Dynamics of Magnesite Formation at Low Temperature and High pCO2 in Aqueous Solution

Environmental Science and Technology

Volumn 49, Issue 17, 2015, Pages 10736-10744

  Qafoku, Odeta ^a   Dixon, David A ^b   Rosso, Kevin M ^a   Schaef, Herbert T ^a   Bowden, Mark E ^c   Arey, Bruce W ^c   Felmy, Andrew R ^a,d  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF ALABAMA   (United States)

^c PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^d WASHINGTON STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONATES; HYDRATION; REACTION INTERMEDIATES; SOLUTIONS; TEMPERATURE;

ACIDIC CONDITIONS; CHEMICAL EQUATIONS; EQUILIBRIUM PHASE; GEOLOGICAL FORMATION; HYDRATED CARBONATES; REACTIVE TRANSPORT; SOLIDS CHARACTERIZATION; SOLUTION ANALYSIS;

MAGNESITE;

CARBON DIOXIDE; CARBONIC ACID; MAGNESITE; MAGNESIUM CARBONATE; MAGNESIUM DERIVATIVE; MAGNESIUM HYDROXIDE; UNCLASSIFIED DRUG; MAGNESIUM; SOLUTION AND SOLUBILITY;

AQUEOUS SOLUTION; CARBON DIOXIDE; CARBON SEQUESTRATION; GEOLOGICAL SURVEY; LOW TEMPERATURE; MAGNESITE; REACTION KINETICS; REACTIVE TRANSPORT; SUPERSATURATION;

ACIDITY; AQUEOUS SOLUTION; ARTICLE; CARBON DIOXIDE TENSION; CHEMICAL REACTION; DISSOLUTION; LOW TEMPERATURE; PRESSURE; ATMOSPHERE; CHEMISTRY; COLD; PARTIAL PRESSURE; SCANNING ELECTRON MICROSCOPY; SOLUTION AND SOLUBILITY; THERMOGRAVIMETRY; X RAY DIFFRACTION;

ATMOSPHERE; CARBON DIOXIDE; COLD TEMPERATURE; MAGNESIUM; MAGNESIUM HYDROXIDE; MICROSCOPY, ELECTRON, SCANNING; PARTIAL PRESSURE; SOLUTIONS; THERMOGRAVIMETRY; X-RAY DIFFRACTION;

EID: 84940972561     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/acs.est.5b02588     Document Type: Article

References (64)

