Microcellular to nanocellular polymer foams: Progress (2004-2015) and future directions - A review

European Polymer Journal

Volumn 73, Issue , 2015, Pages 500-519

  Okolieocha, Chimezie ^a   Raps, Daniel ^a   Subramaniam, Kalaivani ^a   Altstädt, Volker ^a  

^a UNIVERSITY OF BAYREUTH   (Germany)

Author keywords

Closed cell; Expansion ratio; Low density; Microcellular foam; Nanocellular foam; Polymer foam

Indexed keywords

CELLS; CYTOLOGY; FOAMS; INJECTION MOLDING; POLYMERS;

CLOSED CELLS; EXPANSION RATIO; LOW DENSITY; MICROCELLULAR FOAMS; NANOCELLULAR FOAMS; POLYMER FOAMS;

MICROCELLULAR RADIO SYSTEMS;

EID: 84946726883     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2015.11.001     Document Type: Review

References (123)

1. A.B. Strong Plastics: Materials and Processing 2005 Pearson Prentice Hall New Jersey
2. J.E. Martini, F.A. Waldman, N.P. Suh, The Production and Analysis of Microcellular Thermoplastic Foams, vol. 43, SPE ANTEC Tech. Pap., 1982, pp. 674-676.
3. L. Sorrentino, M. Aurilia, and S. Iannace Polymeric foams from high performance thermoplastics Adv. Polym. Technol. 30 2011 234 243
4. R.D. Roberts, and J.C. Kwok Styrene-maleic anhydride copolymer foam for heat resistant packaging J. Cell. Plast. 43 2007 135 143
5. S. Subramonian, P. Filiccia, and J. Alcott Novel soft touch, low abrasion, fine cell polyolefin foams J. Cell. Plast. 43 2007 331 343
6. H. Singh, and A.K. Jain Ignition, combustion, toxicity, and fire retardancy of polyurethane foams: a comprehensive review J. Appl. Polym. Sci. 111 2009 1115 1143
7. S. Liu, J. Duvigneau, and G.J. Vancso Nanocellular polymer foams as promising high performance thermal insulation materials Eur. Polym. J. 65 2015 33 45
8. P. Ferkl, R. Pokorný, M. Bobák, and J. Kosek Heat transfer in one-dimensional micro- and nano-cellular foams Chem. Eng. Sci. 97 2013 50 58
9. B. Notario, J. Pinto, E. Solorzano, J.a. de Saja, M. Dumon, and M.a. Rodríguez-Pérez Experimental validation of the Knudsen effect in nanocellular polymeric foams Polymer 56 2014 57 67
10. Y. Kim, C.B. Park, P. Chen, and R.B. Thompson Origins of the failure of classical nucleation theory for nanocellular polymer foams Soft Matter 7 2011 7351 7358
11. P.U. Jung, Development of Innovative Gas-Assisted Foam Injection Molding Technology, 2013, pp. 1-196.
12. D.W. Oxtoby Nucleation of first-order phase transitions Acc. Chem. Res. 31 1998 91 97
13. 2 mixtures Soft Matter 9 2013 9675 9683
14. S. Costeux, I. Khan, S.P. Bunker, and H.K. Jeon Experimental study and modeling of nanofoams formation from single phase acrylic copolymers J. Cell. Plast. 2014
15. 2 and isopentane Cell. Polym. 17 1998 221 251
16. C. Zhang, B. Zhu, and L.J. Lee Extrusion foaming of polystyrene/carbon particles using carbon dioxide and water as co-blowing agents Polymer 52 2011 1847 1855
17. A.N. Paquet, K.W. Suh, Carbon Black-Containing Bimodal Foam Structures and Process for Making, 5,210,105, 1993.
18. M. Mihai, M.A. Huneault, and B.D. Favis Foaming of polystyrene/thermoplastic starch blends J. Cell. Plast. 43 2007 215 236
19. C. Zhang, B. Zhu, D. Li, and L.J. Lee Extruded polystyrene foams with bimodal cell morphology Polymer 53 2012 2435 2442
