The role of green extraction techniques in Green Analytical Chemistry

TrAC - Trends in Analytical Chemistry

Volumn 71, Issue , 2015, Pages 2-8

  Armenta, Sergio ^a   Garrigues, Salvador ^a   de la Guardia, Miguel ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

Author keywords

Extraction; Green Analytical Chemistry; Liquid liquid extraction; Microextraction; Sample preparation; Selectivity; Sensitivity; Side effect; Solid phase extraction; Sustainability

Indexed keywords

CATALYST SELECTIVITY; CHEMICAL ANALYSIS; PHASE SEPARATION; SOLVENT EXTRACTION; SUSTAINABLE DEVELOPMENT;

GREEN ANALYTICAL CHEMISTRY; LIQUID-LIQUID EXTRACTION; MICROEXTRACTION; SAMPLE PREPARATION; SENSITIVITY; SIDE EFFECT; SOLID-PHASE EXTRACTION;

EXTRACTION;

REAGENT; SOLVENT;

AUTOMATION; CHEMICAL ANALYSIS; ENERGY CONSUMPTION; EXTRACTION; GREEN CHEMISTRY; LIQUID LIQUID EXTRACTION; PRIORITY JOURNAL; REVIEW; SOLID PHASE EXTRACTION; SOLVENT EXTRACTION; TEMPERATURE; WASTE MINIMIZATION;

EID: 84941261463     PISSN: 01659936     EISSN: 18793142     Source Type: Journal    
DOI: 10.1016/j.trac.2014.12.011     Document Type: Review

References (83)