1. 2-rock interactions during CO2 storage in sedimentary rocks Int. J. Greenhouse Gas Control 2010, 4, 73-89 10.1016/j.ijggc.2009.09.015
2. Giammar, D. E.; Bruant, R. G.; Peters, C. A. Forsterite dissolution and magnesite precipitation at conditions relevant for deep saline aquifer storage and sequestration of carbon dioxide Chem. Geol. 2005, 217, 257-276 10.1016/j.chemgeo.2004.12.013
3. 2-Rich Gases-Reaction Design for Added Capacity Energy Convers. Manage. 1993, 34, 941-948 10.1016/0196-8904(93)90040-H
4. 2 sequestration and enhanced coalbed methane recovery in Alberta, Canada-Historical perspective and future plans Abstr. Pap. Am. Chem. Soc. 2000, 220, U396
5. Kaszuba, J. P.; Janecky, D. R.; Snow, M. G. Carbon dioxide reaction processes in a model brine aquifer at 200°C and 200 bar: implications for geologic sequestration of carbon Appl. Geochem. 2003, 18, 1065-1080 10.1016/S0883-2927(02)00239-1
6. Kaszuba, J. P.; Janecky, D. R.; Snow, M. G. Experimental evaluation of mixed fluid reactions between supercritical carbon dioxide and NaCl brine: Relevance to the integrity of a geologic carbon repository Chem. Geol. 2005, 217, 277-293 10.1016/j.chemgeo.2004.12.014
7. 13C NMR Spectroscopy J. Phys. Chem. C 2010, 114, 4126-4134 10.1021/jp1001308
8. McGrail, B. P.; Schaef, H. T.; Glezakou, V. A.; Dang, L. X.; Owen, A. T. Water reactivity in the liquid and supercritical CO2 phase: has half of the story been neglected? Energy Procedia 2009, 1, 3415-3419 10.1016/j.egypro.2009.02.131
9. 2 sequestration Chem. Geol. 2005, 217, 183-186 10.1016/j.chemgeo.2004.12.006
10. 2 SPE J. 2003, 8, 49-60 10.2118/83695-PA
11. 2 Geochim. Cosmochim. Acta 2014, 134, 197-209 10.1016/j.gca.2013.09.024
12. Rochelle, C. A.; Bateman, K.; Pearce, J. M. Fluid-Rock Interactions Resulting from the Underground Disposal of Carbon Dioxide. In Proceedings of 4th International Symposium on Geochemistry of Earth's Surface; Bottrell, S. H., Ed.; University of Leeds: UK, 1996, ' pp 448-452.
13. 2-saturated fluid Appl. Geochem. 2007, 22, 202-218 10.1016/j.apgeochem.2006.09.005
14. 2 disposal in deep arenaceous formations J. Geophys. Res. 2003, 108, 2071-2083 10.2172/801952
15. 2 with forsterite: Evidence for magnesite formation at low temperatures Geochim. Cosmochim. Acta 2012, 91, 271-282 10.1016/j.gca.2012.05.026
16. McPherson, B. Identifying the Most Promising Regional Carbon Sequestration Deployment Opportunities in the Southwestern U.S. In Fourth Annual Conference on Carbon Capture and Sequestration; Southwest Regional Partnership on Carbon Sequestration, DE-PS26-O3NT41983; Socorro, NM, 2006.
17. 2O. II. Activity-Product Constant of Magnesite Am. J. Sci. 1970, 268, 439-453 10.2475/ajs.268.5.439
18. 2O J. Geol. 1965, 73, 730-754 10.1086/627113
19. Sayles, F. L.; Fyfe, W. S. Crystallization of Magnesite from Aqueous-Solution Geochim. Cosmochim. Acta 1973, 37, 87-99 10.1016/0016-7037(73)90246-9
20. 3 systems Proc. Natl. Acad. Sci. U. S. A. 2013, 110, 17750-17755 10.1073/pnas.1307612110
21. Saldi, G. D.; Jordan, G.; Schott, J.; Oelkers, E. H. Magnesite growth rates as a function of temperature and saturation state Geochim. Cosmochim. Acta 2009, 73, 5646-5657 10.1016/j.gca.2009.06.035
22. Bénézeth, P.; Saldi, G. D.; Dandurand, J. L.; Schott, J. Experimental determination of the solubility product of magnesite at 50 to 200°C Chem. Geol. 2011, 286, 21-31 10.1016/j.chemgeo.2011.04.016
23. 2 pressure Chem. Eng. Sci. 2008, 63, 1012-1028 10.1016/j.ces.2007.09.052
