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I have discussed elsewhere how the increased attention to mechanism, beginning around the 1950s, was a key factor in raising the status of inorganic chemistry as a subdiscipline, eventually reaching parity with organic and physical chemistry: Labinger, J. A. Up from Generality: How Inorganic Chemistry Finally Became a Respectable Field; Springer: Heidelberg, Germany, 2013.
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A second edition, with the same title but with two additional co-authors (Jack Norton and Richard Finke), appeared in 1987. More recently, a substantially reworked and expanded version was published: Hartwig, J. J. Organotransition Metal Chemistry: From Bonding to Catalysis; University Science Books: Sausalito, CA, 2010.
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3 in a high-boiling oxygenated solvent, such as ethylene glycol or dimethyl formamide, at temperatures close to 200 °C for a number of hours; the solvent serves as both reductant and source of carbonyl. According to one commentator, the first synthesis succeeded only because Vaska forgot and left it heating overnight: Kirss, R. U. Bull. Hist. Chem. 2013, 38, 52-60
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2 complex suggested the strong possibility of an erroneous measurement resulting from radiation-induced crystal damage: Nolte, M. J.; Singleton, E.; Laing, M. J. Am. Chem. Soc. 1975, 97, 6396-6400 10.1021/ja00855a018
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2 was finally redetermined in 2008, giving the currently accepted O-O bond length shown in Table 2: Lebel, H.; Ladjel, C.; Bélanger-Gariépy, F.; Schaper, F. J. Organomet. Chem. 2008, 693, 2645-2648 10.1016/j.jorganchem.2008.05.025
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