Carbon Dioxide Activation and Reaction Induced by Electron Transfer at an Oxide-Metal Interface

Angewandte Chemie - International Edition

Volumn 54, Issue 42, 2015, Pages 12484-12487

  Calaza, Florencia ^a   Stiehler, Christian ^a   Fujimori, Yuichi ^a   Sterrer, Martin ^a,c   Beeg, Sebastian ^a   Ruiz Oses, Miguel ^a   Nilius, Niklas ^a,d   Heyde, Markus ^a   Parviainen, Teemu ^b   Honkala, Karoliina ^b   Häkkinen, Hannu ^b   Freund, Hans Joachim ^a  

^a FRITZ HABER INSTITUT DER MAX PLANCK GESELLSCHAFT   (Germany)

^b UNIVERSITY OF JYVÄSKYLÄ   (Finland)

^c UNIVERSITY OF GRAZ   (Austria)

^d UNIVERSITY OF OLDENBURG   (Germany)

Author keywords

carbon dioxide; electron transfer; metal insulator metal structure; oxalate; oxygen

Indexed keywords

CARBON; CARBON DIOXIDE; ELECTRON TRANSITIONS; FREE RADICAL REACTIONS; METAL INSULATOR BOUNDARIES; METALS; OXALIC ACID; OXYGEN; SCANNING TUNNELING MICROSCOPY; SEMICONDUCTOR INSULATOR BOUNDARIES;

ANION RADICALS; ATOMIC LEVELS; CARBON DIOXIDE ACTIVATION; ELECTRON TRANSFER; ELEMENTARY STEPS; METAL-INSULATOR-METAL STRUCTURES; OXALATE; OXIDE-METAL INTERFACE;

MIM DEVICES;

EID: 84943199912     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201501420     Document Type: Article

References (44)