24. Higgins, S. R.; Jordan, G.; Eggleston, C. M. Dissolution kinetics of magnesite in acidic aqueous solution: A hydrothermal atomic force microscopy study assessing step kinetics and dissolution flux Geochim. Cosmochim. Acta 2002, 66, 3201-3210 10.1016/S0016-7037(02)00920-1
25. Jordan, G.; Higgins, S. R.; Eggleston, C. M.; Knauss, K. G.; Schmahl, W. W. Dissolution kinetics of magnesite in acidic aqueous solution, a hydrothermal atomic force microscopy (HAFM) study: Step orientation and kink dynamics Geochim. Cosmochim. Acta 2001, 65, 4257-4266 10.1016/S0016-7037(01)00729-3
26. Kittrick, J. A.; Peryea, F. J. Determination of the Gibbs Free-Energy of Formation of Magnesite by Solubility Methods Soil Sci. Soc. Am. J. 1986, 50, 243-247 10.2136/sssaj1986.03615995005000010047x
27. 2 Slurry Enhanced by NaOH and a Heat-Ageing Step (from 20 to 90°C) Cryst. Growth Des. 2012, 12, 5233-5240 10.1021/cg300652s
28. Pokrovsky, O. S.; Schott, J. Processes at the magnesium-bearing carbonates solution interface. II. Kinetics and mechanism of magnesite dissolution Geochim. Cosmochim. Acta 1999, 63, 881-897 10.1016/S0016-7037(99)00013-7
29. Pokrovsky, O. S.; Schott, J.; Thomas, F. Processes at the magnesium-bearing carbonates solution interface. I. A surface speciation model for magnesite Geochim. Cosmochim. Acta 1999, 63, 863-880 10.1016/S0016-7037(99)00008-3
30. 2 Chem. Geol. 2005, 217, 239-255 10.1016/j.chemgeo.2004.12.012
31. Saldi, G. D.; Schott, J.; Pokrovsky, O. S.; Gautier, Q.; Oelkers, E. H. An experimental study of magnesite precipitation rates at neutral to alkaline conditions and 100-200°C as a function of pH, aqueous solution composition and chemical affinity Geochim. Cosmochim. Acta 2012, 83, 93-109 10.1016/j.gca.2011.12.005
32. Deelman, J. C. Low-temperature formation of dolomite and magnesite. Geol. Ser. CD 2011; pp 186-210. http://www.jcdeelman.demon.nl/dolomite/bookprospectus.html.
33. Stevula, L.; Petrovic, J.; Kubranova, M. Formation of Synthetic Magnesite by Carbonatization of Hydromagnesite under Hydrothermal Conditions Chem. Pap. 1978, 32, 441-443
34. Zhang, P.; Anderson, H. L.; Kelly, J. W.; Krumhansl, J. L.; Papenguth, H. W. Kinetics and Mechanisms of Formation of Magnesite from Hydromagnesite in Brine; SAN099-1946J; Sandia National Laboratories: Albuquerque, NM, 2000.
35. Möller, P. In Mineral Deposits, Friedrich, G.; Möller, P., Eds.; Magnesite Series 28; Gebrüder Borntraeger: Berlin-Stutgart, 1989; p 287.
36. 2 sequestration reactions using a novel microreaction system Environ. Sci. Technol. 2004, 38, 932-936 10.1021/es0346375
37. 2 Environ. Sci. Technol. 2011, 45, 6204-6210 10.1021/es201284e
38. 2 Dissolution Environ. Sci. Technol. 2012, 46, 5253-5260 10.1021/es300403n
39. Loring, J. S.; Thompson, C. A.; Zhang, C. Y.; Wang, Z. M.; Schaef, H. T.; Rosso, K. M. In Situ Infrared Spectroscopic Study of Brucite Carbonation in Dry to Water-Saturated Supercritical Carbon Dioxide J. Phys. Chem. A 2012, 116, 4768-4777 10.1021/jp210020t
40. 2: An in situ high pressure X-ray diffraction study Geochim. Cosmochim. Acta 2011, 75, 7458-7471 10.1016/j.gca.2011.09.029
41. 2 Sequestration Environ. Sci. Technol. 2010, 44, 406-411 10.1021/es9017656
42. Harrison, A. L.; Power, I. M.; Dipple, G. M. Accelerated Carbonation of Brucite in Mine Tailings for Carbon Sequestration Environ. Sci. Technol. 2013, 47, 126-134 10.1021/es3012854
43. Felmy, A. R. GMIN, a computerized chemical equilibrium program using a constrained minimization of the Gibbs free energy: Summary report Spec. Publ. Soil Sci. Soc. Am. 1995, 42, 377-407
