Polyethylenimine-functionalized poly(vinyl alcohol) magnetic microspheres as a novel adsorbent for rapid removal of Cr(VI) from aqueous solution

Chemical Engineering Journal

Volumn 262, Issue , 2015, Pages 101-108

  Sun, Xitong ^a,b   Yang, Liangrong ^a   Li, Qian ^c   Liu, Zhini ^a,d   Dong, Tingting ^a,b   Liu, Huizhou ^a  

^a INSTITUTE OF PROCESS ENGINEERING   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c DALIAN POLYTECHNIC UNIVERSITY   (China)

^d XIANGTAN UNIVERSITY   (China)

Author keywords

Adsorption; Cr(VI); Polyethylenimine; PVA; Superparamagnetic

Indexed keywords

ADSORPTION ISOTHERMS; CHROMIUM COMPOUNDS; MAGNETIC BUBBLES; MAGNETISM; MICROSPHERES; POLYVINYL ACETATES; POLYVINYL ALCOHOLS; REUSABILITY; SOLUTIONS; SUPERPARAMAGNETISM; SYNTHESIS (CHEMICAL);

ADSORPTION CAPACITIES; DESORPTION EFFICIENCY; MODIFIED SUSPENSION POLYMERIZATION; POLYETHYLENIMINES; PVA; SATURATED MAGNETIZATION; SUPERPARAMAGNETICS; THERMODYNAMIC PARAMETER;

ADSORPTION;

EID: 84949116260     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2014.09.045     Document Type: Article

References (43)

