Critical metals (REE, Sc, PGE) in Ni laterites from Cuba and the Dominican Republic

Ore Geology Reviews

Volumn 73, Issue , 2016, Pages 127-147

  Aiglsperger, Thomas ^a   Proenza, Joaquin A ^a   Lewis, John F ^b   Labrador, Manuel ^a   Svojtka, Martin ^c   Rojas Purón, Arturo ^d   Longo, Francisco ^e   Ďurišová, Jana ^c  

^a UNIVERSITY OF BARCELONA   (Spain)

^b GEORGE WASHINGTON UNIVERSITY   (United States)

^c INSTITUTE OF GEOLOGY   (Czech Republic)

^d Instituto Superior Minero Metalurgico   (Cuba)

^e A Glencore Company   (Australia)

Author keywords

Caribbean; Cuba; Dominican Republic; Falcondo mining area; Moa Bay mining area; Ni laterite; Platinum Group Elements; Rare Earth Elements; Scandium

Indexed keywords

BIRDS; DEPOSITS; ECONOMIC GEOLOGY; EXPLORATORY GEOCHEMISTRY; EXTRACTION; GEOCHEMISTRY; MANGANESE; NICKEL DEPOSITS; ORE DEPOSITS; ORE TREATMENT; PLATINUM; RARE EARTH ELEMENTS; RARE EARTHS; SCANDIUM; SILICATES; SOILS; WEATHERING;

CARIBBEAN; CUBA; DOMINICAN REPUBLIC; MINING AREAS; NI-LATERITES; PLATINUM GROUP ELEMENTS;

NICKEL;

GEOCHEMISTRY; LATERITE; MINE; MINERALOGY; PLATINUM GROUP ELEMENT; RARE EARTH ELEMENT; SCANDIUM;

CARIBBEAN ISLANDS; CUBA; DOMINICAN REPUBLIC;

EID: 84946426724     PISSN: 01691368     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.oregeorev.2015.10.010     Document Type: Article

References (91)