20. H. Weber, Grave I. De, and E. Röhrl Foamed plastics Ulmann's Encycl. 15 2012 540 570
21. B. Patel, Y. Delaviz, R. Breindel, Mitchell Z. Weekly, R. Loh, Manoj K. Choudhary, Cell Size Enlargers for Polystyrene Foams, WO 2007/149538 A1, 2006.
22. M. Kurte-Jardin, Method and Device for Producing Thermoplastics Foam Panels, Panel Manufactured Using Same Method and Device and Panel Use, EP 2 397 303 A1, 2011.
23. K.W. Suh, C.P. Park, M.J. Maurer, M.H. Tusim, R. De Genova, R. Broos, and et al. Lightweight cellular plastics Adv. Mater. 12 2000 1779 1789
24. Z. Guo, J. Yang, M.J. Wingert, D.L. Tomasko, L.J. Lee, and T. Daniel Comparison of carbon nanofibers and activated carbon on carbon dioxide foaming of polystyrene J. Cell. Plast. 44 2008 453 468
25. D. Scherzer, K. Hahn, G. Alicke, G. Turznik, F.-J. Dietzen, Foam Panel having a Reduced Thermal Conductivity, EP000778309B1, 2002.
26. R.M. Breindel, R.R. Loh, J.P. Rynd, Y. Delaviz, M.E. Polasky, Thermoplastic Foams and Method of Forming them Using Nano-Graphite, US 2011/0064938 A1, 2011.
27. J. Gordon-Duffy, Infrared Attenuated Polymeric Foam Insulation with Flame Retardant Performance, US 2012/0074347 A1, 2012.
28. Y. Delaviz, R.M. Breindel, M.Z. Weekly, Extruded Polystyrene Foam Containing Propylene Carbonate, Ethylene Carbonate or Butylene Carbonate as a Process Aids, US 2011/0144221 A1, 2011.
29. C.V. Vo, and R.T. Fox Assessment of hydrofluoropropenes as insulating blowing agents for extruded polystyrene foams J. Cell. Plast. 49 2013 423 438
30. C. Jacobs, and S.K. Dey Inert gases as alternative blowing agents for extruded low-density polystyrene foam J. Cell. Plast. 31 1995 38 47
31. 2 as Blowing Agent, US 6,268,046 B1, 2001.
32. 2 and 2-ethyl hexanol as replacement foaming agents for extruded polystyrene J. Cell. Plast. 37 2001 262 272
33. K.-M. Lee, E.K. Lee, S.G. Kim, C.B. Park, and H.E. Naguib Bi-cellular foam structure of polystyrene from extrusion foaming process J. Cell. Plast. 45 2009 539 553
34. 2 + 2-propanol) mixture as a foaming agent for polystyrene: a simple thermodynamic model for the high VLE-phase diagrams taking into account foam vitrification J. Appl. Polym. Sci. 104 2007 2663 2671
35. C.V. Vo, and A.N. Paquet An evaluation of the thermal conductivity of extruded polystyrene foam blown with HFC-134a or HCFC-142b J. Cell. Plast. 40 2004 205 228
36. 2 and ethanol J. Cell. Plast. 42 2006 127 138
37. V. Kan, J.J. Hubert, Process for Producing a Thermoplastic Foam Using Water and Ether, EP000937741B1, 2004.
38. Y.P. Handa, Expanded and Extruded Biodegradable and Reduced Emission Foams Made with Methyl Formate-based Blowing Agent, WO 2008/076755 A1, 2008.
39. Y.P. Handa, G.A. Francis, G.C. Castner, M. Zafar, Reduced-VOC and Non-VOC Blowing Agents for Making Expanded and Extruded Thermoplastic Foams, US 2013/0011648, 2013.
40. T. Hayashi, O. Kobayashi, J. Fukuzawa, H. Fujiwara, Extruded Styrene Resin Foams and Methods for Producing the Same, US 6,696,504 B1, 2004.
41. L.M. Michael, R.M. Breindel, M.Z. Weekley, T.E. Cisar, K.J. Prince, Extruded Foam Product with 134A and Alcohol Blowing Agent, US 6,350,789 B1, 2002.
42. L. Chen, K. Blizard, R. Straff, and X. Wang Effect of filler size on cell nucleation during foaming process J. Cell. Plast. 38 2002 139 148
