Fast mineralization and detoxification of amoxicillin and diclofenac by photocatalytic ozonation and application to an urban wastewater

Water Research

Volumn 87, Issue , 2015, Pages 87-96

  Moreira, Nuno F F ^a   Orge, Carla A ^a   Ribeiro, Ana R ^a   Faria, Joaquim L ^a   Nunes, Olga C ^a   Pereira, M Fernando R ^a   Silva, Adrián M T ^a  

^a UNIVERSITY OF PORTO   (Portugal)

Author keywords

Advanced oxidation processes; Amoxicillin; Diclofenac; Escherichia coli and Staphylococcus aureus; Photocatalytic ozonation; Urban wastewater

Indexed keywords

DEGRADATION; DETOXIFICATION; ESCHERICHIA COLI; MINERALOGY; ORGANIC CARBON; ORGANIC POLLUTANTS; OXIDATION; OZONE; OZONE WATER TREATMENT; PHOTOCATALYSIS; PHOTOLYSIS; SOLUTIONS; WASTEWATER TREATMENT;

ADVANCED OXIDATION PROCESSES; AMOXICILLIN; DICLOFENAC; ESCHERICHIA COLI AND STAPHYLOCOCCUS AUREUS; MINERALISATION; PHOTOCATALYTIC APPLICATION; PHOTOCATALYTIC OZONATION; STAPHYLOCOCCUS AUREUS; TOTAL ORGANIC CARBON REMOVAL; URBAN WASTEWATER;

OZONIZATION;

ALACHLOR; AMOXICILLIN; ATORVASTATIN; AZITHROMYCIN; BEZAFIBRATE; CARBAMAZEPINE; CITALOPRAM; CLARITHROMYCIN; CLOPIDOGREL; DICLOFENAC; DIPHENHYDRAMINE; ERYTHROMYCIN; ESTRONE; ETHINYLESTRADIOL; FLUOXETINE; FLUTICASONE PROPIONATE; HYDROCHLOROTHIAZIDE; IBUPROFEN; METOPROLOL; MONTELUKAST; NAPROXEN; OZONE; PROPRANOLOL; SIMVASTATIN; SULFAMETHOXAZOLE; TRAMADOL; TRIMETHOPRIM; UNINDEXED DRUG; VENLAFAXINE; WARFARIN; WASTE WATER; WATER POLLUTANT;

ANTIBIOTICS; AQUEOUS SOLUTION; BACTERIUM; DETOXIFICATION; GROWTH RATE; INHIBITION; MINERALIZATION; ORGANIC POLLUTANT; OZONE; PHOTOCHEMISTRY; PHOTOLYSIS; POLLUTANT REMOVAL; WASTEWATER;

ARTICLE; BACTERIAL GROWTH; CONTROLLED STUDY; DRUG DEGRADATION; DRUG DETOXIFICATION; ESCHERICHIA COLI; GROWTH INHIBITION; MINERALIZATION; NONHUMAN; ORGANIC POLLUTION; OZONATION; PHOTOCATALYSIS; PHOTODEGRADATION; PHOTOLYSIS; PHOTOOXIDATION; PRIORITY JOURNAL; STAPHYLOCOCCUS AUREUS; TOTAL ORGANIC CARBON; URBAN AREA; WASTE COMPONENT REMOVAL; WASTE WATER MANAGEMENT; CATALYSIS; CHEMISTRY; GROWTH, DEVELOPMENT AND AGING; OXIDATION REDUCTION REACTION; PROCEDURES; RADIATION RESPONSE; SEWAGE; WASTE WATER; WATER MANAGEMENT; WATER POLLUTANT;

ESCHERICHIA COLI; STAPHYLOCOCCUS AUREUS;

AMOXICILLIN; CATALYSIS; DICLOFENAC; ESCHERICHIA COLI; OXIDATION-REDUCTION; OZONE; PHOTOLYSIS; STAPHYLOCOCCUS AUREUS; WASTE DISPOSAL, FLUID; WASTE WATER; WATER POLLUTANTS, CHEMICAL; WATER PURIFICATION;

EID: 84941961878     PISSN: 00431354     EISSN: 18792448     Source Type: Journal    
DOI: 10.1016/j.watres.2015.08.059     Document Type: Article

References (31)

