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1]- 3 a (>99 % D-enriched at the benzyl proton, and >99 % H-enriched at the activated methane proton) was indeed obtained by column chromatography on silica gel due to the quick exchange of hydrogen in silica gel with the activated deuterium from the product.
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1]- 3 a (>99 % D-enriched at the benzyl proton, and >99 % H-enriched at the activated methane proton) was indeed obtained by column chromatography on silica gel due to the quick exchange of hydrogen in silica gel with the activated deuterium from the product.
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