43. N.S. Ramesh, and S.T. Lee Do nanoparticles really assist in nucleation of fine cells in polyolefin foams? Cell. Polym. 24 2005 269 277
44. K. Goren, L. Chen, L.S. Schadler, and R. Ozisik Influence of nanoparticle surface chemistry and size on supercritical carbon dioxide processed nanocomposite foam morphology J. Supercrit. Fluids 51 2010 420 427
45. N.H. Fletcher Size effect in heterogeneous nucleation J. Chem. Phys. 29 1958 572 576
46. L. Chen, R. Ozisik, and L.S. Schadler The influence of carbon nanotube aspect ratio on the foam morphology of MWNT/PMMA nanocomposite foams Polymer 51 2010 2368 2375
47. S.N. Leung, C.B. Park, and H. Li Effects of nucleating agents' shapes and interfacial properties on cell nucleation J. Cell. Plast. 46 2010 441 460
48. R.B. McClurg Design criteria for ideal foam nucleating agents Chem. Eng. Sci. 59 2004 5779 5786
49. S.K. Goel, and E.J. Beckman Generation of microcellular polymeric foams using supercritical carbon dioxide. I: effect of pressure and temperature on nucleation Polym. Eng. Sci. 34 1994 1137 1147
50. 2 binding to carbonyl groups J. Phys. Chem. A 102 1998 7860 7863
51. 2 transport in foaming processes of poly(methyl methacrylate)-block copolymer nanocellular and microcellular foams J. Supercrit. Fluids 94 2014 198 205
52. O. Muth, T. Hirth, and H. Vogel Investigation of sorption and diffusion of supercritical carbon dioxide into poly(vinyl chloride) J. Supercrit. Fluids 19 2001 299 306
53. 2 in isotactic polypropylene/nanomontmorillonite composites in melt and solid states Ind. Eng. Chem. Res. 53 2014 2673 2683
54. 2 Polym. Eng. Sci. 43 2003 1378 1390
55. V. Kumar, and J. Weller Production of microcellular polycarbonate using carbon dioxide for bubble nucleation J. Eng. Ind. 116 1994 413 420
56. J. Pinto, E. Solorzano, M.A. Rodriguez-Perez, and J.A. de Saja Characterization of the cellular structure based on user-interactive image analysis procedures J. Cell. Plast. 49 2013 555 575
57. P. Liu, D. Liu, H. Zou, P. Fan, and W. Xu Structure and properties of closed-cell foam prepared from irradiation crosslinked silicone rubber J. Appl. Polym. Sci. 113 2009 3590 3595
58. C. Saiz-Arroyo, M.a. Rodríguez-Pérez, J. Tirado, A. López-Gil, and J.A. de Saja Structure-property relationships of medium-density polypropylene foams Polym. Int. 62 2013 1324 1333
59. 2-blown nanocellular foams J. Appl. Polym. Sci. 131 2014 41293
60. S.P. Nalawade, F. Picchioni, and L.P.B.M. Janssen Supercritical carbon dioxide as a green solvent for processing polymer melts: processing aspects and applications Prog. Polym. Sci. 31 2006 19 43
61. M. Sauceau, J. Fages, A. Common, C. Nikitine, and E. Rodier New challenges in polymer foaming: a review of extrusion processes assisted by supercritical carbon dioxide Prog. Polym. Sci. 36 2011 749 766
62. 2 for polymer foam applications J. Supercrit. Fluids 47 2009 493 499
63. H. Guanghong, and W. Yue Microcellular Foam Injection Molding Process, Some Critical Issues for Injection Molding 2012 Intech
64. G. Zhao, G. Wang, J. Wang, and L. Zhang Foaming mechanism and control in microcellular injection molding SPE Plast. Res. 2014 10.2417/spepro.005571
