Simultaneous acquisition of differential electrochemical mass spectrometry and infrared spectroscopy data for in situ characterization of gas evolution reactions in lithium-ion batteries

Electrochemistry Communications

Volumn 60, Issue , 2015, Pages 64-69

  Berkes, Balázs B ^a   Jozwiuk, Anna ^a   Sommer, Heino ^a,b   Brezesinski, Torsten ^a   Janek, Jürgen ^a,c  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b BASF SE   (Germany)

^c JUSTUS LIEBIG UNIVERSITY   (Germany)

Author keywords

DEMS; FTIR; Gassing; Graphite; Lithium ion battery; NMC

Indexed keywords

ELECTRIC BATTERIES; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GRAPHITE; INFRARED SPECTROSCOPY; IONIZATION OF GASES; IONS; LITHIUM; LITHIUM ALLOYS; LITHIUM COMPOUNDS; MANGANESE; MASS SPECTROMETRY; SECONDARY BATTERIES; SPECTROMETRY;

DECOMPOSITION PRODUCTS; DEMS; DIFFERENTIAL ELECTROCHEMICAL MASS SPECTROMETRY; FTIR; GASSING; IN-SITU CHARACTERIZATION; NMC; SIMULTANEOUS ACQUISITION;

LITHIUM-ION BATTERIES;

EID: 84940510793     PISSN: 13882481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.elecom.2015.08.002     Document Type: Article

References (18)

1. J. Vetter, P. Novák, M.R. Wagner, C. Veit, K.-C. Müller, J.O. Besenhard, M. Winter, M. Wohlfahrt-Mehrens, C. Vogler, and A. Hammouche Ageing mechanisms in lithium-ion batteries J. Power Sources 147 2005 269 281
2. P. Arora, R.E. White, and M. Doyle Capacity fade mechanisms and side reactions in lithium-ion batteries J. Electrochem. Soc. 145 1998 3647 3667
3. C.P. Aiken, J. Xia, D.Y. Wang, D.A. Stevens, S. Trussler, and J.R. Dahn An apparatus for the study of in situ gas evolution in Li-ion pouch cells J. Electrochem. Soc. 161 2014 A1548 A1554
4. S.S. Zhang A review on electrolyte additives for lithium-ion batteries J. Power Sources 162 2006 1379 1394
5. G. Eggert, and J. Heitbaum Electrochemical reactions of propylenecarbonate and electrolytes solved therein - a DEMS study Electrochim. Acta 31 1986 1443 1448
6. P. Novák, J.-C. Panitz, F. Joho, M. Lanz, R. Imhof, and M. Coluccia Advanced in situ methods for the characterization of practical electrodes in lithium-ion batteries J. Power Sources 90 2000 52 58
7. N. Tsiouvaras, S. Meini, I. Buchberger, and H.A. Gasteiger A novel on-line mass spectrometer design for the study of multiple charging cycles of a Li-O2 battery J. Electrochem. Soc. 160 2013 A471 A477
8. H. Baltruschat Differential electrochemical mass spectrometry J. Am. Soc. Mass Spectrom. 15 2004 1693 1706
9. H. Wang, E. Rus, T. Sakuraba, J. Kikuchi, Y. Kiya, and H.D. Abruna CO2 and O2 evolution at high voltage cathode materials of Li-Ion batteries: a differential electrochemical mass spectrometry study Anal. Chem. 86 2014 6197 6201
10. R. Imhof, and P. Novák In situ investigation of the electrochemical reduction of carbonate electrolyte solutions at graphite electrodes J. Electrochem. Soc. 145 1998 1081 1087
11. M. Winter, R. Imhof, F. Joho, and P. Novák FTIR and DEMS investigations on the electroreduction of chloroethylene carbonate-based electrolyte solutions for lithium-ion cells J. Power Sources 81-82 1999 818 823
12. O. Wolter, and J. Heitbaum Differential electrochemical mass spectroscopy (DEMS) - a new method for the study of electrode processes Ber. Bunsenges. Phys. Chem. 88 1984 2 6
13. M. Onuki, S. Kinoshita, Y. Sakata, M. Yanagidate, Y. Otake, M. Ue, and M. Deguchi Identification of the source of evolved gas in Li-ion batteries using 13C-labeled solvents J. Electrochem. Soc. 155 2008 A794 A797
14. B.B. Berkes, A. Jozwiuk, M. Vračar, H. Sommer, T. Brezesinski, and J. Janek On-line continuous flow differential electrochemical mass spectrometry with a realistic battery setup for high-precision, long-term cycling tests Anal. Chem. 87 2015 5878 5883
15. J. Vetter, M. Holzapfel, A. Wuersig, W. Scheifele, J. Ufheil, and P. Novák In situ study on CO2 evolution at lithium-ion battery cathodes J. Power Sources 159 2006 277 281
16. A. Wuersig, W. Scheifele, and P. Novák CO2 gas evolution on cathode materials for lithium-ion batteries J. Electrochem. Soc. 154 2007 A449 A454
17. M. Metzger, C. Marino, J. Sicklinger, D. Haering, and H.A. Gasteiger Anodic oxidation of conductive carbon and ethylene carbonate in high-voltage Li-ion batteries quantified by on-line electrochemical mass spectrometry J. Electrochem. Soc. 162 2015 A1123 A1134
18. G. Inzelt Milestones of the development of kinetics of electrode reactions J. Solid State Electrochem. 15 2011 1373 1389