1. Malissa H. Changes of paradigms in Analytical Chemistry. Reviews on Analytical Chemistry, Euroanalysis VI 1988, Les Editions de Physique, Paris. E. Roth (Ed.).
2. Anastas P.T. Green chemistry and the role of analytical methodology development. Crit. Rev. Anal. Chem 1999, 29:167-175.
3. Anastas P.T., Warner J.C. Green Chemistry: Theory and Practice 1998, Oxford University Press, Oxford.
4. Anastas P.T., Williamson T.C. Green Chemistry: Frontiers in Benign Chemical Syntheses and Processes 1998, Oxford University Press, Oxford.
5. de la Guardia M., Armenta S. Green Analytical Chemistry: Theory and Practice 2011, Elsevier, Amsterdam.
6. Challenges in Green Analytical Chemistry 2011, RSC Publishing, Cambridge. M. de la Guardia, S. Garrigues (Eds.).
7. Handbook of Green Analytical Chemistry 2012, John Wiley & Sons, Ltd., Chichester. M. de la Guardia, S. Garrigues (Eds.).
8. Armenta S., Garrigues S., de la Guardia M. Green analytical chemistry. Trends Analyt. Chem 2008, 27:497-511.
9. Koel M., Kaljurand M. Green Analytical Chemistry 2010, RSC Publishing, Cambridge.
10. de la Guardia M., Garrigues S. The social responsibility of environmental analysis. Trends Environ. Anal. Chem 2014, 3-4:7-13.
11. Galuszka A., Migaszewski Z., Namieśnik J. The 12 principles of green analytical chemistry and the SIGNIFICANCE mnemonic of green analytical practices. Trends Analyt. Chem 2013, 50:78-84.
12. Eionet European topic centre on sustainable consumption and production Available from, accessed 26.05.15. http://scp.eionet.europa.eu/themes/lca.
13. US National Water Quality Monitoring Council, National Environmental Methods Index (NEMI) Available from, accessed 14.12.14. https://www.nemi.gov/home/.
14. Raynie D., Driver J.L. Green assessment of chemical methods 2009, Presented at 13th Green Chemistry and Engineering Conference, Washington, DC.
15. Gałuszka A., Konieczka P., Migaszewski Z.M., Namiesnik J. Analytical Eco-Scale for assessing the greenness of analytical procedures. Trends Analyt. Chem 2012, 37:61-72.
16. Armenta S., de la Guardia M., Namiesnik J. Green microextraction. Analytical Microextraction Techniques 2015, Bentham Science, ebook. M. Valcarcel (Ed.).
17. Garrigues S., de la Guardia M. Non-invasive analysis of solid samples. Trends Analyt. Chem 2013, 43:161-173.
18. Dowlati M., de la Guardia M., Dowlati M., Saeid S. Mohtasebi, Application of machine-vision techniques to fish-quality assessment. Trends Analyt. Chem 2012, 40:168-179.
19. Picó Y. Ultrasound-assisted extraction for food and environmental samples. Trends Analyt. Chem 2013, 43:84-99.
20. Delgado-Povedano M.M., Luque de Castro M.D. Ultrasound-assisted analytical emulsification-extraction. Trends Analyt. Chem 2013, 45:1-13.
21. Bendicho C., De La Calle I., Pena F., Costas M., Cabaleiro N., Lavilla I. Ultrasound-assisted pretreatment of solid samples in the context of green analytical chemistry. Trends Analyt. Chem 2012, 31:50-60.
22. Srogi K. A review: application of microwave techniques for environmental analytical chemistry. Anal. Lett 2006, 39:1261-1288.
23. Lamble K.J., Hill S.J. Microwave digestion procedures for environmental matrices. Analyst 1998, 123:103R-133R.
24. Smith F.E., Arsenault E.A. Microwave-assisted sample preparation in analytical chemistry. Talanta 1996, 43:1207-1268.
25. Soxhlet F. Die gewichtsanalytische Bestimmung des Milchfettes. Polytechnisches J. (Dingler's) 1879, 232:461-465.
26. Hyötyläinen T. Critical evaluation of sample pretreatment techniques. Anal. Bioanal. Chem 2009, 394:743-758.
27. Spietelun A., Marcinkowski L., de la Guardia M., Namieśnik J. Green aspects, developments and perspectives of liquid phase microextraction techniques. Talanta 2014, 119:34-45.
28. Spietelun A., Marcinkowski L., de la Guardia M., Namieśnik J. Recent developments and future trends in solid phase microextraction techniques towards green analytical chemistry. J. Chromatogr. A 2013, 1321:1-13.
29. Mahugo-Santana C., Sosa-Ferrera Z., Torres-Padrón M.E., Santana-Rodríguez J.J. Application of new approaches to liquid-phase microextraction for the determination of emerging pollutants. Trends Analyt. Chem 2011, 30:731-748.
30. Pena-Pereira F., Lavilla I., Bendicho C. Liquid-phase microextraction techniques within the framework of green chemistry. Trends Analyt. Chem 2010, 29:617-628.
31. Kokosa J.M. Advances in solvent-microextraction techniques. Trends Analyt. Chem 2013, 43:2-13.
