In Situ Synthesis of MnS Hollow Microspheres on Reduced Graphene Oxide Sheets as High-Capacity and Long-Life Anodes for Li- and Na-Ion Batteries

ACS Applied Materials and Interfaces

Volumn 7, Issue 37, 2015, Pages 20957-20964

  Xu, Xijun ^a   Ji, Shaomin ^a   Gu, Mingzhe ^a   Liu, Jun ^a,b  

^a XIANGTAN UNIVERSITY   (China)

^b SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

anode; excellent electrochemical performance; hollow structures; Li ion batteries; MnS graphene composites; Na ion batteries

Indexed keywords

ANODES; ELECTRIC BATTERIES; ELECTRIC DISCHARGES; ELECTROCHEMICAL ELECTRODES; ELECTRODES; GRAPHENE; IONS; LITHIUM; LITHIUM COMPOUNDS; LITHIUM-ION BATTERIES; MICROSPHERES; NANOCOMPOSITES; NANOSHEETS;

ELECTROCHEMICAL PERFORMANCE; ELECTRONIC CONDUCTIVITY; HOLLOW STRUCTURE; HYDROTHERMAL METHODS; LI-ION BATTERIES; NA-ION BATTERIES; REDUCED GRAPHENE OXIDES; REDUCED GRAPHENE OXIDES (RGO);

SECONDARY BATTERIES;

EID: 84942238429     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/acsami.5b06590     Document Type: Article

References (46)

