Kinetics study of C2+ oxygenates synthesis from syngas over Rh-MnOx/SiO2 catalysts

Chemical Engineering Science

Volumn 135, Issue , 2014, Pages 312-322

  Mao, Wei ^a   Su, Junjie ^a   Zhang, Zhengpai ^a   Xu, Xin Chao ^a   Dai, Weiwei ^a   Fu, Donglong ^a   Xu, Jing ^a   Zhou, Xinggui ^a   Han, Yi Fan ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Bimetallic Rh Mn catalysts; C2+ oxygenates; Intrinsic kinetics; Mechanism; MnOx promotional effect; Syngas

Indexed keywords

ACTIVATION ENERGY; CATALYSTS; KINETICS; MANGANESE; MANGANESE OXIDE; MECHANISMS; REACTION KINETICS; SYNTHESIS (CHEMICAL); SYNTHESIS GAS;

C2+ OXYGENATES; INTRINSIC KINETICS; MN CATALYST; PROMOTIONAL EFFECT; SYN-GAS;

RHODIUM;

EID: 84948710097     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2015.02.035     Document Type: Article

References (64)

1. V.R. Ahon, E.F. Costa, J.E.P. Monteagudo, C.E. Fontes, E.C. Biscaia, and P.L.C. Lage A comprehensive mathematical model for the Fischer-Tropsch synthesis in well-mixed slurry reactors Chem. Eng. Sci. 60 2005 677 694
2. 3 catalysts Ind. Eng. Chem. Res. 35 1996 1534 1542
3. 2(110)-(1×2): an STM study J. Catal. 183 1999 91 101
4. Y. Choi, and P. Liu Mechanism of ethanol synthesis from syngas on Rh (111) J. Am. Chem. Soc. 131 2009 13054 13061
5. 2+ oxygenate synthesis on Rh catalysts Top. Catal. 32 2005 225 232
6. G.A. Deluga, J.R. Salge, L.D. Schmidt, and X.E. Verykios Renewable hydrogen from ethanol by autothermal reforming Science 303 2004 993 997
7. A. Egbebi, V. Schwartz, S.H. Overbury, and J.J. Spivey Effect of Li promoter on titania-supported Rh catalyst for ethanol formation from CO hydrogenation Catal. Today 149 2010 91 97
8. A.E. Farrell, R.J. Plevin, B.T. Turner, A.D. Jones, M. O'Hare, and D.M. Kammen Ethanol can contribute to energy and environmental goals Science 311 2006 506 508
9. 2 catalysts J. Catal. 262 2009 119 126
10. 2 for CO hydrogenation: detailed analysis of kinetics and mechanism J. Catal. 268 2009 142 149
11. M. Gupta, M.L. Smith, and J.J. Spivey Heterogeneous catalytic conversion of dry syngas to ethanol and higher alcohols on Cu-based catalysts ACS Catal. 1 2011 641 656
12. M. Haider, M. Gogate, and R. Davis Fe-promotion of supported Rh catalysts for direct conversion of syngas to ethanol J. Catal. 261 2009 9 16
13. 4 nanoparticles supported on mesoporous silica SBA-15 J. Phys. Chem. B 110 2006 24450 24456
14. J.P. Hindermann, G.J. Hutchings, and A. Kiennemann Mechanistic aspects of the formation of hydrocarbons and alcohols from CO hydrogenation Catal. Rev. 35 1993 1 127
15. G.W. Huber, J.N. Chheda, C.J. Barrett, and J.A. Dumesic Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates Science 308 2005 1446 1450
16. G.W. Huber, S. Iborra, and A. Corma Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering Chem. Rev. 106 2006 4044 4098
17. E. Iglesia Design, synthesis, and use of cobalt-based Fischer-Tropsch synthesis catalysts Appl. Catal. A: Gen. 161 1997 59 78
18. M.M.M. Jansen, F.J.E. Scheijen, J. Ashley, B.E. Nieuwenhuys, and J.W. Niemantsverdriet Adsorption/desorption studies of CO on a rhodium (100) surface under UHV conditions: A comparative study using XPS, RAIRS, and SSIMS Catal. Today 154 2010 53 60
