Homogeneous catalytic oxidation of secondary alcohols to ketones by molecular oxygen under mild conditions

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 5, 1977, Pages 157-158

  Blackburn, Thomas F ^a   Schwartz, Jeffrey ^a  

^a PRINCETON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84943500387     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39770000157     Document Type: Article

References (12)

1. K. B. Sharpless and R. C. Michaelson: J. Amer. Chem. Soc, 1973, 95, 6136, and refs. cited therein.
2. K. B. Sharpless, K. Akashi, and K. Oshima: Tetrahedron Letters, 1976, 2503.
3. W. G. Lloyd: J. Org. Chem., 1967, 32, 2816.
4. This reaction is known for several group VIII metals including Pd11: J. V. Kingston and G. R. Scollary, Chem. Comm., 1969, 455
5. L. Vaska and J. W. DiLuzio: J. Amer. Chem. Soc, 1962, 84, 4989.
6. For example, see H. L. Roberts and W. R. Symes: J. Chem. Soc. (A), 1968, 1450.
7. A. Dobson and S. D. Robinson: J. Organometallic Chem., 1975, 87, C52
8. A. Dobson and S. D. Robinson: Inorg. Chem., 1977, 16, 137.
9. J.-C. Richer and C. Gilardear: Canad. J. Chem., 1965, 43, 538
10. J.-C. Richer and N. T. T. Hoa: Canad. J. Chem., 1969, 47, 2479.
11. H. G. Kuivila and W. J. Becker: J. Amer. Chem. Soc, 1952, 74, 5329.
12. A rate-determining step involving intramolecular transfer of hydride to an oxygen atom in chromate oxidation of alcohols has been proposed: H. Kwart and P. S. Francis, J. Amer. Chem. Soc, 1959, 81, 2116 and refs. cited therein.