1. Maksin D.D., Nastasovic A.B., Milutinovic-Nikolic A.D., Surucic L.T., Sandic Z.P., Hercigonja R.V., Onjia A.E. Equilibrium and kinetics study on hexavalent chromium adsorption onto diethylene triamine grafted glycidyl methacrylate based copolymers. J. Hazard. Mater. 2012, 209-210:99-110.
2. Sun X.T., Yang L.R., Xing H.F., Zhao J.M., Li X.P., Huang Y.B., Liu H.Z. High capacity adsorption of Cr(VI) from aqueous solution using polyethylenimine-functionalized poly(glycidyl methacrylate) microspheres. Colloids Surf. A 2014, 457:160-168.
3. Sarin V., Singh T.S., Pant K.K. Thermodynamic and breakthrough column studies for the selective sorption of chromium from industrial effluent on activated eucalyptus bark. Bioresour. Technol. 2006, 97:1986-1993.
4. Xing Y.Q., Chen X.M., Wang D.H. Electrically regenerated ion exchange for removal and recovery of Cr(VI) from wastewater. Environ. Sci. Technol. 2007, 41:1439-1443.
5. Barrera-Diaz C.E., Lugo-Lugo V., Bilyeu B. A review of chemical, electrochemical and biological methods for aqueous Cr(VI) reduction. J. Hazard. Mater. 2012, 223-224:1-12.
6. Owlad M., Aroua M.K., Daud W.A.W., Baroutian S. Removal of hexavalent chromium-contaminated water and wastewater: a review. Water Air Soil Pollut. 2009, 200:59-77.
7. Giri A.K., Patel R., Mandal S. Removal of Cr (VI) from aqueous solution by Eichhornia crassipes root biomass-derived activated carbon. Chem. Eng. J. 2012, 185-186:71-81.
8. Al-Othman Z.A., Ali R., Naushad M. Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell: adsorption kinetics, equilibrium and thermodynamic studies. Chem. Eng. J. 2012, 184:238-247.
9. Nemr A.E. Potential of pomegranate husk carbon for Cr(VI) removal from wastewater: kinetic and isotherm studies. J. Hazard. Mater. 2009, 161:132-141.
10. Nethaji S., Sivasamy A., Mandal A.B. Preparation and characterization of corn cob activated carbon coated with nano-sized magnetite particles for the removal of Cr(VI). Bioresour. Technol. 2013, 134:94-100.
11. Kumar A.S.K., Kalidhasan S., Rajesh V., Rajesh N. Application of cellulose-clay composite biosorbent toward the effective adsorption and removal of chromium from industrial wastewater. Ind. Eng. Chem. Res. 2012, 51:58-69.
12. Ngah W.S.W., Teong L.C., Hanafiah M.A.K.M. Adsorption of dyes and heavy metal ions by chitosan composites: a review. Carbohydr. Polym. 2011, 83:1446-1456.
13. Niu L., Deng S.B., Yu G., Huang J. Efficient removal of Cu(II), Pb(II), Cr(VI) and As(V) from aqueous solution using an aminated resin prepared by surface-initiated atom transfer radical polymerization. Chem. Eng. J. 2010, 165:751-757.
14. Samani M.R., Borghei S.M., Olad A., Chaichi M.J. Removal of chromium from aqueous solution using polyaniline-poly ethylene glycol composite. J. Hazard. Mater. 2010, 184:248-254.
15. Miretzky P., Cirelli A.F. Cr(VI) and Cr(III) removal from aqueous solution by raw and modified lignocellulosic materials: a review. J. Hazard. Mater. 2010, 180:1-19.
16. Saha B., Orvig C. Biosorbents for hexavalent chromium elimination from industrial and municipal effluents. Coord. Chem. Rev. 2010, 254:2959-2972.
17. Albadarin A.B., Mangwandi C., Al-Muhtaseb A.A.H., Walker G.M., Allen S.J., Ahmad M.N.M. Kinetic and thermodynamics of chromium ions adsorption onto low-cost dolomite adsorbent. Chem. Eng. J. 2012, 179:193-202.
18. Mulange Wa Mulange D., Garbers-Craig A.M. Stabilization of Cr(VI) from fine ferrochrome dust using exfoliated vermiculite. J. Hazard. Mater. 2012, 223-224:46-52.
19. Donia A.M., Atia A.A., Abouzayed F.I. Preparation and characterization of nano-magnetic cellulose with fast kinetic properties towards the adsorption of some metal ions. Chem. Eng. J. 2012, 191:22-30.
20. Sun X.T., Yang L.R., Xing H.F., Zhao J.M., Li X.P., Huang Y.B., Liu H.Z. Synthesis of polyethylenimine-functionalized poly(glycidyl methacrylate) magnetic microspheres and their excellent Cr(VI) ion removal properties. Chem. Eng. J. 2013, 234:338-345.
21. 3 and multi-walled carbon nanotubes with enhanced adsorption properties for methyl orange. Bioresour. Technol. 2010, 101:5063-5069.