19. A.Y. Khodakov, W. Chu, and P. Fongarland Advances in the development of novel cobalt Fischer-Tropsch catalysts for synthesis of long-chain hydrocarbons and clean fuels Chem. Rev. 107 2007 1692 1744
20. R. Linke, D. Curulla, M.J.P. Hopstaken, and J.W. Niemantsverdriet CO/Rh (111): vibrational frequency shifts and lateral interactions in adsorbate layers J. Chem. Phys. 115 2001 8209 8216
21. A.S. Lisitsyn, S.A. Stevenson, and H. Knözinger Carbon monoxide hydrogenation on supported Rh-Mn catalysts J. Mol. Catal. 63 1990 201 211
22. J. Liu, Z. Guo, D. Childers, N. Schweitzer, C.L. Marshall, R.F. Klie, J.T. Miller, and R.J. Meyer Correlating the degree of metal-promoter interaction to ethanol selectivity over MnRh/CNTs CO hydrogenation catalysts J. Catal. 313 2014 149 158
23. 2 alcohol synthesis catalysts ChemCatChem 5 2013 3665 3672
24. Z. Liu, X. Li, M.R. Close, E.L. Kugler, J.L. Petersen, and D.B. Dadyburjor Screening of alkali-promoted vapor-phase-synthesized molybdenum sulfide catalysts for the production of alcohols from synthesis gas Ind. Eng. Chem. Res. 36 1997 3085 3093
25. 2 contained syngas on supported molybdenum sulfide catalysts Appl. Catal. A: Gen. 150 1997 243 252
26. 2-oxygenates from syngas Appl. Catal. A: Gen. 214 2001 161 166
27. 3 nanocrystals during CO oxidation by Operando Raman spectroscopy J. Phys. Chem. C 116 2012 20975 20981
28. 2 and nanoporous zeolitic material supported Rh-Mn catalysts Surf. Interface Anal. 32 2001 224 227
29. 3 catalysts Catal. Today 228 2014 158 166
30. X.F. Ma, H.Y. Su, H.Q. Deng, and W.X. Li Carbon monoxide adsorption and dissociation on Mn-decorated Rh (111) and Rh (553) surfaces: A first-principles study Catal. Today 160 2011 228 233
31. R.J. Madon, and M. Boudart Experimental criterion for the absence of artifacts in the measurement of rates of heterogeneous catalytic reactions Ind. Eng. Chem. Fundam. 21 1982 438 447
32. S.M. McClure, M.J. Lundwall, and D.W. Goodman Planar oxide supported rhodium nanoparticles as model catalysts Proc. Natl. Acad. Sci. U. S. A. 108 2011 931 936
33. A. Medford, A. Lausche, F. Abild-Pedersen, B. Temel, N. Schjødt, J. Nørskov, and F. Studt Activity and selectivity trends in synthesis gas conversion to higher alcohols Top. Catal. 57 2014 135 142
34. 2 catalysts: a combined experimental and theoretical modeling study J. Catal. 271 2010 325 342
35. 2 for CO hydrogenation: effect on adsorption and reaction J. Catal. 267 2009 167 176
36. 13C incorporation patterns J. Catal. 113 1988 410 433
37. 2-oxygenates synthesis from syngas - effect of manganese loading Appl. Catal. A: Gen. 261 2004 47 55
38. X. Pan, Z. Fan, W. Chen, Y. Ding, H. Luo, and X. Bao Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles Nat. Mater. 6 2007 507 511
39. L. Petrus, and M.A. Noordermeer Biomass to biofuels, a chemical perspective Green Chem. 8 2006 861 867
40. G. Prieto, S. Beijer, M.L. Smith, M. He, Y. Au, Z. Wang, D.A. Bruce, K.P. de Jong, J.J. Spivey, and P.E. de Jongh Design and synthesis of copper-cobalt catalysts for the selective conversion of synthesis gas to ethanol and higher alcohols Angew. Chem. Int. Ed. 53 2014 6397 6401
41. G. Prieto, P. Concepción, A. Martínez, and E. Mendoza New insights into the role of the electronic properties of oxide promoters in Rh-catalyzed selective synthesis of oxygenates from synthesis gas J. Catal. 280 2011 274 288