1. United Nations Framework Convention on Climate Change, at http://unfcc.int/ghg-data/items/3800.php.
2. Carbon Dioxide as Chemical Feedstock (Ed.:, M. Aresta,), Wiley-VCH, Weinheim, 2010;
3. K. Weissermel, H.-J. Arpe, Industrielle organische Chemie, Verlag Chemie, Weinheim, 1978;
4. J. Paul, C.-M. Pradier, Carbon Dioxide Chemistry: Environmental Issues, Special Publication No. 153, The Royal Society of Chemistry, London, 1994;
5. Methane Conversion, Proceedings of a Symposium on the Production of Fuels and Chemicals from Natural Gas. Vol.36 (Eds.:, D.M. Bibby, C.D. Chang, R.F. Howe, S. Yurchak,), Elsevier, Amsterdam, 1988;
6. S. Teuner, Hydrocarbon Process. 1985, 64, 106;
7. F. Solymosi, G. Kutsán, A. Erdöhelyi, Catal. Lett. 1991, 11, 149;
8. M. M. Halmann, M. Steinberg, Greenhouse Gas Carbon Dioxide Mitigation: Science and Technology, CRC, Boca Raton, 1998;
9. E. E. Benson, C. P. Kubiak, A. J. Sathrum, J. M. Smieja, Chem. Soc. Rev. 2009, 38, 89;
10. W. Wang, S. Wang, X. Ma, J. Gong, Chem. Soc. Rev. 2011, 40, 3703;
11. D. Preti, C. Resta, S. Squarcialupi, G. Fachinetti, Angew. Chem. Int. Ed. 2011, 50, 12551;
12. Angew. Chem. 2011, 123, 12759;
13. W. Zhu, R. Michalsky, Ö. Metin, H. Lv, S. Guo, C. J. Wright, X. Sun, A. A. Peterson, S. Sun, J. Am. Chem. Soc. 2013, 135, 16833.
14. H.-J. Freund, M. W. Roberts, Surf. Sci. Rep. 1996, 25, 225;
15. F. Solymosi, J. Mol. Catal. 1991, 65, 337.
16. K. O. Hartman, I. C. Hisatsune, J. Chem. Phys. 1966, 44, 1913;
17. R. N. Compton, P. W. Reinhardt, C. D. Cooper, J. Chem. Phys. 1975, 63, 3821;
18. J. Pacansky, U. Wahlgren, P. S. Bagus, J. Chem. Phys. 1975, 62, 2740;
19. D. Schröder, C. A. Schalley, J. N. Harvey, H. Schwarz, Int. J. Mass Spectrom. 1999, 185-187, 25.
20. A. D. Walsh, J. Chem. Soc. 1953, 2260.
21. T. Sommerfeld, H.-D. Meyer, L. S. Cederbaum, Phys. Chem. Chem. Phys. 2004, 6, 42.
22. U. Burghaus, Prog. Surf. Sci. 2014, 89, 161.
23. A. Stamatovic, K. Stephan, T. D. Märk, Int. J. Mass Spectrom. Ion Processes 1985, 63, 37;
24. M. Knapp, O. Echt, D. Kreisle, T. D. Märk, E. Recknagel, Chem. Phys. Lett. 1986, 126, 225;
25. E. L. Quitevis, D. R. Herschbach, J. Phys. Chem. 1989, 93, 1136;
26. M. Lezius, T. Rauth, V. Grill, M. Foltin, T. D. Mark, Z. Phys. D 1992, 24, 289.
27. H. J. Freund, N. Nilius, T. Risse, S. Schauermann, Phys. Chem. Chem. Phys. 2014, 16, 8148;
28. T. Risse, S. Shaikhutdinov, N. Nilius, M. Sterrer, H.-J. Freund, Acc. Chem. Res. 2008, 41, 949.
29. D. Ricci, A. Bongiorno, G. Pacchioni, U. Landman, Phys. Rev. Lett. 2006, 97, 036106.
30. M. Sterrer, T. Risse, M. Heyde, H.-P. Rust, H.-J. Freund, Phys. Rev. Lett. 2007, 98, 206103.
31. X. Lin, B. Yang, H. M. Benia, P. Myrach, M. Yulikov, A. Aumer, M. Brown, M. Sterrer, O. Bondarchuk, E. Kieseritzky, J. Rocker, T. Risse, H. Gao, N. Nilius, H. J. Freund, J. Am. Chem. Soc. 2010, 132, 7745.
32. C. Stiehler, F. Calaza, W.-D. Schneider, N. Nilius, H.-J. Freund, submitted.
33. X. Lin, N. Nilius, M. Sterrer, P. Koskinen, H. Häkkinen, H.-J. Freund, Phys. Rev. B 2010, 81, 153406.
34. X. Lin, N. Nilius, H. J. Freund, M. Walter, P. Frondelius, K. Honkala, H. Häkkinen, Phys. Rev. Lett. 2009, 102, 206801.
35. C. Stiehler, Y. Pan, W.-D. Schneider, P. Koskinen, H. Häkkinen, N. Nilius, H.-J. Freund, Phys. Rev. B 2013, 88, 115415.
36. M. Sterrer, M. Nowicki, M. Heyde, N. Nilius, T. Risse, H.-P. Rust, G. Pacchioni, H.-J. Freund, J. Phys. Chem. B 2006, 110, 46.
37. O. Seiferth, K. Wolter, B. Dillmann, G. Klivenyi, H. J. Freund, D. Scarano, A. Zecchina, Surf. Sci. 1999, 421, 176.
38. G. Pacchioni, ChemPhysChem 2003, 4, 1041;
39. G. Preda, G. Pacchioni, M. Chiesa, E. Giamello, J. Phys. Chem. C 2008, 112, 19568;
40. C. A. Downing, A. A. Sokol, C. R. A. Catlow, Phys. Chem. Chem. Phys. 2014, 16, 184.
41. J. Fujita, A. E. Martell, K. Nakamoto, J. Chem. Phys. 1962, 36, 339.
42. J. Paul, F. M. Hoffmann, L. L. Robbins, J. Phys. Chem. 1988, 92, 6967;
43. F. M. Hoffmann, M. D. Weisel, J. Paul, Surf. Sci. 1994, 316, 277;
44. R. L. Toomes, D. A. King, Surf. Sci. 1996, 349, 65.