High-Performance Flexible All-Solid-State Supercapacitor from Large Free-Standing Graphene-PEDOT/PSS Films

Scientific Reports

Volumn 5, Issue , 2015, Pages

  Liu, Yuqing ^a   Weng, Bo ^b   Razal, Joselito M ^c   Xu, Qun ^d   Zhao, Chen ^a   Hou, Yuyang ^a   Seyedin, Shayan ^c   Jalili, Rouhollah ^a   Wallace, Gordon G ^a   Chen, Jun ^a  

^a UNIVERSITY OF WOLLONGONG   (Australia)

^b SOUTHWEST UNIVERSITY   (China)

^c DEAKIN UNIVERSITY   (Australia)

^d ZHENGZHOU UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84947742775     PISSN: None     EISSN: 20452322     Source Type: Journal    
DOI: 10.1038/srep17045     Document Type: Article

References (48)

1. Yoshio, M., Brodd, R. J., Kozawa, A. Lithium-ion batteries: science and technologies. Springer (2009).
2. Winter, M., Brodd R. J. What are batteries, fuel cells and supercapacitors Chem. Rev. 104, 4245-4269 (2004).
3. Miller, J. R., Simon, P. Electrochemical capacitors for energy management. Science (New York, NY) 321, 651-652 (2008).
4. Pech, D. et al. Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nat. Nanotechnol. 5, 651-654 (2010).
5. Lang, X., Hirata, A., Fujita, T., Chen, M. Nanoporous metal/oxide hybrid electrodes for electrochemical supercapacitors. Nat. Nanotechnol. 6, 232-236 (2011).
6. Kang, Y. J., Chung, H., Han, C.-H., Kim, W. All-solid-state flexible supercapacitors based on papers coated with carbon nanotubes and ionic-liquid-based gel electrolytes. Nanotechnology 23, 289501 (2012).
7. Hu, L. et al. Stretchable, porous, and conductive energy textiles. Nano Lett. 10, 708-714 (2010).
8. Chen, W. et al. High-performance nanostructured supercapacitors on a sponge. Nano Lett. 11, 5165-5172 (2011).
9. Yuan, L. et al. Polypyrrole-coated paper for flexible solid-state energy storage. Energy Environ. Sci. 6, 470-476 (2013).
10. Yuan, L. et al. Paper-based supercapacitors for self-powered nanosystems. Angew. Chem. Int. Ed. 51, 4934-4938 (2012).
11. Anothumakkool, B., Torris, A. T. A., Bhange, S. N., Badiger, M. V., Kurungot, S. Electrodeposited polyethylenedioxythiophene with infiltrated gel electrolyte interface: a close contest of an all-solid-state supercapacitor with its liquid-state counterpart. Nanoscale 6, 5944-5952 (2014).
12. Moon, I. K., Lee, J., Ruoff, R. S., Lee, H. Reduced graphene oxide by chemical graphitization. Nat. Commun. 1, 73 (2010).
13. Choi, B. G., Hong, J., Hong, W. H., Hammond, P. T., Park, H. Facilitated Ion Transport in all-solid-state flexible supercapacitors. ACS Nano 5(9), 7205-7213 (2011).
14. Jo, K. et al. Stable aqueous dispersion of reduced graphene nanosheets via non-covalent functionalization with conducting polymers and application in transparent electrodes. Langmuir 27, 2014-2018 (2011).
15. Kaempgen, M., Chan, C. K., Ma, J., Cui, Y., Gruner, G. Printable thin film supercapacitors using single-walled carbon nanotubes. Nano lett. 9, 1872-1876 (2009).
16. Wu, Z. S., Liu, Z., Parvez, K., Feng, X., Mullen, K. Ultrathin Printable Graphene Supercapacitors with AC Line-Filtering Performance. Adv. Mater. 27, 3669-3675 (2015).
17. Choi, K. S., Liu, F., Choi, J. S., Seo, T. S. Fabrication of free-standing multilayered graphene and poly(3,4-ethylenedioxythiophene) composite films with enhanced conductive and mechanical properties. Langmuir 26, 12902-12908 (2010).
18. Crispin, X. et al. The origin of the high conductivity of ( PEDOT-PSS ) plastic electrodes. Chem. Mater. 18, 4354-4360 (2006).
19. Ryu, K. S. et al. Poly(ethylenedioxythiophene) (PEDOT) as polymer electrode in redox supercapacitor. Electrochim. Acta 50, 843-847 (2004).
20. Snook, G. A., Kao, P., Best, A. S. Conducting-polymer-based supercapacitor devices and electrodes. J. Power Sources 196, 1-12 (2011).
21. Wu, Q., Xu, Y., Yao, Z., Liu, A., Shi, G. Supercapacitors based on flexible graphene/polyaniline nanofiber composite films. ACS Nano 4(4), 1963-1970 (2010).
22. Li, Z. et al. Flexible graphene/MnO2 composite papers for supercapacitor electrodes. J. Mater. Chem. 21, 14706-14706 (2011).
23. Gao, K. et al. Cellulose nanofiber-graphene all solid-state flexible supercapacitors. J. Mater. Chem. A 1, 63-63 (2013).
24. Sun, Y., Shi, G. Graphene/polymer composites for energy applications. J. Polym. Sci. Part B Polym. Phys. 51, 231-253 (2013).