32. Mehdinia A., Aziz-Zanjani M.O. Advances for sensitive, rapid and selective extraction in different configurations of solid-phase microextraction. Trends Analyt. Chem 2013, 51:13-22.
33. Risticevic S., Niri V.H., Vadoud D., Vuckovic D., Pawliszyn J. Recent developments in solid-phase microextraction. Anal. Bioanal. Chem 2009, 393:781-795.
34. Andruch V., Burdel M., Kocúrová L., Šandrejová J., Balogh I.S. Application of ultrasonic irradiation and vortex agitation in solvent microextraction. Trends Analyt. Chem 2013, 49:1-19.
35. Szreniawa-Sztajnert A., Zabiegała B., Namieśnik J. Developments in ultrasound-assisted microextraction techniques for isolation and preconcentration of organic analytes from aqueous samples. Trends Analyt. Chem 2013, 49:45-54.
36. Capelo J.L., Mota A.M. Ultrasonication for analytical chemistry. Curr. Anal. Chem 2005, 1:193-201.
37. Pastor A., Vazquez E., Ciscar R., de la Guardia M. Efficiency of the microwave-assisted extraction of hydrocarbons and pesticides from sediments. Anal. Chim. Acta 1997, 344:241-249.
38. Nieto A., Borrull F., Pocurull E., Marcé R.M. Pressurized liquid extraction: a useful technique to extract pharmaceuticals and personal-care products from sewage sludge. Trends Analyt. Chem 2010, 29:752-764.
39. Sun H.W., Ge X.S., Lu Y.K., Wang A.B. Application of accelerated solvent extraction in the analysis of organic contaminants, bioactive and nutritional compounds in food and feed. J. Chromatogr. A 2012, 1237:1-23.
40. Mustafa A., Turner C. Pressurized liquid extraction as a green approach in food and herbal plants extraction: a review. Anal. Chim. Acta 2011, 703:8-18.
41. Luque de Castro M.D., Priego-Capote F. Soxhlet extraction: past and present panacea. J. Chromatogr. A 2010, 1217:2383-2389.
42. Psillakis E., Kalogerakis N. Developments in single-drop microextraction. Trends Analyt. Chem 2002, 21:54-64.
43. Jain A., Verma K.K. Recent advances in applications of single-drop microextraction: a review. Anal. Chim. Acta 2011, 706:37-65.
44. Jeannot M.A., Przyjazny A., Kokosa J.M. Single drop microextraction-Development, applications and future trends. J. Chromatogr. A 2010, 1217:2326-2336.
45. Kocurova L., Balogh I.S., Andruch V. A glance at achievements in the coupling of headspace and direct immersion single-drop microextraction with chromatographic techniques. J. Sep. Sci 2013, 36:3758-3768.
46. Rezaee M., Assadi Y., Millani M.R., Aghaee E., Ahmadi F., Berijani S. Determination of organic compounds in water using dispersive liquid-liquid microextraction. J. Chromatogr. A 2006, 1116:1-9.
47. Pedersen-Bjergaard S., Rasmussen K.E. Liquid-liquid-liquid microextraction for sample preparation of biological fluids prior to capillary electrophoresis. Anal. Chem 1999, 71:2650-2656.
48. Liu W., Lee H.K. Continuous-flow microextraction exceeding 1000-Fold concentration of dilute analytes. Anal. Chem 2000, 72:4462-4467.
49. Lu Y., Lin Q., Luo G., Dai Y. Directly suspended droplet microextraction. Anal. Chim. Acta 2006, 566:259-264.
50. Chimuka L., Cukrowska E., Michel M., Buszewski B. Advances in sample preparation using membrane-based liquid-phase microextraction techniques. Trends Analyt. Chem 2011, 30:1781-1792.
51. Miró M., Frenzel W. Automated membrane-based sampling and sample preparation exploiting flow-injection analysis. Trends Analyt. Chem 2004, 23:624-636.
52. Kuban P., Karlberg B. Flow/sequential injection sample treatment coupled to capillary electrophoresis. A review. Anal. Chim. Acta 2009, 648:129-145.
53. Maya F., Horstkotte B., Estela J.M., Cerdà V. Automated in-syringe dispersive liquid-liquid microextraction. Trends Analyt. Chem 2014, 59:1-8.
54. Martinis E.M., Berton P., Wuilloud R.G. Ionic liquid-based microextraction techniques for trace-element analysis. Trends Analyt. Chem 2014, 60:54-70.
55. Trujillo-Rodríguez M.J., Rocío-Bautista P., Pino V., Afonso A.M. Ionic liquids in dispersive liquid-liquid microextraction. Trends Analyt. Chem 2013, 51:87-106.
56. Aguilera-Herrador E., Lucena R., Cárdenas S., Valcárcel M. The roles of ionic liquids in sorptive microextraction techniques. Trends Analyt. Chem 2010, 29:602-616.
57. Zhang P.J., Hu L., Lu R.H., Zhou W.F., Gao H.X. Application of ionic liquids for liquid-liquid microextraction. Anal. Methods-UK 2013, 5:5376-5385.
58. Chemat F., Vian M.A., Cravotto G. Green extraction of natural products: concept and principles. Int. J. Mol. Sci 2012, 13:8615-8627.
