Case of Triglycerides Methanolysis Using CaO. Appl. Catal. B: Environ. 2009, 89, 265-272.
14. Prasetyanto, E. A.; Park, S. E. Synthesis of Short-channeled Amino-functionalized SBA-15 and its Beneficial Applications in Basecatalyzed Reactions. Appl. Catal. A: Gen. 2008, 350, 244-251.
15. Olivier-Bourbigou, H.; Magna, L.; Morvan, D. Ionic Liquids and Catalysis: Recent Progress from Knowledge to Applications. Appl. Catal. A: Gen. 2010, 373, 1-56.
16. Vallette, H.; Pican, S.; Boudou, C.; Levillain, J.; Plaquevent, J. C.; Gaumont, A. C. Palladium Catalyzed C-P Cross-coupling Reactions in Ionic Liquids. Tetrahedron Lett. 2006, 47, 5191-5193.
17. Welton, T. Ionic Liquids in Catalysis. Coord. Chem. Rev. 2004, 248, 2459-2477.
18. 2 Adsorption in the Amine-containing SBA-15 by Hydroxyl Group. Microporous Mesoporous Mater. 2008, 114, 74-81.
19. Zhang, Y.; Jiao, Q.; Zhen, B.; Wu, Q.; Li, H. Transesterification of Glycerol Trioleate Catalyzed by Basic Ionic Liquids Immobilized on Magnetic Nanoparticles: Influence of Pore Diffusion Effect. Appl. Catal. A: Gen. 2013, 453, 327-333.
20. Zhao, H.; Yu, N.; Ding, Y.; Tan, R.; Liu, C.; Yin, D.; Qiu, H. Task-Specific Basic Ionic Liquid Immobilized on Mesoporous Silicas: Efficient and Reusable Catalysts for Knoevenagel Condensation in Aqueous Media. Microporous Mesoporous Mater. 2010, 136, 10-17.
21. Srivastava, R. An Efficient, Eco-friendly Process for Aldol and Michael Reactions of Trimethylsilyl Enolate over Organic Basefunctionalized SBA-15 Catalysts. J. Mol. Catal. A: Chem. 2007, 64, 146-152.
22. 2 with Epoxides. Catal. Today 2013, 200, 117-124.
23. Rodriguez, I.; Iborra, S.; Corma, A.; Rey, F.; Jordá, J. L. MCM-41-Quaternary Organic Tetraalkylammonium Hydroxide Composites as Strong and Stable Brønsted Base Catalysts. Chem. Commun. 1999, 7, 593-594.
24. Xie, W.; Li, H. Alumina-supported Potassium Iodide as a Heterogeneous Catalyst for Biodiesel Production from Soybean Oil. J. Mol. Catal. A: Chem. 2006, 255, 1-9.
25. Gelbard, G.; Bres, O.; Vargas, R. M.; Vielfaure, F.; Schuchardt, U. F. 1H Nuclear Magnetic Resonance Determination of the Yield of the Transesterification of Rapeseed Oil with Methanol. J. Am. Oil Chem. Soc. 1995, 72, 1239-1241.
26. Li, M.; Pham, P. J.; Pittman, C. U., Jr.; Li, T. SBA-15-Supported Ionic Liquid Compounds Containing Silver Salts: Novel Mesoporous π-complexing Sorbents for Separating Polyunsaturated Fatty Acid Methyl Esters. Microporous Mesoporous Mater. 2009, 117, 436-443.
27. Kalita, P.; Kumar, R. Immobilization of 1, 5, 7-Triazabicyclo [4.4.0] dec-5-ene over Mesoporous Materials: an Efficient Catalyst for Michael-addition Reactions under Solvent-free Condition. Appl. Catal. A: Gen. 2011, 397, 250-258.
28. C¸itak, A.; Erdem, B.; Erdem, S.; Öksüzoʇlu, R. M. Synthesis, Characterization and Catalytic Behavior of Functionalized Mesoporous SBA-15 with Various Organo-silanes. J. Colloid Interface Sci. 2012, 369, 160-163.
29. 2 as Oxidant. Catal. Commun. 2012, 24, 56-60.
30. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds; John Wiley & Sons: New York, 1978.
31. Colthup, N. B.; Daly, L. H.; Wiberley, S. E. Introduction to Infrared and Raman Spectroscopy; Academic Press: New York, 1990.
32. Karavalakis, G.; Anastopoulos, G.; Stournas, S. Tetramethylguanidine as an Efficient Catalyst for Transesterification of Waste Frying Oils. Appl. Energy 2011, 88, 3645-3650.
33. White, L. D.; Tripp, C. P. Reaction of (3-Aminopropyl)-dimethylethoxysilane with Amine Catalysts on Silica Surfaces. J. Colloid Interface Sci. 2000, 232, 400-407.
34. Meloni, D.; Monaci, R.; Zedde, Z.; Gcutrufello, M.; Fiorilli, S.; Ferino, I. Transesterification of Soybean Oil on Guanidine Base-functionalized SBA-15 Catalysts. Appl. Catal. B: Environ. 2011, 102, 505-514.
35. Xie, W.; Fan, M. Immobilization of Tetramethylguanidine on Mesoporous SBA-15 Silica: a Heterogeneous Basic Catalyst for Transesterification of Soybean Oil. Bioresour. Technol. 2013, 139, 388-392.
36. Dias, J. M.; Alvim-Ferraz, M. C. M.; Almeida, M. F.; Méndez Díaz, J. D.; Sánchez Polo, M.; Rivera Utrilla, J. Biodiesel Production Using Calcium Manganese Oxide as Catalyst and Different Raw Materials. Energy Convers. Manage. 2013, 65, 647-653.
37. 2 Mixed Oxides. Fuel 2011, 90, 1868-1874.