Synergistic electrocatalysis of N,Nʹ-bis(salicylidene)-ethylenediamine-cobalt(II) and conductive carbon black (BP) for high efficient CO2 electroreduction

Journal of Solid State Electrochemistry

Volumn 19, Issue 11, 2015, Pages 3355-3363

  Fu, Yishu ^a   Liu, Yuyu ^b   Li, Yanan ^a   Li, Jing ^a   Qiao, Jinli ^a   Zhang, Jiujun ^a,c  

^a DONGHUA UNIVERSITY   (China)

^b TOHOKU UNIVERSITY   (Japan)

^c NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

Catalytic activity; Electrochemical reduction of CO2; Formic acid; Gas diffusion electrode; Onset potential

Indexed keywords

CARBON BLACK; CATALYST ACTIVITY; COBALT; DIFFUSION IN GASES; ELECTROCATALYSIS; ELECTRODES; ELECTROLYTIC REDUCTION; FORMIC ACID; IONIZATION OF GASES; REDUCTION;

CONDUCTIVE CARBON BLACKS; ELECTRICAL CONDUCTIVITY; ELECTROCHEMICAL REDUCTIONS; FARADAIC EFFICIENCIES; GAS DIFFUSION ELECTRODES; MAXIMUM CURRENT DENSITY; ONSET POTENTIAL; REDUCTION PRODUCTS;

ELECTROCHEMICAL ELECTRODES;

EID: 84945479534     PISSN: 14328488     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10008-015-2955-z     Document Type: Article

References (24)

1. 2 gas at Sn based gas diffusion electrode. Curr Appl Phys 11:986–988
2. 2 by Cu2O-catalyzed carbon clothes. Mater Lett 63:1001–1003
3. Sanchez-Sanchez CM, Montiel V, Tryk DA, Aldaz A, Fujishima A (2001) Electrochemical approaches to alleviation of the problem of carbon dioxide accumulation. Pure Appl Chem 73:1917–1927
4. Qiao JL, Liu YY, Hong F, Zhang JJ (2014) A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels. Chem Soc Rev 43:631–675
5. 2O reduction at room temperature. J Electrochem Soc 155:B42–B49
6. Lee KR, Lim JH, Lee JK, Chun HS (1999) Reduction of carbon dioxide in 3-dimensional gas diffusion electrodes. Korean J Chem Eng 16:829–836
7. 2 and small organic molecules. Chem Asian J 4(10):1516–1523
8. 2 reduction and mechanism of synergistic electrocatalysis J Solid State Electr 17:1657–1664
9. Zhou XJ, Xu P, Xu L, Bai ZY, Chen WZ, Qiao JL, Zhang JJ (2014) N,N'-Bis(salicylidene)ethylenediamine as a nitrogen-rich precursor to synthesize electrocatalysts with high methanol-tolerance for polymer electrolyte membrane fuel cell oxygen reduction reaction. J Power Sources 260:349–356
10. Hayashi T (1999) Catalytic asymmetric reactions via pi-allylpalladium complexes coordinated with chiral monophosphine ligands. J Organomet Chem 576:195–202
11. Fisher BJ, Eisenberg R (1980) Electrocatalytic reduction of carbon-dioxide by using macrocycles of nickel and cobalt. J Am Chem Soc 102(24):7361–7363
12. Christensen PA, Hamnett A, Muir AVG (1988) An insitu ftir study of the electroreduction of Co2 by copc-coated edge graphite-electrodes. J Electroanal Chem 241(1):361–371
13. Losada J, Del Peso I, Beyer L, Hartung J, Fernandez V, Möbius M (1995) Electrocatalytic reduction of O-2 and Co2 with electropolymerized films of polypyrrole cobalt(Ii) Schiff-base complexes. J Electroanal Chem 398(1):89–93
14. Tang L, Zhan L, Yang GZ, Yang JH, Wang YL, Qiao WM, Ling LC (2011) Preparation of mesoporous carbon microsphere/activated carbon composite for electric double-layer capacitors. New Carbon Mater 26(3):237–240
15. Li GC, Hu JJ, Li GR, Ye SH, Gao XP (2013) Sulfur/activated-conductive carbon black composites as cathode materials for lithium/sulfur battery. J Power Sources 240:598–605
16. Xu P, Chen WZ, Wang Q, Zhu TS, Wu MJ, Qiao JL, Chen ZW, Zhang JJ (2015) Effects of transition metal precursors (Co, Fe, Cu, Mn, or Ni) on pyrolyzed carbon supported metal-aminopyrine electrocatalysts for oxygen reduction reaction. RSC Adv 5:6195–6206
17. Antony R, Manickam STD, Saravanan K, Karuppasamy K, Balakumar S (2013) Synthesis, spectroscopic and catalytic studies of Cu(II), Co(II) and Ni(II) complexes immobilized on Schiff base modified chitosan. J Mol Struct 1050:53–60
18. Kianfar AH, Mahmood WAK, Dinari M, Farrokhpour H, Enteshari M, Azarian MH (2015) Immobilization of cobalt(III) Schiff base complexes onto Montmorillonite-K10: synthesis, experimental and theoretical structural determination. Spectrochimi Acta A 136:1582–1592
19. Choi A, Jeong H, Kim S, Jo S, Jeon S (2008) Electrocatalytic reduction of dioxygen by cobalt porphyrin-modified glassy carbon electrode with single-walled carbon nanotubes and nafion in aqueous solutions. Electrochim Acta 53:2579–2584
20. Lv WX, Zhang R, Gao PR, Lei LX (2014) Studies on the faradaic efficiency for electrochemical reduction of carbon dioxide to formate on tin electrode. J Power Sources 253:276–281
21. Zhao HZ, Zhang Y, Zhao B, Chang YY, Li ZS (2012) Electrochemical reduction of carbon dioxide in an MFC-MEC system with a layer-by-layer self-assembly carbon nanotube/cobalt phthalocyanine modified electrode. Environ Sci Technol 46:5198–5204
22. Kumar B, Asadi M, Pisasale D, Ray SS, Rosen BA, Haasch R, Abiade J, Yarin AL, Khojin AS (2013) Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction. Nat Commun 4:94–105
23. Kapusta S, Hackerman N (1984) Carbon-dioxide reduction at a metal phthalocyanine catalyzed carbon electrode. J Electrochem Soc 131:1511–1514
24. Jia F, Yu X, Zhang L (2014) Enhanced selectivity for the electrochemical reduction of CO2 to alcohols in aqueous solution with nanostructured Cu-Au alloy as catalyst. J Power Sources 252:85–89