A single Au nanoparticle anchored inside the porous shell of periodic mesoporous organosilica hollow spheres

Nano Research

Volumn 8, Issue 10, 2015, Pages 3404-3411

  Yang, Ying ^a   Zhang, Wen ^a   Zhang, Ying ^a   Zheng, Anmin ^b   Sun, Hui ^a   Li, Xinsong ^a   Liu, Suyan ^a   Zhang, Pengfang ^a   Zhang, Xin ^a  

^a CHINA UNIVERSITY OF PETROLEUM   (China)

^b Wuhan National Laboratory for Optoelectronics   (China)

Author keywords

4 nitropheol reduction; core shell interaction; gold nanoparticles; periodic mesoporous organosilica; yolk shell nanostructure

Indexed keywords

EID: 84943357031     PISSN: 19980124     EISSN: 19980000     Source Type: Journal    
DOI: 10.1007/s12274-015-0840-9     Document Type: Article

References (24)

1. Li, G. D.; Tang, Z. Y. Noble metal nanoparticle@metal oxide core/yolk-shell nanostructures as catalysts: Recent progress and perspective. Nanoscale2014, 6, 3995–4011.
2. Pérez-Lorenzo, M.; Vaz, B.; Salgueiriño, V.; Correa-Duarte, M. A. Hollow-shelled nanoreactors endowed with high catalytic activity. Chem. Eur. J.2013, 19, 12196–12211.
3. Liu, J.; Qiao, S. Z.; Chen, J. S.; Lou, X. W.; Xing, X. R.; Lu, G. Q. Yolk/shell nanoparticles: new platforms for nanoreactors, drug delivery and lithium-ion batteries. Chem. Commun.2011, 47, 12578–12591.
4. Park, J. C.; Song, H. Metal@silica yolk-shell nanostructures as versatile bifunctional nanocatalysts. Nano Res.2011, 4, 33–49.
5. Lou, X. W.; Archer, L. A.; Yang, Z. C. Hollow micro-/nanostructures: Synthesis and applications. Adv. Mater.2008, 20, 3987–4019.
6. Ko, Y. N.; Kang, Y. C.; Park, S. B. Continuous one-pot synthesis of sandwich structured core-shell particles and transformation to yolk-shell particles. Chem. Commun.2013, 49, 3884–3886.
7. Arnal, P. M.; Comotti, M.; Schth, F. High-temperaturestable catalysts by hollow sphere encapsulation. Angew. Chem. Int. Ed.2006, 45, 8224–8227.
8. Liu, R.; Mahurin, S. M.; Li, C.; Unocic, R. R.; Idrobo, J. C.; Gao, H. J.; Pennycook, S. J.; Dai, S. Dopamine as a carbon source: The controlled synthesis of hollow carbon spheres and yolk-structured carbon nanocomposites. Angew. Chem. Int. Ed. 2011, 50, 6799–6802.
9. Yang, T. Y.; Liu, J.; Zheng, Y.; Monteiro, M. J.; Qiao, S. Z. Facile fabrication of core-shell-structured Ag@carbon and mesoporous yolk-shell-structured Ag@carbon@silica by an extended Stöber method. Chem. Eur. J.2013, 19, 6942–6945.
10. Dong, K.; Liu, Z.; Ren, J. S. A general and eco-friendly self-etching route to prepare highly active and stable Au@metal silicate yolk-shell nanoreactors for catalytic reduction of 4-Nitrophenol. CrystEngComm2013, 15, 6329–6334.
11. Han, J.; Wang, M. G.; Chen, R.; Han, N.; Guo, R. Beyond yolk-shell nanostructure: A single Au nanoparticle encapsulated in the porous shell of polymer hollow spheres with remarkably improved catalytic efficiency and recyclability. Chem. Commun. 2014, 50, 8295–8298.
12. Li, B. X.; Gu, T.; Ming, T.; Wang, J. X.; Wang, P.; Wang, J. F.; Yu, J. C. (Gold core)@(ceria shell) nanostructures for plasmon-enhanced catalytic reactions under visible light. ACS Nano2014, 8, 8152–8162.
13. Liu, J.; Yang, H. Q.; Kleitz, F.; Chen, Z. G.; Yang, T. Y.; Strounina, E.; Lu, G. Q.; Qiao, S. Z. Yolk-shell hybrid materials with a periodic mesoporous organosilica shell: Ideal nanoreactors for selective alcohol oxidation. Adv. Funct. Mater.2012, 22, 591–599.
14. Gallo, J. M. R.; Pastore, H. O.; Schuchardt, U. Silylation of [Nb]-MCM-41 as an efficient tool to improve epoxidation activity and selectivity. J. Catal.2006, 243, 57–63.
15. Wahab, M. A.; Kim, II.; Ha, C.-S. Hybrid periodic mesoporous organosilica materials prepared from 1,2-Bis(triethoxysilyl)ethane and (3-Cyanopropyl)triethoxysilane. Micropor. Mesopor. Mater.2004, 69, 19–27.
16. Jin, Y.; Wang, P. J.; Yin, D. H.; Liu, J. F.; Qiu, H. Y.; Yu, N. Y. Gold nanoparticles stabilized in a novel periodic mesoporous organosilica of SBA-15 for styrene epoxidation. Micropor. Mesopor. Mater.2008, 111, 569–576.
17. Zhuang, T. Y.; Shi, J. Y.; Ma, B. C.; Wang, W. Chiral norbornane-bridged periodic mesoporous organosilicas. J. Mater. Chem.2010, 20, 6026–6029.
18. Corma, A. From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem. Rev.1997, 97, 2373–2419.
19. Robles-Dutenhefner, P. A.; Rocha, K. A. D.; Sousa, E. M. B.; Gusevskaya, E. V. Cobalt-catalyzed oxidation of terpenes: Co-MCM-41 as an efficient shape-selective heterogeneous catalyst for aerobic oxidation of isolongifolene under solventfree conditions. J. Catal.2009, 265, 72–79.
20. 2 catalysts. Angew. Chem. Int. Ed.2011, 50, 10208–10211.
21. Liu, R.; Qu, F. L.; Guo, Y. L.; Yao, N.; Priestley, R. D. Au@carbon yolk-shell nanostructures via one-step coreshell-shell template. Chem. Commun.2014, 50, 478–480.
22. Han, J.; Chen, R.; Wang, M. G.; Lu, S.; Guo, R. Core-shell to yolk-shell nanostructure transformation by a novel sacrificial template-free strategy. Chem. Commun.2013, 49, 11566–11568.
23. Wang, S. N.; Zhang, M. C.; Zhang, W. Q. Yolk-shell catalyst of single Au nanoparticle encapsulated within hollow mesoporous silica microspheres. ACS Catal. 2011, 1, 207–211.
24. 2 yolk/shell structure for catalytic reduction of p-Nitrophenol. Adv. Mater.2008, 20, 1523–1528.