1. van Achterbergh E., Ryan C.G., Jackson S.E., Griffin W.L. Data Reduction Software for LA-ICP-MS. Laser-ablation-ICPMS in the Earth Sciences: Principles and Applications 2001, 239-243. Mineralogical Association of Canada, Short Course. P. Sylvester (Ed.).
2. Aiglsperger T., Proenza J.A., Zaccarini F., Lewis J.F., Garuti G., Labrador M., Longo F. Platinum group minerals (PGM) in the Falcondo Ni laterite deposit, Loma Caribe peridotite (Dominican Republic). Mineral. Deposita 2015, 50:105-123.
3. Anders E., Grevesse N. Abundances of the elements: meteoritic and solar. Geochim. Cosmochim. Acta 1989, 53:197-214.
4. Audet M.A. Le massif du Koniambo, Nouvelle-Calédonie Formation et obduction d'un complexe ophiolitique du type SSZ. Enrichissement en nickel, cobalt et scandium dans les profils résiduels 2008, (PhD thesis (in French), 327 pp.).
5. Augé T., Legendre O. Platinum-Group Element oxides from the Pirogues ophiolitic mineralization, New Caledonia: origin and significance. Econ. Geol. 1994, 89:1454-1468.
6. Babechuk M.G., Widdowson M., Kamber B.S. Quantifying chemical weathering intensity and trace element release from two contrasting basalt profiles, Deccan Traps, India. Chem. Geol. 2014, 363:56-75.
7. Beaton D.W., Kryski K.M., Srivastava R.M. 43-101 Technical report on the central Moa nickel laterite operation in Eastern Cuba: Prepared for Sherritt International Corporation 2011, Available at: http://www.sedar.com/GetFile.do?lang=EN&docClass=24&issuerNo=00002460&fileName=/csfsprod/data123/filings/01811517/00000001/z%3A%5Crarcher%5C12941-2081%5CTechRpts%5CMoa.PDF. Accessed 25.03.2015.
8. Bowin C.O. Geology of the central Dominican Republic (a case history of part of an island arc). Mem. Geol. Soc. Am. 1966, 98:11-84. H. Hess (Ed.).
9. Brand N.W., Butt C.R.M., Elias M. Nickel laterites: classification and features. AGSO J. Aust. Geol. Geophys. 1998, 17:81-88.
10. Braun J., Pagel M., Muller J., Bilong P., Michard A., Guillet B. Cerium anomalies in lateritic profiles. Geochim. Cosmochim. Acta 1990, 54:781-795.
11. Butt C.R.M., Cluzel D. Nickel laterite ore deposits: weathered serpentinites. Elements 2013, 9:123-128.
12. Chakhmouradian A.R., Wall F. Rare earth elements: rare earth elements: minerals, mines, magnets (and more). Elements 2012, 8:333-340.
13. Chan T.K., Finch I.J. Determination of platinum-group elements and gold by inductively coupled plasma mass spectrometry. Australian Platinum Conference, Perth, Western Australia 2001, 1-9.
14. Chorover J., Kretzschmar R., Garcia-Pichel F., Sparks D.L. Soil biogeochemical processes within the critical zone. Elements 2007, 3:321-326.
15. Chu H., Chi G., Bosman S., Card C. Diagenetic and geochemical studies of sandstones from drill core DV10-001 in the Athabasca basin, Canada, and implications for uranium mineralization. J. Geochem. Explor. 2015, 148:206-230.
16. Dalvi A.D., Bacon W.G., Osborne R.C. The past and future of nickel laterites. PDAC 2004, International Convention, Prospectors and Developers Association of Canada, March 7-10, Toronto, Ontario, Canada 2004, 1-27.
17. Degen T., Sadki M., Bron E., König U., Nénert G. The HighScore suite. Powder Diffr. 2014, 29:S13-S18.
18. Draper G., Gutiérrez G., Lewis J.F. Thrust emplacement of the Hispaniola peridotite belt: orogenic expression of the mid Cretaceous Caribbean arc polarity reversal?. Geology 1996, 24:1143-1146.
19. Duzgoren-Aydin N.S., Aydin A., Malpas J. Distribution of clay minerals along a weathered pyroclastic profile, Hong Kong. Catena 2002, 50:17-41.
20. EC (European Commission) Report on critical raw materials for the EU. Report of the Ad-hoc Working Group in Defining Critical Raw Materials: Brussels, Belgium 2014, (Available at http://ec.europa.eu/enterprise/policies/raw-materials/files/docs/crm-report-on-critical-raw-materials_en.pdf. Accessed 25 March 2015).