1. Zhu, T.; Peh, N.; Kang, C.; Hong, M.; Ho, G. W. Outside-In Recrystallization of ZnS-Cu1.8S Hollow Spheres with Interdispersed Lattices for Enhanced Visible Light Solar Hydrogen Generation Chem.-Eur. J. 2014, 20, 11505-11510 10.1002/chem.201402491
2. Liu, J.; Song, K.; van Aken, P. A.; Maier, J.; Yu, Y. Self-Supported Li4Ti5O12-C Nanotube Arrays as High-Rate and Long-Life Anode Materials for Flexible Li-Ion Batteries Nano Lett. 2014, 14, 2597-2603 10.1021/nl5004174
3. Liu, J.; Liu, W.; Chen, K.; Ji, S.; Zhou, Y.; Wan, Y.; Xue, D.; Hodgson, P.; Li, Y. Facile Synthesis of Transition-Metal Oxide Nanocrystals Embedded in Hollow Carbon Microspheres for High-Rate Lithium-Ion-Battery Anodes Chem.-Eur. J. 2013, 19, 9811-9816 10.1002/chem.201300357
4. Li, X.; Shen, J.; Li, N.; Ye, M. Fabrication of γ-MnS/rGO Composite by Facile One-Pot Solvothermal Approach for Supercapacitor Applications J. Power Sources 2015, 282, 194-201 10.1016/j.jpowsour.2015.02.057
5. Guo, J.; Li, F.; Sun, Y.; Zhang, X.; Tang, L. Graphene-Encapsulated Cobalt Sulfides Nanocages with Excellent Anode Performances for Lithium Ion Batteries Electrochim. Acta 2015, 167, 32-38 10.1016/j.electacta.2015.03.136
6. Zhu, C.; Mu, X.; van Aken, P. A.; Yu, Y.; Maier, J. Single-Layered Ultrasmall Nanoplates of MoS2 Embedded in Carbon Nanofibers with Excellent Electrochemical Performance for Lithium and Sodium Storage Angew. Chem., Int. Ed. 2014, 53, 2152-2156 10.1002/anie.201308354
7. Liu, J.; Wen, Y.; van Aken, P. A.; Maier, J.; Yu, Y. In Situ Reduction and Coating of SnS2 Nanobelts for Free-Standing SnS@Polypyrrole-Nanobelt/Carbon-Nanotube Paper Electrodes With Superior Li-ion Storage J. Mater. Chem. A 2015, 3, 5259-5265 10.1039/C5TA00431D
8. Wang, Q.; Jiao, L.; Han, Y. et al. CoS2 Hollow Spheres: Fabrication and Their Application in Lithium-Ion Batteries J. Phys. Chem. C 2011, 115, 8300-8304 10.1021/jp111626a
9. Zhang, Z.; Zhao, H.; Zeng, Z.; Gao, C.; Wang, J.; Xia, Q. Hierarchical Architectured NiS@SiO2 Nanoparticles Enveloped in Graphene Sheets as Anode Material for Lithium Ion Batteries Electrochim. Acta 2015, 155, 85-92 10.1016/j.electacta.2014.12.074
10. Lee, S. M.; Ko, Y. N.; Choi, S. H.; Kim, J. H.; Kang, Y. C. Capacitive Properties of Reduced Graphene Oxide Microspheres with Uniformly Dispersed Nickel Sulfide Nanocrystals Prepared by Spray Pyrolysis Electrochim. Acta 2015, 167, 287-293 10.1016/j.electacta.2015.03.196
11. Liu, J.; Xue, D. Solvothermal Synthesis of CuS Semiconductor Hollow Spheres Based on a Bubble Template Route J. Cryst. Growth 2009, 311, 500-503 10.1016/j.jcrysgro.2008.09.025
12. Jin, J.; Zhang, X.; He, T. Self-Assembled CoS2 Nanocrystal Film as an Efficient Counter Electrode for Dye-Sensitized Solar Cells J. Phys. Chem. C 2014, 118, 24877-24883 10.1021/jp508814y
13. Yang, B.; Zuo, X.; Chen, P.; Zhou, L.; Yang, X.; Zhang, H.; Li, G.; Wu, M.; Ma, Y.; Jin, S.; Chen, X. Nanocomposite of Tin Sulfide Nanoparticles with Reduced Graphene Oxide in High-Efficiency Dye-Sensitized Solar Cells ACS Appl. Mater. Interfaces 2015, 7, 137-143 10.1021/am5040522
14. Liu, J.; Wen, Y.; Wang, Y.; van Aken, P. A.; Maier, J.; Yu, Y. Carbon-Encapsulated Pyrite as Stable and Earth-Abundant High Energy Cathode Material for Rechargeable Lithium Batteries Adv. Mater. 2014, 26, 6025-6030 10.1002/adma.201401496
15. Liu, J.; Zhou, Y.; Liu, C.; Wang, J.; Pan, Y.; Xue, D. Self-assembled Porous Hierarchical-Like CoO@C Microsheets Transformed from Inorganic-Organic Precursors and Their Lithium-Ion Battery Application CrystEngComm 2012, 14, 2669-2674 10.1039/c2ce06497a
