Mechanisms of magnesium ion transport in pyrrolidinium bis(trifluoromethanesulfonyl)imide-based ionic liquid electrolytes

Journal of Physical Chemistry C

Volumn 118, Issue 49, 2014, Pages 28361-28368

  Jeremias, Sebastian ^a   Giffin, Guinevere A ^a,b,c   Moretti, Arianna ^a,b,c   Jeong, Sangsik ^a,b,c   Passerini, Stefano ^a,b,c  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b HELMHOLTZ INSTITUTE ULM HIU   (Germany)

^c KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFUSION; ELECTROLYTES; ION EXCHANGE; METAL IONS;

AMBIENT CONDITIONS; BIDENTATE COORDINATION; BIS(TRIFLUOROMETHANE SULFONYL)IMIDE; BRIDGING MECHANISM; DIFFUSION BEHAVIOR; IONIC LIQUID ELECTROLYTES; SALT CONCENTRATION; STRUCTURAL DIFFUSION;

IONIC LIQUIDS;

EID: 84949114957     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp5071506     Document Type: Article

References (40)

1. Yoo, H. D.; Shterenberg, I.; Gofer, Y.; Gershinsky, G.; Pour, N.; Aurbach, D. Mg Rechargeable Batteries: an On-Going Challenge Energy Environ. Sci. 2013, 6, 2265-2279
2. Muldoon, J.; Bucur, C. B.; Oliver, A. G.; Sugimoto, T.; Matsui, M.; Kim, H. S.; Allred, G. D.; Zajicek, J.; Kotani, Y. Electrolyte Roadblocks to a Magnesium Rechargeable Battery Energy Environ. Sci. 2012, 5, 5941-5950
3. Balducci, A.; Jeong, S. S.; Kim, G. T.; Passerini, S.; Winter, M.; Schmuck, M.; Appetecchi, G. B.; Marcilla, R.; Mecerreyes, D.; Barsukov, V. Development of Safe, Green and High Performance Ionic Liquids-Based Batteries (ILLIBATT Project) J. Power Sources 2011, 196, 9719-9730
4. Amir, N.; Vestfrid, Y.; Chusid, O.; Gofer, Y.; Aurbach, D. Progress in Nonaqueous Magnesium Electrochemistry J. Power Sources 2007, 174, 1234-1240
5. Cheek, G. T.; OGrady, W. E.; El, A. S. Z.; Moustafa, E. M.; Endres, F. Studies on the Electrodeposition of Magnesium in Ionic Liquids J. Electrochem. Soc. 2007, 155, D91-D95
6. Kakibe, T.; Hishii, J.-y.; Yoshimoto, N.; Egashira, M.; Morita, M. Binary Ionic Liquid Electrolytes Containing Organo-Magnesium Complex for Rechargeable Magnesium Batteries J. Power Sources 2012, 203, 195-200
7. 2/Acetonitrile Electrolyte for Use in Mg-Ion Cells J. Electrochem. Soc. 2012, 159, A2005-A2009
8. 2+ Cations J. Phys. Chem. C 2014, 118, 9966-9973
9. Piccolo, M.; Giffin, G. A.; Vezzù, K.; Bertasi, F.; Alotto, P.; Guarnieri, M.; Di Noto, V. Molecular Relaxations in Magnesium Polymer Electrolytes via GHz Broadband Electrical Spectroscopy ChemSusChem 2013, 6, 2157-2160
10. 2 Solid State Ionics 2002, 147, 377-382
11. x Polymer Electrolytes: Studies Based on Electrical Spectroscopy Solid State Ionics 2002, 147, 309-316
12. 2 and Poly(ethylene glycol) 400 Electrochim. Acta 1998, 43, 1225-1237
13. Di Noto, V.; Münchow, V.; Vittadello, M.; Collet, J. C.; Lavina, S. Synthesis, Characterization and Conductivity Studies of Li and Mg Polymer Electrolytes Based on Esters of Ethylenediaminetetraacetic Acid and PEG400 Solid State Ionics 2002, 147, 397-402
14. 2 Solid State Ionics 2002, 147, 341-347
15. Appetecchi, G. B.; Scaccia, S.; Tizzani, C.; Alessandrini, F.; Passerini, S. Synthesis of Hydrophobic Ionic Liquids for Electrochemical Applications J. Electrochem. Soc. 2006, 153, A1685-A1691
16. Montanino, M.; Alessandrini, F.; Passerini, S.; Appetecchi, G. B. Water-Based Synthesis of Hydrophobic Ionic Liquids for High-Energy Electrochemical Devices Electrochim. Acta 2013, 96, 124-133
17. Di Noto, V.; Giffin, G. A.; Vezzù, K.; Piga, M.; Lavina, S. Broadband Dielectric Spectroscopy: A Powerful Tool for the Determination of Charge Transfer Mechanisms in Ion Conductors. Solid State Proton Conductors: Properties and Applications in Fuel Cells; Wiley: New York, 2012; pp 109-183.