21. Economou-Eliopoulos M., Eliopoulos D.G., Apostolikas A., Maglaras K. Precious and rare earth element distribution in Ni-laterite deposits Lokris area, Central Greece. Proceedings of the 4th Biennial SGA Meeting 1997, 411-413. (Balkema, Rotterdam, Turku, Finland). H. Papunen (Ed.).
22. Eliopoulos D.G., Economou-Eliopoulos M. Geochemical and mineralogical characteristics of Fe-Ni- and bauxitic-laterite deposits of Greece. Ore Geol. Rev. 2000, 16:41-58.
23. Eliopoulos D., Economou G., Tzifas I., Papatrechas C. The potential of rare earth elements in Greece. ERES 2014, 1st European Rare Earth Resources Conference, September 4-7, Milos, Greece 2014, 308-316.
24. Escuder Viruete J., Díaz de Neira A., Hernaiz Huerta P.P., Monthel J., García Senz J., Joubert M., Lopera E., Ullrich T., Friedman R., Mortensen J., Pérez-Estaún A. Magmatic relationships and ages of Caribbean Island arc tholeiites, boninites and related felsic rocks, Dominican Republic. Lithos 2006, 90:161-186.
25. Escuder Viruete J., Pérez-Estaún A., Contreras F., Joubert M., Weis D., Ullrich T.D., Spadea P. Plume mantle source heterogeneity through time: insights from the Duarte Complex, Hispaniola, northeastern Caribbean. J. Geophys. Res. 2007, 112:B04203.
26. Freyssinet P., Butt C.R.M., Morris R.C. Ore-forming processes related to lateritic weathering. Econ. Geol. 100th Anniversary Volume 2005, 681-722.
27. Frost B.R., Evans K.A., Swapp S.M., Beard J.S., Mothersole F.E. The process of serpentinization in dunite from New Caledonia. Lithos 2013, 178:24-39.
28. Galí S., Proenza J.A., Labrador M., Tauler E., Melgarejo J.C. Numerical modelling of oxide-type Ni laterite deposits: preliminary results. Digging Deeper, 2 2007, 1385-1388. Irish Association of Economic Geology. C.J. Andrew (Ed.).
29. Gleeson S.A., Butt C.R., Elias M. Nickel laterites: a review. SEG Newsl. 2003, 54:11-18.
30. Golightly J.P. Nickeliferous laterite deposits. Econ. Geol. 75th Anniversary Vol. 1981, 710-735.
31. Golightly J.P. Progress in understanding the evolution of nickel laterites. Soc. Econ. Geol. Spec. Publ. 2010, 15:451-485.
32. Golightly J.P., Plamondon M., Srivastava R.M. 43-101F1 technical report on the Moa Occidental and Moa Oriental nickel laterite properties in Cuba: Prepared for Sherritt International Corporation accessed March 25, 2015, at, (102 pp.). http://www.sedar.com/GetFile.do?lang=EN&docClass=24&issuerNo=00002460&fileName=/csfsprod/data88/filings/01240793/00000001/f%3A%5Crarcher%5C12941-0001%5C2007AIF%5C43-101report.pdf.
33. Grant J.A. The isocon diagram-a simple solution to Gresens' equation for metasomatic alteration. Econ. Geol. 1986, 81:1976-1982.
34. Grant J.A. Isocon analysis: a brief review of the method and applications. Phys. Chem. Earth 2005, 30:997-1004.
35. Gray J.D., Schorin K.H., Butt C.R.M. Mineral associations of platinum and palladium in lateritic regolith, Ora Banda Sill, Western Australia. J. Geochem. Explor. 1996, 57:245-255.
36. Gresens R.L. Composition-volume relationships of metasomatism. Chem. Geol. 1967, 2:47-55.
37. Haldemann E.G., Buchan R., Blowes J.H., Chandler T. Geology of lateritic nickel deposits, Dominican Republic. International Laterite Symposium 1979, 57-84. Amer. Inst. Mining, Metal., and Petroleum Engineers, New York. D.J.I. Evans, R.S. Shoemaker, H. Veltman (Eds.).
38. Hein J.R., Mizell K., Koschinsky A., Conrad T.A. Deep-ocean mineral deposits as a source of critical metals for high- and green-technology applications: comparison with land-based resources. Ore Geol. Rev. 2013, 51:1-14.