16. Liu, J.; Liu, W.; Wan, Y.; Ji, S.; Wang, J.; Zhou, Y. Facile Synthesis of Layered LiV3O8 Hollow Nanospheres as Superior Cathode Materials for High-Rate Li-Ion Batteries RSC Adv. 2012, 2, 10470-10474 10.1039/c2ra20969a
17. Liu, J.; Wan, Y.; Liu, C.; Liu, W.; Ji, S.; Zhou, Y.; Wang, J. Solvothermal Synthesis of Uniform Co3O4/C Hollow Quasi- Nanospheres for Enhanced Lithium Ion Intercalation Applications Eur. J. Inorg. Chem. 2012, 24, 3825-3829 10.1002/ejic.201200486
18. Wang, Q.; Jiao, L.; Han, Y.; Du, H.; Peng, W.; Huan, Q.; Song, D.; Si, Y.; Wang, Y.; Yuan, H. CoS2 Hollow Spheres: Fabrication and Their Application in Lithium-ion Batteries J. Phys. Chem. C 2011, 115, 8300-8304 10.1021/jp111626a
19. Su, Q.; Xie, J.; Zhang, J.; Zhong, Y.; Du, G.; Xu, B. In Situ Transmission Electron Microscopy Observation of Electrochemical Behavior of CoS2 in Lithium-Ion Battery ACS Appl. Mater. Interfaces 2014, 6, 3016-3022 10.1021/am4056084
20. Liu, W.; Liu, J.; Chen, K.; Ji, S.; Wan, Y.; Zhou, Y.; Xue, D.; Hodgson, P.; Li, Y. Enhancing the Electrochemical Performance of the LiMn2O4 Hollow Microsphere Cathode With a LiNi0. 5Mn1. 5O4 Coated Layer Chem.-Eur. J. 2014, 20, 824-830 10.1002/chem.201303675
21. Liu, J.; Liu, W.; Ji, S.; Wan, Y.; Gu, M.; Yin, H.; Zhou, Y. Iron Fluoride Hollow Porous Microspheres: Facile Solution-Phase Synthesis and Their Application for Li-Ion Battery Cathodes Chem.-Eur. J. 2014, 20, 5815-5820 10.1002/chem.201304713
22. Li, B.; Rooney, D. W.; Zhang, N.; Sun, K. An In Situ Ionic-Liquid-Assisted Synthetic Approach to Iron Fluoride/Graphene Hybrid Nanostructures as Superior Cathode Materials for Lithium Ion Batteries ACS Appl. Mater. Interfaces 2013, 5, 5057-5063 10.1021/am400873e
23. Park, S.; An, J.; Jung, I.; Piner, R. D.; An, S. J.; Li, X.; Velamakanni, A.; Ruoff, R. S. Colloidal Suspensions of Highly Reduced Graphene Oxide in a Wide Variety of Organic Solvents Nano Lett. 2009, 9, 1593-1597 10.1021/nl803798y
24. Li, X.; Zhu, Y.; Cai, W.; Borysiak, M.; Han, B.; Chen, D.; Piner, R. D.; Colombo, L.; Ruoff, R. S. Transfer of Large-Area Graphene Films for High-Performance Transparent Conductive Electrodes Nano Lett. 2009, 9, 4359-4363 10.1021/nl902623y
25. Wu, Z.-S.; Zhou, G.; Yin, L.-C.; Ren, W.; Li, F.; Cheng, H.-M. Graphene/Metal Oxide Composite Electrode Materials for Energy Storage Nano Energy 2012, 1, 107-131 10.1016/j.nanoen.2011.11.001
26. Dreyer, D. R.; Park, S.; Bielawski, C. W.; Ruoff, R. S. The Chemistry of Graphene Oxide Chem. Soc. Rev. 2010, 39, 228-240 10.1039/B917103G
27. Park, S.; Ruoff, R. S. Chemical Methods for the Production of Graphenes Nat. Nanotechnol. 2009, 4, 217-224 10.1038/nnano.2009.58
28. Kong, S.; Jin, Z.; Liu, H.; Wang, Y. Morphological Effect of Graphene Nanosheets on Ultrathin CoS Nanosheets and Their Applications for High-Performance Li-Ion Batteries and Photocatalysis J. Phys. Chem. C 2014, 118, 25355-25364 10.1021/jp508698q
29. Zhang, S.; Shao, Y.; Liao, H.-g.; Liu, J.; Aksay, I. A.; Yin, G.; Lin, Y. Graphene Decorated With PtAu Alloy Nanoparticles: Facile Synthesis and Promising Application for Formic Acid Oxidation Chem. Mater. 2011, 23, 1079-1081 10.1021/cm101568z
30. Li, H.; Tay, R. Y.; Tsang, S. H.; Liu, W.; Teo, E. H. T. Reduced Graphene Oxide/Boron Nitride Composite Film as a Novel Binder-Free Anode for Lithium Ion Batteries with Enhanced Performances Electrochim. Acta 2015, 166, 197-205 10.1016/j.electacta.2015.03.109