25. Yan, J., Wang, Q., Wei, T., Fan, Z. Recent Advances in Design and Fabrication of Electrochemical Supercapacitors with High Energy Densities. Adv. Energy Mater. 4, 1300816 (2014).
26. Kim, J. Y., Jung, J. H., Lee, D. E., Joo, J. Enhancement of electrical conductivity by a change of solvents. Synt. Met. 126, 311-316 (2002).
27. Crispin, X. et al. Stability of Poly (3, 4-ethylene dioxythiophene)-Poly (styrene sulfonate): A Photoelectron Spectroscopy Study. J. Polym. Sci. Part B Polym. Phys. 41, 2561-2583 (2003).
28. Jalili, R., Razal, J. M., Innis, P. C., Wallace, G. G. One-Step Wet-Spinning Process of Poly(3,4-ethylenedioxythiophene):Poly(st yrenesulfonate) Fibers and the Origin of Higher Electrical Conductivity. Adv. Funct. Mater. 21, 3363-3370 (2011).
29. Ouyang, J., Chu, C. W., Chen, F. C., Xu, Q., Yang, Y. High-Conductivity Poly(3,4-ethylenedioxythiophene):Poly(styrene sulfonate) Film and Its Application in Polymer Optoelectronic Devices. Adv. Funct. Mater. 15, 203-208 (2005).
30. Jalili, R., Razal, J. M., Wallace, G. G. Exploiting high quality PEDOT:PSS-SWNT composite formulations for wet-spinning multifunctional fibers. J. Mater. Chem. 22, 25174-25182 (2012).
31. Jalili, R., Razal, J. M., Wallace, G. G. Wet-spinning of PEDOT:PSS/functionalized-SWNTs composite: a facile route toward production of strong and highly conducting multifunctional fibers. Sci. Rep. 3, 3438 (2013).
32. Wang, D. W. et al. Fabrication of Graphene/Polyaniline composite paper via in situ anodic electropolymerization for highperformance flexible electrode. ACS Nano 3(7), 1745-1752 (2009).
33. Zhang, X., Chang, D., Liu, J., Luo, Y. Conducting polymer aerogels from supercritical CO2 drying PEDOT-PSS hydrogels. J. Mater. Chem. 20, 5080-5080 (2010).
34. Antiohos, D. et al. Performance enhancement of single-walled nanotube-microwave exfoliated graphene oxide composite electrodes using a stacked electrode configuration. J. Mater. Chem. A 2, 14835-14835 (2014).
35. Zhang, K., Zhang, L. L., Zhao, X. S., Wu, J. Graphene/Polyaniline nanofiber composites as supercapacitor electrodes. Chem. Mater. 22, 1392-1401 (2010).
36. Wang, X. et al. A facile and cost-effective approach to the reduction of exfoliated graphite oxide using sodium hypophosphite under acidic conditions. J. Mater. Chem. C 1, 690-694 (2013).
37. Stankovich, S. et al. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45, 1558-1565 (2007).
38. Chen, J. et al. Scalable solid-template reduction for designed reduced graphene oxide architectures. ACS Appl. Mater. Interfaces 5, 7676-7681 (2013).
39. Antiohos, D. et al. Manganosite-microwave exfoliated graphene oxide composites for asymmetric supercapacitor device applications. Electrochim. Acta 101, 99-108 (2013).
40. Antiohos, D. et al. Compositional effects of PEDOT-PSS/single walled carbon nanotube films on supercapacitor device performance. J. Mater. Chem. 21, 15987-15994 (2011).
41. Alvi, F. et al. Graphene-polyethylenedioxythiophene conducting polymer nanocomposite based supercapacitor. Electrochim. Acta 56, 9406-9412 (2011).
42. Zhang, J., Zhao, X. S. Conducting polymers directly coated on reduced graphene oxide sheets as high-performance supercapacitor electrodes. J. Phys. Chem. C 116, 5420-5426 (2012)
43. Xu, Y. et al. Flexible solid-state supercapacitors based on three-dimensional. ACS Nano 7(5), 4042-4049 (2013).
44. El-Kady, M. F., Strong, V., Dubin, S., Kaner, R. B. Laser scribing of high-performance and flexible graphene-based electrochemical capacitors. Science (New York, NY) 335, 1326-1330 (2012).
45. Weng, Z. et al. Graphene-cellulose paper flexible supercapacitors. Adv. Energy Mater. 1, 917-922 (2011).
46. Kang, Y. J. et al. All-solid-state flexible supercapacitors fabricated with bacterial nanocellulose papers , carbon nanotubes , and triblock-copolymer ion gels. ACS Nano 6(7), 6400-6406 (2012).
47. Anothumakkool, B., Bhange, S. N., Soni, R., Kurungot, S. Novel scalable synthesis of highly conducting and robust PEDOT paper for high performance flexible solid-supercapacitor. Energy Environ. Sci. 8, 1339-1347 (2015).
48. Marcano, D. C. et al. Improved synthesis of graphene oxide. ACS Nano 4(8), 4806-4814 (2010).