65. Z. Ma, G. Zhang, Q. Yang, X. Shi, and A. Shi Fabrication of microcellular polycarbonate foams with unimodal or bimodal cell-size distributions using supercritical carbon dioxide as a blowing agent J. Cell. Plast. 50 2013 55 79
66. 2: solubility versus block copolymers addition J. Cell. Plast. 47 2011 535 548
67. M.P. Tran, C. Detrembleur, M. Alexandre, C. Jerome, and J.M. Thomassin The influence of foam morphology of multi-walled carbon nanotubes/poly(methyl methacrylate) nanocomposites on electrical conductivity Polymer 54 2013 3261 3270
68. J.-B. Bao, T. Liu, L. Zhao, G.-H. Hu, X. Miao, and X. Li Oriented foaming of polystyrene with supercritical carbon dioxide for toughening Polymer 53 2012 5982 5993
69. L. Chen, L.S. Schadler, and R. Ozisik An experimental and theoretical investigation of the compressive properties of multi-walled carbon nanotube/poly(methyl methacrylate) nanocomposite foams Polymer 52 2011 2899 2909
70. D. Miller, P. Chatchaisucha, and V. Kumar Microcellular and nanocellular solid-state polyetherimide (PEI) foams using sub-critical carbon dioxide I. Processing and structure Polymer 50 2009 5576 5584
71. J.E. Weller, and V. Kumar Solid-state microcellular polycarbonate foams. II. The effect of cell size on tensile properties Polym. Eng. Sci. 50 2010 2170 2175
72. H. Janani, and M.H.N. Famili Investigation of a strategy for well controlled inducement of microcellular and nanocellular morphologies in polymers Polym. Eng. Sci. 50 2010 1558 1570
73. C. Li, G. Yang, H. Deng, K. Wang, Q. Zhang, F. Chen, and et al. The preparation and properties of polystyrene/functionalized graphene nanocomposite foams using supercritical carbon dioxide Polym. Int. 62 2013 1077 1084
74. J.A. Reglero Ruiz, C. Saiz-Arroyo, M. Dumon, M.A. Rodríguez-Perez, and L. Gonzalez Production, cellular structure and thermal conductivity of microcellular (methyl methacrylate)-(butyl acrylate)-(methyl methacrylate) triblock copolymers Polym. Int. 60 2011 146 152
75. Y.-W. Chang, D. Lee, and S.-Y. Bae Preparation of polyethylene-octene elastomer/clay nanocomposite and microcellular foam processed in supercritical carbon dioxide Polym. Int. 55 2006 184 189
76. K. Lee, Y.-W. Chang, and S.W. Kim Ethylene-propylene-diene terpolymer/halloysite nanocomposites: thermal, mechanical properties, and foam processing J. Appl. Polym. Sci. 131 2014
77. J. Yang, L. Huang, Y. Zhang, F. Chen, and M. Zhong Mesoporous silica particles grafted with polystyrene brushes as a nucleation agent for polystyrene supercritical carbon dioxide foaming J. Appl. Polym. Sci. 130 2013 4308 4317
78. 2 philic perfluorinated block copolymer J. Appl. Polym. Sci. 126 2012 38 45
79. W. Zhai, S.N. Leung, L. Wang, H.E. Naguib, and C.B. Park Preparation of microcellular poly(ethylene-co-octene) rubber foam with supercritical carbon dioxide J. Appl. Polym. Sci. 2010
80. 2 process: effect of microstructure on compression behavior J. Appl. Polym. Sci. 118 2010 320 331
81. 2 J. Supercrit. Fluids 57 2011 87 94
82. 2: influence of the rheological properties and the process parameters on the cellular structure J. Supercrit. Fluids 58 2011 177 188
83. H. Zhang, Q. Yan, W. Zheng, Z. He, and Z. Yu Tough graphene-polymer microcellular foams for electromagnetic interference shielding Appl. Mater. Interfaces 3 2011 918 924