39. Iturralde-Vinent M.A., Díaz Otero C., Rodríguez Vega A., Díaz Martínez R. Tectonic implications of paleontologic dating of Cretaceous-Danian sections of Eastern Cuba. Geol. Acta 2006, 4:89-102.
40. Janots E., Bernier F., Brunet F., Muñoz M., Trcera N., Berger A., Lanson M. Ce(III) and Ce(IV) (re)distribution and fractionation in a laterite profile from Madagascar: insights from in situ XANES spectroscopy at the Ce LIII-edge. Geochim. Cosmochim. Acta 2015, 153:134-148.
41. Jochum K.P., Weis U., Stoll B., Kuzmin D., Yang Q., Raczek I., Jacob D.E., Stracke A., Birbaum K., Frick D.A., Günther D., Enzweiler J. Determination of reference values for NIST SRM 610-617 glasses following ISO guidelines. Geostand. Geoanal. Res. 2011, 35:397-429.
42. Johnson D.B., du Plessis C.A. Biomining in reverse gear: using bacteria to extract metals from oxidised ores. Miner. Eng. 2015, 75:2-5.
43. Kooijman E., Berndt J., Mezger K. U-Pb dating of zircon by laser ablation ICP-MS: recent improvements and new insights. Eur. J. Mineral. 2012, 24:5-21.
44. Alatha S., Economou-Eliopoulos M. Framboidal pyrite and bacterio-morphic goethite at transitional zones between Fe-Ni laterites and limestones: evidence from Lokris, Greece. Ore Geol. Rev. 2015, 65:413-425.
45. Labrador M., Proenza J.A., Galí S., Melgarejo J.C., Tauler E., Rojas-Purón A.L., Muñoz-Gómez N., Blanco-Moreno J.A. Supergene Co-Ni-Mn mineralization in Ni-laterite deposits from northeast Cuba. Digging Deeper, 2. Irish Assoc. Econ. Geol. 2007, 1397-1400. C.J. Andrew (Ed.).
46. Laskou M., Economou-Eliopoulos M. The role of microorganisms on the mineralogical and geochemical characteristics of the Parnassos-Ghiona bauxite deposits, Greece. J. Geochem. Explor. 2007, 93:67-77.
47. Lavaut W. Tendencias geológicas del intemperismo de las rocas ultramáficas en Cuba oriental. Rev. Minera Geol. 1998, 15:9-16.
48. Lazarenkov V.G., Tikhomirov B., Zhidkov Y., Talovina V. Platinum group metals and gold in supergene nickel ores of the Moa and Nikaro deposits (Cuba). Lithol. Miner. Resour. 2005, 40:521-527.
49. Lázaro C., Blanco-Quintero I.F., Rojas-Agramonte Y., Proenza J.A., Núñez-Cambra K., García-Casco A. First description of a metamorphic sole related to ophiolite obduction in the northern Caribbean: geochemistry and petrology of the Güira de Jauco Amphibolite complex (eastern Cuba) and tectonic implications. Lithos 2013, 179:193-210.
50. Lewis J.F., Jiménez J.G. Duarte complex in the La Vega-Jarabacoa-Janico Area, Central Hispaniola: geological and geochemical features of the sea floor during the early stages of arc evolution. Geol. Soc. Am. Spec. Paper 1991, 262:115-142. P. Mann, G. Draper, J.F. Lewis (Eds.).
51. Lewis J.F., Draper G., Proenza J.A., Espaillat J., Jiménez J. Ophiolite-related ultramafic rocks (serpentinites) in the Caribbean region: a review of their occurrence, composition, origin, emplacement and nickel laterite soils. Geol. Acta 2006, 4:237-263.
52. Lewis J.F., Escuder-Viruete J., Hernaiz-Huerta P.P., Gutiérrez G., Draper G., Pérez-Estaún A. Subdivisión geoquímica del arco de Isla Circum-Caribeño, Cordillera Central Dominicana: Implicaciones para la formación, acreción y crecimiento cortical en un ambiente intraoceánico. Acta Geol. Hisp. 2002, 37:81-122.
53. Lewis J.F., Proenza J.A., Jolly W.T., Lidiak E.G. Monte del Estado (Puerto Rico) and Loma Caribe (Dominican Republic) peridotites: a look at two different Mesozoic mantle sections within northern Caribbean region. 8 2006, A-08798.
54. Liivamägi S., Somelar P., Mahaney W.C., Kirs J., Vircava I., Kirsimäe K. Late Neoproterozoic Baltic paleosol: intense weathering at high latitude?. Geology 2014, 42:323-326.
