Hard X-rays in-soft X-rays out: An operando piggyback view deep into a charging lithium ion battery with X-ray Raman spectroscopy

Journal of Electron Spectroscopy and Related Phenomena

Volumn 200, Issue , 2015, Pages 257-263

  Braun, Artur ^a   Nordlund, Dennis ^b   Song, Seung Wan ^c   Huang, Tzu Wen ^a   Sokaras, Dimosthenis ^b   Liu, Xiasong ^d   Yang, Wanli ^d   Weng, Tsu Chien ^b   Liu, Zhi ^d  

^a SWISS FEDERAL LABORATORIES FOR MATERIALS SCIENCE AND TECHNOLOGY   (Switzerland)

^b SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^c Chungnam National University   (South Korea)

^d LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

Battery; Lithium; Manganese; Operando; Soft X rays; X ray Raman

Indexed keywords

CATHODES; ELECTRIC BATTERIES; ELECTRODES; ELECTRONIC STRUCTURE; LITHIUM; LITHIUM ALLOYS; LITHIUM-ION BATTERIES; MANGANESE; PROBES; RAMAN SPECTROSCOPY; SECONDARY BATTERIES;

BATTERY; BATTERY CHARGING AND DISCHARGING; BULK SENSITIVE; CATH-ODE MATERIALS; LITHIUM INTERCALATION; OPERANDO; SOFT X-RAY; STRUCTURE INFORMATION;

CHARGING (BATTERIES);

EID: 84942295859     PISSN: 03682048     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.elspec.2015.03.005     Document Type: Article

References (25)

1. D.J. Fabian, L.M. Watson, and C.A.W. Marshall Soft X-ray spectroscopy and the electronic structure of solids Rep. Prog. Phys. 34 2 1971 601 696
2. F.M.F. de Groot, and A. Kotani Core Level Spectroscopy of Solids 2008 CRC Press New York 9780849390715
3. A. Braun, S. Seifert, P. Thiyagarajan, S.P. Cramer, and E.J. Cairns In situ anomalous small angle X-ray scattering and absorption on an operating rechargeable lithium ion battery cell Electrochem. Commun. 3 3 2001 136 141
4. A. Braun, S. Shrout, A.C. Fowlks, B.A. Osaisai, S. Seifert, E. Granlund, and E.J. Cairns Electrochemical in situ reaction cell for X-ray scattering, diffraction and spectroscopy J. Synchrotron Radiat. 10 2003 320 325
5. R. Qiao, T. Chin, S.J. Harris, S. Yan, and W. Yang Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides Curr. Appl. Phys. 13 2013 544 548
6. S.P. Cramer, and et al. Ligand field strengths and oxidation states from manganese L-edge spectroscopy J. Am. Chem. Soc. 113 21 1991 7937 7940
7. A. Braun, and et al. Origin of chemical shift of manganese in lithium battery electrode materials - a comparison of hard and soft X-ray techniques J. Power Sources 112 1 2003 231 235
8. A. Braun, H. Wang, T. Funk, S. Seifert, and E.J. Cairns Depth profile analysis of a cycled lithium ion LiMn2O4 battery electrode via the valence state of Mn with soft X-ray emission spectroscopy J. Power Sources 195 22 2010 7644 7648
9. J. Guo The development of in situ photon-in/photon-out soft X-ray spectroscopy on beamline 7.0.1 at the ALS J. Electron Spectrosc. Relat. Phenom. 2013 10.1016/j.elspec.2012.12.007
10. K. Tohji, and Y. Udagawa X-ray Raman scattering as a substitute for soft-X-ray extended X-ray-absorption fine structure Phys. Rev. B 39 1989 7590 7594
11. W. Schülke Electron Dynamics by Inelastic X-ray Scattering 2007 Oxford University Press
12. F. Gel'mukhanov, and H. Agren X-ray Raman scattering as a means for studies of near-edge and extended X-ray absorption fine structures Physica B 208-209 1995 100 102
13. U. Bergmann, P. Glatzel, and S.P. Cramer Bulk-sensitive XAS characterization of light elements: from X-ray Raman scattering to X-ray Raman spectroscopy Microchem. J. 71 2002 221 230
14. U. Bergmann, and et al. X-ray Raman spectroscopy at the oxygen K edge of water and ice: implications on local structure models Phys. Rev. B 66 2002 092107 092110
15. D. Sokaras, and et al. A high resolution and large solid angle X-ray Raman spectroscopy end-station at the Stanford Synchrotron Radiation Lightsource Rev. Sci. Instrum. 83 2012 043112
16. R.S. Liu, and et al. X-ray absorption studies in spinel-type LiMn2O4 J. Solid State Chem. 128 1997 326 329
17. J.-W. Song, and et al. Impacts of surface Mn valence on cycling performance and surface chemistry of Li- and Al-substituted spinel battery cathodes J. Electrochem. Soc. 158 5 2011 A458 A464
18. W.-S. Yoon, K.-Y. Chung, K.-W. Oh, and K.-B. Kim Changes in electronic structure of the electrochemically Li-ion deintercalated LiMn2O4 system investigated by soft X-ray absorption spectroscopy J. Power Sources 119-121 2003 706 709
19. F.M.F. de Groot X-ray absorption and dichroism of transition metals and their compounds J. Electron Spectrosc. Relat. Phenom. 67 4 1994 529 622
20. L.F.J. Piper, and et al. Soft X-ray spectroscopic study of dense strontium-doped lanthanum manganite cathodes for solid oxide fuel cell applications J. Electrochem. Soc. 158 2 2011 B99 B105
21. S. Kobayashi, T. Usui, H. Ikuta, Y. Uchimoto, and M. Wakihara Soft X-ray absorption near edge structure analysis on lithium manganese oxide prepared by microwave heating J. Am. Ceram. Soc. 87 6 2004 1002 1007
22. B.T. Thole, and G. van der Laan Branching ratio in X-ray absorption spectroscopy Phys. Rev. B 38 1988 3158 3171
23. R. Follath The versatility of collimated plane grating monochromators Nucl. Instrum. Methods Phys. Res. A 467-468 2001 418 425
24. T. Ressler WinXAS: a program for X-ray absorption spectroscopy data analysis under MS-Windows J. Synchrotron Radiat. 5 2 1998 118 122
25. X. Liu, D. Wang, G. Liu, V. Srinivasan, Z. Liu, Z. Hussain, and W. Yang Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy Nat. Commun. 4 2013 2568