84. C. Okolieocha, F. Beckert, M. Herling, J. Breu, R. Mülhaupt, and V. Altstädt Preparation of microcellular low-density PMMA nanocomposite foams: influence of different fillers on the mechanical, rheological and cell morphological properties Compos. Sci. Technol. 118 2015 108 116
85. S.-K. Yeh, Y.-C. Liu, W.-Z. Wu, K.-C. Chang, W.-J. Guo, and S.-F. Wang Thermoplastic polyurethane/clay nanocomposite foam made by batch foaming J. Cell. Plast. 49 2013 119 130
86. S. Costeux, and L. Zhu Low density thermoplastic nanofoams nucleated by nanoparticles Polymer 54 2013 2785 2795
87. 2 Polymer 56 2015 46 56
88. H. Ruckdäschel, Micro- and Nanostructured Polymer Blends - Processing, Properties and Foaming Behaviour, 2008, pp. 242-270.
89. S. Costeux, and S.P. Bunker Homogenous nanocellular foams from styrenic-acrylic polymer blends J. Mater. Res. 28 2013 2351 2365
90. M.M. Khorasani, S.R. Ghaffarian, A. Babaie, and N. Mohammadi Foaming behavior and cellular structure of microcellular HDPE nanocomposites prepared by a high temperature process J. Cell. Plast. 46 2010 173 190
91. 2 J. Cell. Plast. 41 2005 487 502
92. N.J. Hossieny, M.R. Barzegari, M. Nofar, S.H. Mahmood, and C.B. Park Crystallization of hard segment domains with the presence of butane for microcellular thermoplastic polyurethane foams Polymer 55 2014 651 662
93. Y. Ito, M. Yamashita, and M. Okamoto Foam processing and cellular structure of polycarbonate-based nanocomposites Macromol. Mater. Eng. 291 2006 773 783
94. S. Costeux, I. Khan, S.P. Bunker, and H.K. Jeon Experimental study and modeling of nanofoams formation from single phase acrylic copolymers J. Cell. Plast. 51 2015 197 221
95. K. Satish, J. Eric, S.K. Goel, and E.J. Beckman Generation of microcellular polymeric foams using supercritical carbon dioxide. II: cell growth and skin formation Polym. Eng. Sci. 34 1994 1148 1156
96. D. Szegda, S. Duangphet, J. Song, and K. Tarverdi Extrusion foaming of PHBV J. Cell. Plast. 50 2014 145 162
97. W. Liu, X. Wang, H. Li, Z. Du, and C. Zhang Study on rheological and extrusion foaming behaviors of chain-extended poly(lactic acid)/clay nanocomposites J. Cell. Plast. 49 2013 535 554
98. W. Michaeli, K. Westermann, and S. Sitz Extrusion of physically foamed rubber profiles J. Cell. Plast. 47 2011 483 495
99. G.M. Rizvi, C.B. Park, and G. Guo Strategies for processing wood plastic composites with chemical blowing agents J. Cell. Plast. 44 2008 125 137
100. 2 and talc contents on foaming behavior of recyclable high-melt-strength PP J. Cell. Plast. 42 2006 405 428
101. E.H. Tejeda Morphology and mechanical properties of foamed polyethylene-polypropylene blends J. Cell. Plast. 41 2005 417 435
102. Z. Xu Effects of formulations and processing parameters on foam morphologies in the direct extrusion foaming of polypropylene using a single-screw extruder J. Cell. Plast. 41 2005 169 185
103. A.P. Ranade Structure-property relationships in coextruded foam/film microlayers J. Cell. Plast. 40 2004 497 507
104. 2-philic polymers: sustainable route to polymer foams in a continuous process Polymer 54 2013 4645 4652