1. Aguinaco A., Beltrán F.J., García-Araya J.F., Oropesa A. Photocatalytic ozonation to remove the pharmaceutical diclofenac from water: influence of variables. Chem. Eng. J. 2012, 189-190:275-282.
2. Agustina T.E., Ang H.M., Vareek V.K. A review of synergistic effect of photocatalysis and ozonation on wastewater treatment. J. Photochem. Photobiol. C Photochem. Rev. 2005, 6(4):264-273.
3. Andreozzi R., Canterino M., Marotta R., Paxeus N. Antibiotic removal from wastewaters: the ozonation of amoxicillin. J. Hazard. Mater. 2005, 122(3):243-250.
4. Anipsitakis G.P., Dionysiou D.D. Transition metal/UV-based advanced oxidation technologies for water decontamination. Appl. Catal. B Environ. 2004, 54(3):155-163.
5. Bagal M.V., Gogate P.R. Degradation of diclofenac sodium using combined processes based on hydrodynamic cavitation and heterogeneous photocatalysis. Ultrason. Sonochem. 2014, 21(3):1035-1043.
6. Deblonde T., Cossu-Leguille C., Hartemann P. Emerging pollutants in wastewater: a review of the literature. Int. J. Hyg. Environ. Health 2011, 214(6):442-448.
7. Decision 495 Commission Implementing Decision (EU) 2015/495 of 20 March 2015 establishing a watch list of substances for Union-wide monitoring in the field of water policy pursuant to Directive 2008/105/EC of the European Parliament and of the Council. Off. J. Eur. Union L 2015, 78:40-42.
8. 2 photocatalysis. J. Environ. Manag. 2012, 98:168-174.
9. Dutta N.K., Annadurai S., Mazumdar K., Dastidar S.G., Kristiansen J.E., Molnar J., Martins M., Amaral L. Potential management of resistant microbial infections with a novel non-antibiotic: the anti-inflammatory drug diclofenac sodium. Int. J. Antimicrob. Agents 2007, 30(3):242-249.
10. 2 photocatalysis. Desalination 2010, 252(1-3):46-52.
11. Faria P.C.C., Órfão J.J.M., Pereira M.F.R. Activated carbon catalytic ozonation of oxamic and oxalic acids. Appl. Catal. B Environ. 2008, 79(3):237-243.
12. Faria P.C.C., Órfão J.J.M., Pereira M.F.R. Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents. Appl. Catal. B Environ. 2009, 88(3-4):341-350.
13. 2 catalysed processes. J. Chem. Technol. Biotechnol. 2010, 85(6):798-804.
14. Kasprzyk-Hordern B., Ziólek M., Nawrocki J. Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment. Appl. Catal. B Environ. 2003, 46(4):639-669.
15. Kaur S.P., Rao R., Nanda S. Amoxicillin: a broad spectrum antibiotic. Int. J. Pharm. Pharm. Sci. 2011, 3(3):30-37.
16. 2 photocatalytic oxidation of monochloroacetic acid and pyridine: influence of ozone. J. Photochem. Photobiol. A Chem. 2000, 136(3):163-168.
17. Marques R.R.N., Sampaio M.J., Carrapiço P.M., Silva C.G., Morales-Torres S., Dražić G., Faria J.L., Silva A.M.T. Photocatalytic degradation of caffeine: developing solutions for emerging pollutants. Catal. Today 2013, 209:108-115.
18. Mehrjouei M., Müller S., Möller D. A review on photocatalytic ozonation used for the treatment of water and wastewater. Chem. Eng. J. 2015, 263:209-219.
19. 2 nanoparticles. Int. J. Photoenergy 2012, 2012:1-11.
20. Orge C.A., Órfão J.J.M., Pereira M.F.R. Catalytic ozonation of organic pollutants in the presence of cerium oxide-carbon composites. Appl. Catal. B Environ. 2011, 102(3-4):539-546.
21. 2 photocatalysts: operating parameters and photocatalytic mechanism. Appl. Catal. B Environ. 2012, 113-114:221-227.
22. 2-assisted photocatalysis efficiency on amoxicillin degradation. Environ. Sci. Pollut. Res. Int. 2014, 21(2):1292-1303.
23. Pérez-Estrada L.A., Maldonado M.I., Gernjak W., Agüera A., Fernández-Alba A.R., Ballesteros M.M., Malato S. Decomposition of diclofenac by solar driven photocatalysis at pilot plant scale. Catal. Today 2005, 101(3-4):219-226.
24. Quiñones D.H., Álvarez P.M., Rey A., Contreras S., Beltrán F.J. Application of solar photocatalytic ozonation for the degradation of emerging contaminants in water in a pilot plant. Chem. Eng. J. 2015, 260:399-410.
25. Rehman, M.S., Rashid, N., Ashfaq, M., Saif, A., Ahmad, N., Han J.I., Global risk of pharmaceutical contamination from highly populated developing countries, Chemosphere, http://dx.doi.org/10.1016/j.chemosphere.2013.02.036, (in press).
26. Sánchez L., Peral J., Domènech X. Aniline degradation by combined photocatalysis and ozonation. Appl. Catal. B Environ. 1998, 19(1):59-65.
27. Vaz-Moreira I., Nunes O.C., Manaia C.M. Bacterial diversity and antibiotic resistance in water habitats: searching the links with the human microbiome. FEMS Microbiol. Rev. 2014, 38(4):761-778.
28. Wang S., Shiraishi F., Nakano K. A synergistic effect of photocatalysis and ozonation on decomposition of formic acid in an aqueous solution. Chem. Eng. J. 2002, 87(2):261-271.
29. Watkinson A.J., Murby E.J., Costanzo S.D. Removal of antibiotics in conventional and advanced wastewater treatment: implications for environmental discharge and wastewater recycling. Water Res. 2007, 41(18):4164-4176.
30. Xiao J., Xie Y., Cao H. Organic pollutants removal in wastewater by heterogeneous photocatalytic ozonation. Chemosphere 2015, 121:1-17.
31. Yu H., Nie E., Xu J., Yan S., Cooper W.J., Song W. Degradation of diclofenac by advanced oxidation and reduction processes: kinetic studies, degradation pathways and toxicity assessments. Water Res. 2013, 47(5):1909-1918.