31. Xie, J.; Liu, S.; Cao, G.; Zhu, T.; Zhao, X. Self-Assembly of CoS2/Graphene Nanoarchitecture by a Facile One-Pot Route and Its Improved Electrochemical Li-Storage Properties Nano Energy 2013, 2, 49-56 10.1016/j.nanoen.2012.07.010
32. Qiu, B.; Zhao, X.; Xia, D. In Situ Synthesis of CoS2/RGO Nanocomposites with Enhanced Electrode Performance for Lithium-Ion Batteries J. Alloys Compd. 2013, 579, 372-376 10.1016/j.jallcom.2013.05.148
33. Liu, Y.; Qiao, Y.; Zhang, W.-X.; Li, Z.; Hu, X.-L.; Yuan, L.-X.; Huang, Y.-H. Coral-Like α-MnS Composites with N-Doped Carbon as Anode Materials for High-Performance Lithium-Ion Batteries J. Mater. Chem. 2012, 22, 24026-24033 10.1039/c2jm35227c
34. Chen, D.; Quan, H.; Wang, G. S.; Guo, L. Hollow α-MnS Spheres and Their Hybrids with Reduced Graphene Oxide: Synthesis, Microwave Absorption, and Lithium Storage Properties ChemPlusChem 2013, 78, 843-851 10.1002/cplu.201300141
35. Lee, S. M.; Lee, J. K.; Kang, Y. C. Electrochemical Properties of Hollow-Structured MnS-Carbon Nanocomposite Powders Prepared by a One-Pot Spray Pyrolysis Process Chem.-Asian J. 2014, 9, 590-595 10.1002/asia.201301261
36. Aurbach, D.; Levi, M.; Gamulski, K.; Markovsky, B.; Salitra, G.; Levi, E.; Heider, U.; Heider, L.; Oesten, R. Capacity Fading of LixMn2O4 Spinel Electrodes Studied by XRD and Electroanalytical Techniques J. Power Sources 1999, 81, 472-479 10.1016/S0378-7753(99)00204-9
37. Chen, J.; Cheng, F. Combination of Lightweight Elements and Nanostructured Materials for Batteries Acc. Chem. Res. 2009, 42, 713-723 10.1021/ar800229g
38. Ma, H.; Zhang, S.; Ji, W.; Tao, Z.; Chen, J. α-CuV2O6 Nanowires: Hydrothermal Synthesis and Primary Lithium Battery Application J. Am. Chem. Soc. 2008, 130, 5361-5367 10.1021/ja800109u
39. Xu, X.; Ji, S.; Gao, R.; Liu, J. Facile Synthesis of P2-Type Na0.4Mn0.54Co0.46O2 as a High Capacity Cathode Material for Sodium-Ion Batteries RSC Adv. 2015, 5, 51454-51460 10.1039/C5RA06275F
40. Liu, J.; Liu, W.; Ji, S.; Wan, Y.; Yin, H.; Zhou, Y. Facile Synthesis of Carbon-Encapsulated Li4Ti5O12@C Hollow Microspheres as Superior Anode Materials for Li-Ion Batteries Eur. J. Inorg. Chem. 2014, 12, 2073-2079 10.1002/ejic.201301558
41. Wang, L.; Zhao, J.; He, X.; Gao, J.; Li, J.; Wan, C.; Jiang, C. Electrochemical impedance spectroscopy (EIS) study of LiNi1/3Co1/3Mn1/3O2 for Li-ion batteries Int. J. Electrochem. Sci. 2012, 1, 345-353
42. Liu, J.; Wan, Y.; Liu, W.; Wang, J.; Zhou, Y.; Xue, D. Advanced Nanostructured Cathode and Anode Materials for High-Performance Li-Ion Batteries Energy Environ. Focus 2012, 1, 19-38 10.1166/eef.2012.1003
43. Li, J.; Xiong, S.; Liu, Y.; Ju, Z.; Qian, Y. Uniform LiNi1/3Co1/3Mn1/3O2 Hollow Microspheres: Designed Synthesis, Topotactical Structural Transformation and Their Enhanced Electrochemical Performance Nano Energy 2013, 2, 1249-1260 10.1016/j.nanoen.2013.06.003
44. Zhang, L.; Zhou, L.; Wu, H. B.; Xu, R.; Lou, X. W. D. Unusual Formation of Single-Crystal Manganese Sulfide Microboxes Co-mediated by the Cubic Crystal Structure and Shape Angew. Chem. Int. Ed. 2012, 124, 7379-7382 10.1002/ange.201202877
45. Shadike, Z.; Cao, M.-H.; Ding, F.; Sang, L.; Fu, Z. Improved Electrochemical Performance of CoS2/MWCNT Nanocomposites for Sodium-Ion Batteries Chem. Commun. 2015, 51, 10486-10489 10.1039/C5CC02564H
46. Liu, J.; Wen, Y.; van Aken, P. A.; Maier, J.; Yu, Y. Facile synthesis of highly porous Ni-Sn intermetallic microcages with excellent electrochemical performance for lithium and sodium storage Nano Lett. 2014, 14, 6387-6392 10.1021/nl5028606