42. 2 reaction on some modified iron-catalysts Appl. Catal. 13 1984 193 210
43. W.M.H. Sachtler, and M. Ichikawa Catalytic site requirements for elementary steps in syngas conversion to oxygenates over promoted rhodium J. Phys. Chem. 90 1986 4752 4758
44. H. Schulz Selforganization in Fischer-Tropsch synthesis with iron- and cobalt catalysts Catal. Today 228 2014 113 122
45. V. Schwartz, A. Campos, A. Egbebi, J.J. Spivey, and S.H. Overbury EXAFS and FT-IR characterization of Mn and Li promoted titania-supported Rh catalysts for CO hydrogenation ACS Catal. 1 2011 1298 1306
46. J.J. Spivey, and A. Egbebi Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas Chem. Soc. Rev. 36 2007 1514
47. A. Stroppa, F. Mittendorfer, J.N. Andersen, G. Parteder, F. Allegretti, S. Surnev, and F.P. Netzer Adsorption and dissociation of CO on bare and Ni-decorated stepped Rh (553) surfaces J. Phys. Chem. C 113 2008 942 949
48. 2 catalysts AIChE J. 60 2014 1797 1809
49. V. Subramani, and S.K. Gangwal A review of recent literature to search for an efficient catalytic process for the conversion of syngas to ethanol Energy Fuels 22 2008 814 839
50. 2/CO ratio, space velocity, and pressure on ethanol selectivity from syngas J. Catal. 272 2010 204 209
51. V.R. Surisetty, A.K. Dalai, and J. Kozinski Intrinsic reaction kinetics of higher alcohol synthesis from synthesis gas over a sulfided alkali-promoted Co-Rh-Mo trimetallic catalyst supported on multiwalled carbon nanotubes (MWCNTs) Energy Fuels 24 2010 4130 4137
52. V.R. Surisetty, A.K. Dalai, and J. Kozinski Alcohols as alternative fuels: an overview Appl. Catal. A: Gen. 404 2011 1 11
53. H. Treviño, T. Hyeon, and W.M.H. Sachtler A novel concept for the mechanism of higher oxygenate formation from synthesis gas over MnO-promoted rhodium catalysts J. Catal. 170 1997 236 243
54. 2 in silica-supported rhodium catalysts J. Catal. 93 1985 340 352
55. J. Wang, P.A. Chernavskii, A.Y. Khodakov, and Y. Wang Structure and catalytic performance of alumina-supported copper-cobalt catalysts for carbon monoxide hydrogenation J. Catal. 286 2012 51 61
56. Y. Wang, H. Luo, D. Liang, and X. Bao Different mechanisms for the formation of acetaldehyde and ethanol on the Rh-based catalysts J. Catal. 196 2000 46 55
57. K. Xiao, X. Qi, Z. Bao, X. Wang, L. Zhong, K. Fang, M. Lin, and Y. Sun CuFe, CuCo and CuNi nanoparticles as catalysts for higher alcohol synthesis from syngas: a comparative study Catal. Sci. Technol. 3 2013 1591 1602
58. B.-Q. Xu, and W.M.H. Sachtler Rh/NaY: A selective catalyst for direct synthesis of acetic acid from syngas J. Catal. 180 1998 194 206
59. 3 nanocatalyst J. Catal. 300 2013 225 234
60. 2 catalysts with various Rh loadings Energy Fuels 17 2003 1401 1406
61. 2 J. Mol. Catal. A: Chem. 367 2013 38 45
62. S. Zaman, and K.J. Smith A Review of molybdenum catalysts for synthesis gas conversion to alcohols: catalysts, mechanisms and kinetics Catal. Rev.-Sci. Eng. 54 2012 41 132
63. x thin films on Rh (111) Surf. Sci. 606 2012 1507 1511
64. Y. Zhang, M.E. Grass, J.N. Kuhn, F. Tao, S.E. Habas, W. Huang, P. Yang, and G.A. Somorjai Highly selective synthesis of catalytically active monodisperse rhodium nanocubes J. Am. Chem. Soc. 130 2008 5868 5869