18. x Electrolytic Complexes: Studies Based on Electrical Spectroscopy J. Phys. Chem. B 2001, 105, 4584-4595
19. - Anions Chem. Mater. 2004, 16, 2881-2885
20. Triolo, A.; Russina, O.; Fazio, B.; Appetecchi, G. B.; Carewska, M.; Passerini, S. Nanoscale Organization in Piperidinium-based Room Temperature Ionic Liquids J. Chem. Phys. 2009, 130, 164521
21. Zhou, Q.; Fitzgerald, K.; Boyle, P. D.; Henderson, W. A. Phase Behavior and Crystalline Phases of Ionic Liquid-Lithium Salt Mixtures with 1-Alkyl-3-methylimidazolium Salts Chem. Mater. 2010, 22, 1203-1208
22. 14 Electrochim. Acta 2012, 60, 163-169
23. -) J. Raman Spectrosc. 2005, 36, 762-770
24. 2NH (HTFSI) J. Phys. Chem. A 1998, 102, 3249-3258
25. Brouillette, D.; Irish, D. E.; Taylor, N. J.; Perron, G.; Odziemkowski, M.; Desnoyers, J. E. Stable Solvates in Solution of Lithium Bis(trifluoromethylsulfone)imide in Glymes and Other Aprotic Solvents: Phase Diagrams, Crystallography and Raman Spectroscopy Phys. Chem. Chem. Phys. 2002, 4, 6063-6071
26. Cao, Y.; Mu, T. Comprehensive Investigation on the Thermal Stability of 66 Ionic Liquids by Thermogravimetric Analysis Ind. Eng. Chem. Res. 2014, 53, 8651-8664
27. Zhou, Q.; Henderson, W. A.; Appetecchi, G. B.; Montanino, M.; Passerini, S. Physical and Electrochemical Properties of N-Alkyl-N-methylpyrrolidinium Bis(fluorosulfonyl)imide Ionic Liquids: PY13FSI and PY14FSI J. Phys. Chem. B 2008, 112, 13577-13580
28. MacFarlane, D. R.; Meakin, P.; Amini, N.; Forsyth, M. Structural Studies of Ambient Temperature Plastic Crystal Ion Conductors J. Phys.: Condens. Matter 2001, 13, 8257-8267
29. Moreno, M.; Montanino, M.; Carewska, M.; Appetecchi, G. B.; Jeremias, S.; Passerini, S. Water-Soluble, Triflate-Based, Pyrrolidinium Ionic Liquids Electrochim. Acta 2013, 99, 108-116
30. Frömling, T.; Kunze, M.; Schönhoff, M.; Sundermeyer, J.; Roling, B. Enhanced Lithium Transference Numbers in Ionic Liquid Electrolytes J. Phys. Chem. B 2008, 112, 12985-12990
31. Vila, J.; Franjo, C.; Pico, J. M.; Varela, L. M.; Cabeza, O. Temperature Behavior of the Electrical Conductivity of EMIM-Based Ionic Liquids in Liquid and Solid States Port. Electrochim. Acta 2007, 25, 163-172
32. Appetecchi, G. B.; Montanino, M.; Carewska, M.; Moreno, M.; Alessandrini, F.; Passerini, S. Chemical-Physical Properties of Bis(perfluoroalkylsulfonyl)imide-based Ionic Liquids Electrochim. Acta 2011, 56, 1300-1307
33. Pitawala, J.; Kim, J.-K.; Jacobsson, P.; Koch, V.; Croce, F.; Matic, A. Phase Behaviour, Transport Properties, and Interactions in Li-salt Doped Ionic Liquids Faraday Discuss. 2012, 154, 71-80
34. Bayley, P. M.; Best, A. S.; MacFarlane, D. R.; Forsyth, M. Transport Properties and Phase Behaviour in Binary and Ternary Ionic Liquid Electrolyte Systems of Interest in Lithium Batteries ChemPhysChem 2011, 12, 823-827
35. + Ions in Lithium-Salt-Doped Ionic Liquid Electrolytes J. Phys. Chem. Lett. 2011, 2, 153-157
36. Jeremias, S.; Kunze, M.; Passerini, S.; Schönhoff, M. Polymerizable Ionic Liquid with State of the Art Transport Properties J. Phys. Chem. B 2013, 117, 10596-10602
37. Castiglione, F.; Moreno, M.; Raos, G.; Famulari, A.; Mele, A.; Appetecchi, G. B.; Passerini, S. Structural Organization and Transport Properties of Novel Pyrrolidinium-Based Ionic Liquids with Perfluoroalkyl Sulfonylimide Anions J. Phys. Chem. B 2009, 113, 10750-10759
38. Stilbs, P. Fourier Transform Pulsed-Gradient Spin-Echo Studies of Molecular Diffusion Prog. Nucl. Magn. Reson. Spectrosc. 1987, 19, 1-45
39. - Ionic Liquids J. Phys. Chem. B 2006, 110, 16879-16886
40. Liu, H.; Maginn, E. Effect of Ion Structure on Conductivity in Lithium-Doped Ionic Liquid Electrolytes: A Molecular Dynamics Study J. Chem. Phys. 2013, 139, 114508