105. J.-M. Julien, J.-C. Bénézet, E. Lafranche, J.-C. Quantin, A. Bergeret, M.-F. Lacrampe, and et al. Development of poly(lactic acid) cellular materials: physical and morphological characterizations Polymer 53 2012 5885 5895
106. C. Okolieocha, T. Koppl, S. Kerling, F.J. Tolle, A. Fathi, R. Mülhaupt, and V. Altstädt Influence of graphene on the cell morphology and mechanical properties of extruded polystyrene foam J. Cell. Plast. 51 2015 413 426
107. Å. Larsen, and C. Neldin Physical extruder foaming of poly(lactic acid)-processing and foam properties Polym. Eng. Sci. 53 2013 941 949
108. A.K. Chaudhary, and K. Jayaraman Extrusion of linear polypropylene-clay nanocomposite foams Polym. Eng. Sci. 51 2011 1749 1756
109. M. Mihai, M.A. Huneault, and B.D. Favis Rheology and extrusion foaming of chain-branched poly(lactic acid) Polym. Eng. Sci. 50 2010 629 642
110. S.-K. Yeh, J. Yang, N.-R. Chiou, T. Daniel, and L.J. Lee Introducing water as a coblowing agent in the carbon dioxide extrusion foaming process for polystyrene thermal insulation foams Polym. Eng. Sci. 50 2010 1577 1584
111. P. Spitael, and C.W. Macosko Strain hardening in polypropylenes and its role in extrusion foaming Polym. Eng. Sci. 44 2004 2090 2100
112. A. Ayoub, and S.S.H. Rizvi Reactive supercritical fluid extrusion for development of moisture resistant starch-based foams J. Appl. Polym. Sci. 120 2011 2242 2250
113. Y. Lee, and K. Wang Effects of clay dispersion on the foam morphology of LDPE/clay nanocomposites J. Appl. Polym. Sci. 103 2007 2129 2134
114. S. Costeux, and D. Foether Continuous extrusion of nanocellular foam SPE ANTEC Tech. Pap. 100 2015 1 6
115. 2 by foam extrusion process J. Cell. Plast. 45 2009 499 514
116. F.J. Gomez-Gomez, D. Arencon, M.a. Sanchez-Soto, and a.B. Martinez Influence of the injection moulding parameters on the microstructure and thermal properties of microcellular polyethylene terephthalate glycol foams J. Cell. Plast. 49 2012 47 63
117. M. Reza Barzegari, and D. Rodrigue Prediction of the shear modulus of polymer structural foams J. Cell. Plast. 45 2009 555 576
118. C. Tovar-Cisneros, R. Gonzalez-Nunez, and D. Rodrigue Effect of mold temperature on morphology and mechanical properties of injection molded HDPE structural foams J. Cell. Plast. 44 2008 223 237
119. G. Kotzev, S. Djoumaliisky, M. Krasteva, M. Iliev, E. Pérez, and M.L. Cerrada Effect of sample configuration on the morphology of foamed LDPE/PP blends injection molded by a gas counterpressure process Macromol. Mater. Eng. 292 2007 769 779
120. M.R. Barzegari, and D. Rodrigue The effect of injection molding conditions on the morphology of polymer structural foams Polym. Eng. Sci. 49 2009 949 959
121. G.H. Motlagh, a.N. Hrymak, and M.R. Thompson Improved through-plane electrical conductivity in a carbon-filled thermoplastic via foaming Polym. Eng. Sci. 48 2008 687 696
122. J. Li, Z. Chen, X. Wang, T. Liu, Y. Zhou, and S. Luo Cell morphology and mechanical properties of microcellular mucell V injection molded polyetherimide and polyetherimide/fillers composite foams J. Appl. Polym. Sci. 2013 4171 4181
123. J. Zhou, Z. Yao, C. Zhou, D. Wei, and S. Li Mechanical properties of PLA/PBS foamed composites reinforced by organophilic montmorillonite J. Appl. Polym. Sci. 131 2014 40773