55. Linchenat A., Shirakova I. Individual characteristics of nickeliferous iron (laterite) deposits of the northeast part of Cuba (Pinares de Mayari, Nicaro and Moa). 24th International Geological Congress, Montreal, Part 14, Section 14 1964, 172-187.
56. Lithgow E.W. Nickel laterites of central Dominican Republic Part I. Mineralogy and ore dressing. Fundamental Aspects 1993, vol. I:403-425. The Minerals, Metals and Materials Society, Portland. R.G. Reddy, R.N. Weizenbach (Eds.).
57. Little B.J., Wagner P.A., Lewandowski Z. Spatial relationships between bacteria and mineral surfaces. Reviews in Mineralogy 1997, 35:123-159. J.F. Banfield, K.H. Nealson (Eds.).
58. Maier W.D., Barnes S.-J., Bandyayera D., Livesey T., Li C., Ripley E. Early Kibaran rift-related mafic-ultramafic magmatism in western Tanzania and Burundi: petrogenesis and ore potential of the Kapalagulu and Musongati layered intrusions. Lithos 2008, 101:24-53.
59. Maksimović Z.J., Pantó G. Authigenic rare earth minerals in karst-bauxites and karstic nickel deposits. Mineralogical Society Series 1996, 7:257-279. Chapman and Hall, London. A.P. Jones, F. Wall, C.T. Williams (Eds.).
60. Marchesi C., Garrido C.J., Godard M., Proenza J.A., Gervilla F., Blanco-Moreno J. Petrogenesis of highly depleted peridotites and gabbroic rocks from the MayariD-Baracoa Ophiolitic Belt (eastern Cuba). Contrib. Mineral. Petrol. 2006, 151:717-736.
61. Marchesi C., Garrido C.J., Proenza J.A., Konc Z., Hidas K., Lewis J.F., Lidiak E. Mineral and whole rock compositions of peridotites from Loma Caribe (Dominican Republic): insights into the evolution of the oceanic mantle in the Caribbean region. Geophys. Res. Abstr. 2012, 14:EGU2012-EGU12161.
62. Marsh E.E., Anderson E.D. Ni-Co laterite deposits. U.S. Geol. Surv. Open File Rep. 2011, 2011:1259-1268.
63. Medaris L.G., Singer B.S., Dott R.H., Naymark A., Johnson C.M., Schott R.C. Late Paleoproterozoic climate and tectonics in southern Lake Superior region and Proto-North America: evidence from Baraboo interval quartzites. J. Geol. 2003, 111:243-257.
64. Meyer F.M., Happel U., Hausberg J., Wiechowski A. The geometry and anatomy of the Los Pijiguaos bauxite deposit, Venezuela. Ore Geol. Rev. 2002, 20:27-54.
65. Mongelli G. Ce-anomalies in the textural components of Upper Cretaceous karst bauxites from the Apulian carbonate platform (southern Italy). Chem. Geol. 1997, 140:69-79.
66. Naldrett A.J., Duke J.M. Platinum metals in magmatic sulfide ores. Science 1980, 208:1417-1428.
67. Ndjigui P.D., Bilong P. Platinum-group elements in the serpentinite lateritic mantles of the Kongo-Nkamouna ultramafic massif (Lomié region, South-East Cameroon). J. Geochem. Explor. 2010, 107:63-76.
68. Nelson C.E., Proenza J.A., Lewis J.F., López-Kramer J. The metallogenic evolution of the Greater Antilles. Geol. Acta 2011, 9:229-264.
69. Platina Resources Excellent Testwork Results from Owendale Scoping Study Available at:, (Accessed 25 March 2015). http://www.platinaresources.com.au/files/announcements/2015_01_20_-_PGM_ASX_-_Owendale_Scoping_Study.pdf.
70. Pol A., Barends T.R.M., Bietl A., Khadem A.F., Eygensteyn J., Jetten M.S.M., Op den Camp H.J.M. Rare earth metals are essential for methanotrophic life in volcanic mudpots. Environ. Microbiol. 2014, 16:255-264.
71. Proenza J.A., Gervilla F., Melgarejo J.C. La Moho Transition Zone en el Macizo Ofiolítico Moa-Baracoa: un ejemplo de interacción magma/peridotite. Rev. Soc. Geol. Esp. 1999, 12:309-327.
72. Proenza J.A., Gervilla F., Melgarejo J.C., Bodinier J.L. Al- and Cr-rich chromitites from the Mayarí-Baracoa Ophiolitic Belt (Eastern Cuba): consequence of interaction between volatile-rich melts and peridotite in suprasubduction mantle. Econ. Geol. 1999, 94:547-566.