59. Sarafraz Yazdi A. Surfactant-based extraction methods. Trends Analyt. Chem 2011, 30:918-929.
60. Alexandru L., Binello A., Mantegna S., Boffa L., Chemat F., Cravotto G. Efficient green extraction of polyphenols from post-harvested agro-industry vegetal sources in Piedmont. C. R. Chim 2014, 17:212-217.
61. Buszewski B., Szultka M. Past, present, and future of solid phase extraction: a review. Crit. Rev. Anal. Chem 2012, 42:198-213.
62. Anastassiades M., Lehotay S.J., Stajnbaher D., Schenck F.J. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and "dispersive solid-phase extraction" for the determination of pesticide residues in produce. J. AOAC Int 2003, 86:412-431.
63. Arthur C.L., Pawliszyn J. Solid phase microextraction with thermal desorption using fused silica optical fibers. Anal. Chem 1990, 62:2145-2148.
64. Spietelun A., Kloskowski A., Chrzanowski W., Namiesnik J. Understanding solid-phase microextraction: key factors influencing the extraction process and trends in improving the technique. Chem. Rev 2013, 113:1667-1685.
65. Kloskowski A., Pilarczyk M., Namieśnik J. Membrane solid-phase microextraction - A new concept of sorbent preparation. Anal. Chem 2009, 81:7363-7367.
66. Basheer C., Suresh V., Renu R., Lee H.K. Development and application of polymer-coated hollow fiber membrane microextraction to the determination of organochlorine pesticides in water. J. Chromatogr. A 2004, 1033:213-220.
67. Luo Y.Z., Pawliszyn J. Calibration of membrane extraction for air analysis. Anal. Chem 2000, 72:1064-1071.
68. Aziz-Zanjani M.O., Mehdinia A. Electrochemically prepared solid-phase microextraction coatings-a review. Anal. Chim. Acta 2013, 781:1-13.
69. Chai X., He Y., Ying D., Jia J., Sun T. Electrosorption-enhanced solid-phase microextraction using activated carbon fiber for determination of aniline in water. J. Chromatogr. A 2007, 1165:26-31.
70. Seidi S., Yamini Y., Rezazadeh M. Electrochemically assisted solid based extraction techniques: a review. Talanta 2015, 132:339-353.
71. Li Y., Fabiano-Tixier A.S., Vian M.A., Chemat F. Solvent-free microwave extraction of bioactive compounds provides a tool for green analytical chemistry. Trends Analyt. Chem 2013, 47:1-11.
72. Kabir A., Furton K.G., Malik A. Innovations in sol-gel microextraction phases for solvent-free sample preparation in analytical chemistry. Trends Analyt. Chem 2013, 45:197-218.
73. Rout P.K., Rao Y.R., Naik S. Analysis of floral volatiles by using headspace-solid phase microextraction: a review. Asian J. Chem 2012, 24:945-956.
74. Stashenko E.E., Martinez J.R. Sampling volatile compounds from natural products with headspace/solid-phase micro-extraction. J. Biochem. Biophys. Methods 2007, 70:235-242.
75. Valenzuela A., Lespes G., Quiroz W., Aguilar L.F., Bravo M.A. Speciation analysis of organotin compounds in human urine by headspace solid-phase micro-extraction and gas chromatography with pulsed flame photometric detection. Talanta 2014, 125:196-203.
76. de Mello A.J., Beard N. Dealing with 'real' samples: sample pre-treatment in microfluidic systems. Lab Chip 2003, 3:11N-19N.
77. Miró M. On-chip microsolid-phase extraction in a disposable sorbent format using mesofluidic platforms. Trends Analyt. Chem 2014, 62:154-161.
78. de la Guardia M., Garrigues S. Partial least squares attenuated total reflectance IR spectroscopy versus chromatography: the greener method. Bioanalysis 2012, 4:1267-1269.
79. Kakhki R.M. Recent developments in microextraction techniques based on crown ethers. J. Incl. Phenom. Macrocycl. Chem 2013, 76:253-261.
80. Beltran A., Borrull F., Marcé R.M., Cormack P.A.G. Molecularly-imprinted polymers: useful sorbents for selective extractions. Trends Analyt. Chem 2010, 29:1363-1375.
81. Farhadi K., Matin A.A., Amanzadeh H., Biparva P., Tajik H., Farshid A.A., et al. A novel dispersive micro solid phase extraction using zein nanoparticles as the sorbent combined with headspace solid phase micro-extraction to determine chlorophenols in water and honey samples by GC-ECD. Talanta 2014, 128:493-499.
82. Acebal C.C., Simonet B.M., Valcárcel M. Nanoparticles and continuous-flow systems combine synergistically for preconcentration. Trends Analyt. Chem 2013, 43:109-120.
83. Lasarte-Aragones G., Lucena R., Cardenas S., Valcarcel M. Nanoparticle-based microextraction techniques in bioanalysis. Bioanalysis 2011, 3:2533-2548.