22. 4 magnetic nanocomposite. J. Hazard. Mater. 2011, 190:381-390.
23. Bayramoglu G., Yakuparica M. Adsorption of Cr(VI) onto PEI immobilized acrylate-based magnetic beads: isotherms, kinetics and thermodynamics study. Chem. Eng. J. 2008, 139:20-28.
24. Pang Y., Zeng G.M., Tang L., Zhang Y., Liu Y.Y., Lei X.X., Li Z., Zhang J.C., Liu Z.F., Xiong Y.Q. Preparation and application of stability enhanced magnetic nanoparticles for rapid removal of Cr(VI). Chem. Eng. J. 2011, 175:222-227.
25. Huang S.H., Chen D.H. Rapid removal of heavy metal cations and anions from aqueous solutions by an amino-functionalized magnetic nano-adsorbent. J. Hazard. Mater. 2009, 163:174-179.
26. 4 magnetic polymers for removal of Cr(VI) in wastewater. J. Hazard. Mater. 2010, 182:295-302.
27. 2+ crosslinking and freeze-thawing cycles for controlled release of diclofenac sodium. Int. J. Biol. Macromol. 2010, 46:517-523.
28. Paradossi G., Cavalieri F., Chiessi E., Spagnoli C., Cowman M.K. Poly(vinyl alcohol) as versatile biomaterial for potential biomedical applications. J. Mater. Sci. - Mater. Med. 2003, 14:687-691.
29. Li P.F., Yang L.R., He X.Q., Wang J., Kong P., Xing H.F., Liu H.Z. Synthesis of PGMA microspheres with amino groups for high-capacity adsorption of Cr(VI) by cerium initiated graft polymerization. Chin. J. Chem. Eng. 2012, 20:95-104.
30. Chen S.H., Yue Q.Y., Gao B.Y., Li Q., Xu X. Removal of Cr(VI) from aqueous solution using modified corn stalks: characteristic, equilibrium, kinetic and thermodynamic study. Chem. Eng. J. 2011, 168:909-917.
31. Ma Z.Y., Guan Y.P., Liu X.Q., Liu H.Z. Preparation and characterization of micron-sized non-porous magnetic polymer microspheres with immobilized metal affinity ligands by modified suspension polymerization. J. Appl. Polym. Sci. 2005, 96:2174-2180.
32. Zhu H.Y., Fu Y.Q., Jiang R., Yao J., Xiao L., Zeng G.M. Novel magnetic chitosan/poly(vinyl alcohol) hydrogel beads: preparation, characterization and application for adsorption of dye from aqueous solution. Bioresour. Technol. 2012, 105:24-30.
33. Hu X.J., Wang J.S., Liu Y.G., Li X., Zeng G.M., Bao Z.L., Zeng X.X., Chen A.W., Long F. Adsorption of chromium (VI) by ethylenediamine-modified cross-linked magnetic chitosan resin: isotherms, kinetics and thermodynamics. J. Hazard. Mater. 2011, 185:306-314.
34. 3) nanoparticles. Sep. Purif. Technol. 2007, 58:76-82.
35. Wang Q., Guan Y.P., Liu X., Ren X.F., Yang M.Z. High-capacity adsorption of hexavalent chromium from aqueous solution using magnetic microspheres by surface dendrimer graft modification. J. Colloid Interface Sci. 2012, 375:160-166.
36. 4/PPy composite microspheres and their excellent Cr(VI) ion removal properties. J. Mater. Chem. 2012, 22:9034-9040.
37. 4 magnetic polymers in Cu(II), Cr(VI) co-existing water system. Chem. Eng. J. 2012, 183:180-191.
38. Sun X.T., Yang L.R., Li Q., Zhao J.M., Li X.P., Wang X.Q., Liu H.Z. Amino-functionalized magnetic cellulose nanocomposite as adsorbent for removal of Cr(VI): synthesis and adsorption studies. Chem. Eng. J. 2014, 241:175-183.
39. Wei L.S., Yang G., Wang R., Ma W. Selective adsorption and separation of chromium(VI) on the magnetic iron-nickel oxide from waste nickel liquid. J. Hazard. Mater. 2009, 164:1159-1163.
40. Huang G.L., Zhang H.Y., Shi J.X., Langrish T.A.G. Adsorption of chromium(VI) from aqueous solutions using cross-linked magnetic chitosan beads. Ind. Eng. Chem. Res. 2009, 48:2646-2651.
41. Li H.D., Li Z., Liu T., Xiao X., Peng Z.H., Deng L. A novel technology for biosorption and recovery hexavalent chromium in wastewater by bio-functional magnetic beads. Bioresour. Technol. 2008, 99:6271-6279.
42. Abou El-Reash Y.G., Otto M., Kenawy I.M., Ouf A.M. Adsorption of Cr(VI) and As(V) ions by modified magnetic chitosan chelating resin. Int. J. Biol. Macromol. 2011, 49:513-522.
43. Badruddoza A.Z.M., Tay A.S.H., Tan P.Y., Hidajat K., Uddin M.S. Carboxymethyl-beta-cyclodextrin conjugated magnetic nanoparticles as nano-adsorbents for removal of copper ions: synthesis and adsorption studies. J. Hazard. Mater. 2011, 185:1177-1186.