44. Pitzer, K. S. Thermodynamics of Electrolytes: I. Theoretical Basis and General Equations J. Phys. Chem. 1973, 77, 268-277 10.1021/j100621a026
45. Pitzer, K. S.; Simonson, J. M. Correction J. Phys. Chem. 1991, 95, 6746-6746 10.1021/j100170a069
46. 2O System to High Ionic Strengths at 25°C Geochim. Cosmochim. Acta 1984, 48, 723-751 10.1016/0016-7037(84)90098-X
47. De Visscher, A.; Vanderdeelen, J.; Konigsberger, E.; Churagulov, B. R.; Ichikuni, M.; Tsurumi, M. IUPAC-NIST Solubility Data Series. 95. Alkaline Earth Carbonates in Aqueous Systems. Part 1. Introduction, Be and Mg J. Phys. Chem. Ref. Data 2012, 41 (1) 1-67 dx.doi.org/10.1063/1.3675992 10.1063/1.3675992
48. 5 Pascals) Pressure and at Higher Temperatures; U.S. Geological Survey Bulletin No. 2131; U.S. Government Printing Office: Washington, DC, 1995.
49. Gautier, Q.; Bénézeth, P.; Mavromatis, V.; Schott, J. Hydromagnesite solubility product and growth kinetics in aqueous solution from 25 to 75°C Geochim. Cosmochim. Acta 2014, 138, 1-20 10.1016/j.gca.2014.03.044
50. Davies, P. J.; Bubela, B. Transformation of Nesquehonite into Hydromagnesite Chem. Geol. 1973, 12, 289-300 10.1016/0009-2541(73)90006-5
51. Zachmann, D. W. In Mineral Deposits, Friedrich, G.; Möller, P., Eds.; Magnesite Series 28; Gebrüder Borntraeger: Berlin-Stutgart, 1989, 61.
52. Putnis, A.; Putnis, C. V. The mechanism of reequilibration of solids in the presence of a fluid phase J. Solid State Chem. 2007, 180, 1783-1786 10.1016/j.jssc.2007.03.023
53. 2 degassing of Mg-bearing solutions Geochim. Cosmochim. Acta 2012, 76, 1-13 10.1016/j.gca.2011.10.023
54. 2O Trans. Faraday Soc. 1959, 55, 2203-2220 10.1039/tf9595502203
55. Frost, R. L.; Hales, M. C.; Locke, A. J.; Kristof, J.; Horvath, E.; Vagvolgyi, V. Controlled Rate Thermal analysis of hydromagnesite J. Therm. Anal. Calorim. 2008, 92, 893-897 10.1007/s10973-007-8845-6
56. Hales, M. C.; Frost, R. L.; Martens, W. N. Thermo-Raman spectroscopy of synthetic Nesquehonite-implication for the geosequestration of greenhouse gases J. Raman Spectrosc. 2008, 39, 1141-1149 10.1002/jrs.1950
57. 2O Geochim. Cosmochim. Acta 1999, 63, 3105-3119 10.1016/S0016-7037(99)00238-0
58. 2 sequestration Geochim. Cosmochim. Acta 2015, 148, 477-495 10.1016/j.gca.2014.10.020
59. Power, I. M.; Wilson, S. A.; Harrison, A. L.; Dipple, G. M.; McCutcheon, J.; Southam, G.; Kenward, P. A. A depositional model for hydromagnesite-magnesite playas near Atlin, Britich Columbia, Canada Sedimentology 2014, 61, 1701-1733 10.1111/sed.12124
60. Ruiz-Agudo, E.; Putnis, C. V.; Putnis, A. Coupled dissolution and precipitation at mineral fluid interfaces Chem. Geol. 2014, 383, 132-146 10.1016/j.chemgeo.2014.06.007
61. Putnis, C. V.; Ruiz-Agudo, E.; Hövelmann, J. Coupled fluctuations in element release during dolomite dissolution Mineral. Mag. 2014, 78, 1355-1362 10.1180/minmag.2014.078.6.01
62. McGrail, B. P.; Spane, F. A.; Amonette, J. E.; Thompson, C. R.; Brown, C. F. Injection and Monitoring at the Wallula Basalt Pilot Project Energy Procedia 2014, 63, 2939-2948 10.1016/j.egypro.2014.11.316
63. McGrail, B. P.; Spane, F. A.; Sullivan, E. C.; Bacon, D. H.; Hund, G. The Wallula basalt sequestration pilot project Energy Procedia 2011, 4, 5653-5660 10.1016/j.egypro.2011.02.557
64. McGrail, B. P.; Sullivan, E. C.; Spane, F. A.; Bacon, D. H.; Hund, G.; Thorne, P. D.; Thompson, C. J.; Reidel, S. P.; Colwell, F. S. Preliminary Hydrogeologic Characterization Results from the Wallula Basalt Pilot Study; PNWD-4129; Battelle Pacific Northwest Division: Richland, WA, 2009.