73. th general meeting of the IMA, 21-27 August 2010, Budapest Hungary 2010.
74. Proenza J.A., Tauler E., Melgarejo J.C., Gali S., Labrador M., Marrero N., Perez-Nelo N., Rojas-Puron A.L., Blanco-Moreno J.A. Mineralogy of oxide and hydrous silicate Ni laterite profiles in Moa Bay area, northeast Cuba. Digging Deeper, 2 2007, 1389-1392. Irish Association of Economic Geology. C.J. Andrew (Ed.).
75. Proenza J.A., Zaccarini F., Lewis J., Longo F., Garuti G. Chromian spinel composition and platinum-group mineral assemblage of PGE-rich Loma Peguera chromitites, Loma Caribe peridotite, Dominican Republic. Can. Mineral. 2007, 45:211-228.
76. Proenza J.A., Díaz-Marínez R., Iriondo A., Marchesi C., Melgarejo J.C., Gervilla F., Garrido C.J., Rodríguez-Vega A., Lozano-Santacruz R., Blanco-Moreno J.A. Primitive Cretaceous island-arc volcanic rocks in eastern Cuba: the Téneme Formation. Geol. Acta 2006, 4:103-121.
77. Redwood S. Gold surge mining is booming in the Dominican Republic as investors follow the gold rush. Min. J. 2014, 24:23-27.
78. Roqué-Rosell J., Mosselmans J.F.W., Proenza J.A., Labrador M., Galí S., Atkinson K.D., Quinn P.D. Sorption of Ni by "lithiophorite-asbolane" intermediates in Moa Bay lateritic deposits, Eastern Cuba. Chem. Geol. 2010, 275:9-18.
79. Rudashevsky, N.S., Rudashevsky, V.N., 2006. Patent of Russian Federation #2281808, Invention "Hydraulic Classifier", Moscow, 20 August 2006.
80. Rudashevsky, N.S., Rudashevsky, V.N., 2007. Patent of Russian Federation #69418, Industrial (Useful) Model, "Device for Separation of Solid Particles", Moscow, December 27, 2007.
81. Rudashevsky, N.S., Lupal, S.D., Rudashevsky, V.N., 2001. The Hydraulic Classifier. Russia Patent N 2165300, Patent Cooperation Treaty PCT/RU01/00123 (Moscow: 20 April 2001; 10 May 2001) (in Russian and English).
82. Sherritt Sherrit International Corporation. 2012 Annual Report Available at:, (Accessed 25.03.2015). http://www.sherritt.com/getattachment/7a7b0634-0dd4-46c4-bcda-19d73042fa9c/2012-Annual-Report.
83. Simandl G.J. Geology and market-dependent significance of rare earth element resources. Mineral. Deposita 2014, 49:889-904.
84. Terekhov D.S., Nanthakumar V.E. Direct extraction of nickel and iron from laterite ores using carbonyl process. Miner. Eng. 2013, 54:124-130.
85. Trincal V., Charpentier D., Buatier M.D., Grobety B., Lacroix B., Labaume P., Sizun J.P. Quantification of mass transfers and mineralogical transformations in a thrust fault (Monte Perdido thrust unit, southern Pyrenees, Spain). Mar. Pet. Geol. 2014, 55:160-175.
86. Tsikouras B., Karipi S., Rigopoulos I., Perraki M., Pomonis P., Hatzipanagiotou K. Geochemical processes and petrogenetic evolution of rodingite dikes in the ophiolite complex of Othrys (Central Greece). Lithos 2009, 113:540-554.
87. USGS Mineral commodity summaries 2013 Available at:, (Accessed 25.03.2015). http://minerals.usgs.gov/minerals/pubs/mcs/2013/mcs2013.pdf.
88. Villanova-de-Benavent C., Proenza J.A., Galí S., García-Casco A., Tauler E., Lewis J.F., Longo F. Garnierites and garnierites: textures, mineralogy and geochemistry of garnierites in the Falcondo Ni laterite deposit, Dominican Republic. Ore Geol. Rev. 2014, 58:91-109.
89. Vodyanitskii Y.N. Iron hydroxides in soils: a review of publications. Eurasian Soil Sci. 2010, 43:1244-1254.
90. Wang W., Pranolo Y., Cheng C.Y. Metallurgical processes for scandium recovery from various resources: a review. Hydrometallurgy 2011, 108:100-108.
91. Wilde A., Edwards A., Yakubchuk A. Unconventional deposits of Pt and Pd: a review with implications for exploration. SEG Newsletter 52, 1 and 10-18 2003.